Li, Y; Han, HT; Pan, DW
; Zhang, PQ发表期刊JOURNAL OF THE ELECTROCHEMICAL SOCIETY
ISSN0013-4651
2019-08-02
卷号166期号:12页码:B1038-B1043
关键词CARBON-PASTE ELECTRODEVOLTAMMETRIC DETERMINATIONELECTROCHEMICAL DETECTIONASSISTED SYNTHESISNITRITENANOPARTICLESPERFORMANCEOXIDEMICROELECTRODESAMPLES
研究领域Electrochemistry; Materials Science, Coatings & Films
DOI10.1149/2.1281912jes
产权排序[Li, Ying; Zhang, Peiqing] Yantai Univ, Sch Chem & Chem Engn, Yantai 264005, Peoples R China; [Li, Ying; Han, Haitao; Pan, Dawei] Chinese Acad Sci, Yantai Inst Coastal Zone Res, Res Ctr Coastal Envimnment Engn Technol Shandong, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China; [Han, Haitao; Pan, Dawei] Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Shandong, Peoples R China; [Han, Haitao; Pan, Dawei] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
通讯作者Han, Haitao(hthan@yic.ac.cn); Zhang, Peiqing(zhangpqytu@126.com)
作者部门海岸带环境工程技术研究与发展中心
英文摘要In this work, a new micro-needle sensor based on copper microspheres (CuMSs) and polyaniline (PANI) film was fabricated through electrodeposition method and used for the voltammetric determination of nitrate (NO3-) in coastal river samples. The PANI film functions as the conductive polymer and adhesion agent to immobilize the CuMSs which has good electrocatalytic property for the reduction of NO3-. The CuMSs could be more easily deposited on the micro-needle electrode (MNE) surface with PANI film as adhesion agent. The physical and electrochemical properties of the as-prepared micro-needle electrode were characterized by different techniques. CuMSs with diameter of about 0.5 to 1 mu m were decorated on the PANI film modified micro-needle electrode. The unique structure of micro-needle electrode and excellent properties of CuMSs and PANI film make the micro-needle sensor possesses the advantages of larger specific surface and high electrocatalytic property towards the reduction of NO3-. The micro-needle electrode based on CuMSs and PANI film shows a linear response to NO3- in the concentrations ranging from 0.02 to 6 mM (R-2 = 0.995) with the detection limit of 8 mu M. More importantly, the determination of NO3- in coastal river water samples was achieved with the micro-needle electrode with satisfactory results. (C) The Author(s) 2019. Published by ECS.
文章类型Article
资助机构Key Research and Development Plan of Yantai City [2017ZH096, 2018ZHGY076]; Key Research and Development Plan of Shandong Province [2017GHY215002]
收录类别SCI
语种英语
关键词[WOS]CARBON-PASTE ELECTRODE; VOLTAMMETRIC DETERMINATION; ELECTROCHEMICAL DETECTION; ASSISTED SYNTHESIS; NITRITE; NANOPARTICLES; PERFORMANCE; OXIDE; MICROELECTRODE; SAMPLES
研究领域[WOS]Electrochemistry; Materials Science, Coatings & Films
WOS记录号WOS:000478803200001
引用统计被引频次：7[WOS][WOS记录][WOS相关记录]
文献类型期刊论文
条目标识符http://ir.yic.ac.cnhttp://ir.yic.ac.cn/handle/133337/24886
专题中科院海岸带环境过程与生态修复重点实验室_海岸带环境工程技术研究与发展中心
作者单位1.Yantai Univ, Sch Chem & Chem Engn, Yantai 264005, Peoples R China;
2.Chinese Acad Sci, Yantai Inst Coastal Zone Res, Res Ctr Coastal Envimnment Engn Technol Shandong, Key Lab Coastal Environm Proc & Ecol Remediat, Yantai 264003, Peoples R China;
3.Chinese Acad Sci, Ctr Ocean Mega Sci, Qingdao 266071, Shandong, Peoples R China;
4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714Li, Y,Han, HT,Pan, DW,et al. Fabrication of a Micro-Needle Sensor Based on Copper Microspheres and Polyaniline Film for Nitrate Determination in Coastal River Waters[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY,2019,166(12):B1038-B1043.
APALi, Y,Han, HT,Pan, DW,&Zhang, PQ.(2019).Fabrication of a Micro-Needle Sensor Based on Copper Microspheres and Polyaniline Film for Nitrate Determination in Coastal River Waters.JOURNAL OF THE ELECTROCHEMICAL SOCIETY,166(12),B1038-B1043.
MLALi, Y,et al."Fabrication of a Micro-Needle Sensor Based on Copper Microspheres and Polyaniline Film for Nitrate Determination in Coastal River Waters".JOURNAL OF THE ELECTROCHEMICAL SOCIETY 166.12(2019):B1038-B1043.
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