蒋继宏, 张小影, 金祖权
青岛理工大学 土木工程学院, 山东 青岛 266033

摘要:
海洋环境下的金属面临着非常严峻的腐蚀问题，必须采取措施进行防护。光电化学阴极保护是一种绿色环保的新型防腐蚀技术，受到了广泛的关注。本文简要阐述了光电化学阴极保护技术的原理以及对光阳极的要求；详细介绍了以二氧化钛为代表的几种常见光阳极材料及其不同改性方法；此外还介绍了兼具储能与阴极保护功能的光阳极，它有望实现暗态下连续保护的目标；最后讨论了光电化学阴极保护技术的发展趋势。
关键词:海洋环境腐蚀防护光电化学阴极保护光电半导体二氧化钛
DOI：10.11759/hykx20200720002
分类号:
基金项目:国家自然科学基金项目（U1806225，41976044，51609233）

Research progress in photochemical cathodic protection technology
JIANG Ji-hong, ZHANG Xiao-ying, JIN Zu-quan
School of Civil Engineering, Qingdao University of Technology, Qingdao 266033, China
Abstract:
Metals in the marine environment encounter serious corrosion problems; thus, measures must be taken to protect them. Photochemical cathodic protection is a new green and environmental anti-corrosion technology, which has attracted considerable attention. This study briefly describes the principle of photochemical cathodic protection technology and the requirements for photoanode. Several common photoanode materials represented by TiO₂ and their different modification methods are introduced in detail. In addition, the photoanode with the functions of energy storage and cathodic protection, which is expected to achieve the goal of continuous protection in the unilluminated state, is introduced. Finally, the development trend of photoelectrochemical cathodic protection technology is discussed.
Key words:marine environmentcorrosion protectionphotochemical cathodic protectionphotoelectric semiconductorTiO₂





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