Chen, Tianshu1; Xue, Likun1,2; Zheng, Penggang1; Zhang, Yingnan1; Liu, Yuhong1; Sun, Jingjing1; Han, Guangxuan3
; Li, Hongyong1; Zhang, Xin1,4; Li, Yunfeng1,4; Li, Hong4; Dong, Can1; Xu, Fei1,2; Zhang, Qingzhu1; Wang, Wenxing1发表期刊ATMOSPHERIC CHEMISTRY AND PHYSICS
ISSN1680-7316
2020-06-15
卷号20期号:11页码:7069-7086
DOI10.5194/acp-20-7069-2020
通讯作者Xue, Likun(xuelikun@sdu.edu.cn)
英文摘要Oil and natural gas (O&NG) exploration presents a significant source of atmospheric volatile organic compounds (VOCs), which are central players of tropospheric chemistry and contribute to formations of ozone (O-3) and secondary organic aerosols. The impacts of O&NG extraction on regional air quality have been investigated in recent years in North America, but have long been overlooked in China. To assess the impacts of O&NG exploration on tropospheric O-3 and regional air quality in China, intensive field observations were conducted during February-March and June-July 2017 in the Yellow River delta, an oil extraction region in northern China. Very high concentrations of ambient VOCs were observed at a rural site, with the highest alkane mixing ratios reaching 2498 ppbv. High-O-3 episodes were not encountered during wintertime but were frequently observed in summer. The emission profiles of VOCs from the oil fields were directly measured for the first time in China. The chemical budgets of ROx radicals and O-3 were dissected with a detailed chemical box model constrained by in situ observations. The highly abundant VOCs facilitated strong atmospheric oxidation capacity and O-3 formation in the region. Oxygenated VOCs (OVOCs) played an essential role in the ROx primary production, OH loss, and radical recycling. Photolysis of OVOCs, O-3, and HONO as well as ozonolysis reactions of unsaturated VOCs were major primary sources of ROx. NOx was the limiting factor of radical recycling and O-3 formation. This study underlines the important impacts of O&NG extraction on atmospheric chemistry and regional air quality in China.
资助机构National Natural Science Foundation of China; Shandong Provincial Science Fund for Distinguished Young Scholar; Shenzhen Science and Technology Research and Development Funds Grant; Qilu Youth Talent Programme of Shandong University; Jiangsu Collaborative Innovation Center for Climate Change; Taishan Scholars
收录类别SCI
语种英语
关键词[WOS]PEARL RIVER DELTA; C-1-C-5 ALKYL NITRATES; NATURAL-GAS EXTRACTION; MISSING OH SOURCE; UINTAH BASIN; ATMOSPHERIC OXIDATION; SURFACE OZONE; WINTERTIME OZONE; RURAL SITE; SIGNIFICANT INCREASE
研究领域[WOS]Environmental Sciences & Ecology; Meteorology & Atmospheric Sciences
WOS记录号WOS:000541777500003
引用统计被引频次：11[WOS][WOS记录][WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cnhttp://ir.yic.ac.cn/handle/133337/28685
专题中科院海岸带环境过程与生态修复重点实验室_海岸带环境过程实验室
中科院海岸带环境过程与生态修复重点实验室
通讯作者Xue, Likun作者单位1.Shandong Univ, Environm Res Inst, Jinan, Shandong, Peoples R China
2.Shandong Univ, Shenzhen Res Inst, Shenzhen, Guangdong, Peoples R China
3.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai, Shandong, Peoples R China
4.Chinese Res Inst Environm Sci, Beijing, Peoples R China
推荐引用方式
GB/T 7714Chen, Tianshu,Xue, Likun,Zheng, Penggang,et al. Volatile organic compounds and ozone air pollution in an oil production region in northern China[J]. ATMOSPHERIC CHEMISTRY AND PHYSICS,2020,20(11):7069-7086.
APAChen, Tianshu.,Xue, Likun.,Zheng, Penggang.,Zhang, Yingnan.,Liu, Yuhong.,...&Wang, Wenxing.(2020).Volatile organic compounds and ozone air pollution in an oil production region in northern China.ATMOSPHERIC CHEMISTRY AND PHYSICS,20(11),7069-7086.
MLAChen, Tianshu,et al."Volatile organic compounds and ozone air pollution in an oil production region in northern China".ATMOSPHERIC CHEMISTRY AND PHYSICS 20.11(2020):7069-7086.
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