赵长秋教授简介
hxhgxy.lcu.edu.cn

教授
TEL/ **
EMAIL/ zhaochangqiu@lcu.edu.cn
出生日期/ 1963.08
籍 贯/山东聊城
科研方向/有机化学，不对称合成化学

讲授课程
《有机金属化学》（研究生课程）
《现代合成化学》（研究生课程）
教育经历
1984年本科毕业于山东师范大学化学系，1989年毕业于原杭州大学化学系并获硕士学位，后在原聊城师范学院工作。1993-96年在浙江大学攻读博士学位，从事金属有机化学、有机杂原子化学的研究，1996-98年在南开大学进行博士后研究工作。1998-2001年，在日本物质工学工业技术研究所担任STA研究员，从事有机磷化学的研究工作，2001年至2003年在加拿大西安大略大学做博士后，从事含磷配体的设计合成以及相关配合物超分子化学的研究工作，2003年回到日本产业技术综合研究所，担任特别研究员，继续从事有机磷化学的研究，2007年进入聊城大学化学系工作。
科研项目
碳磷多手性叔膦化合物的合成、应用及不对称诱导作用机理研究（山东省自然科学基金面上项目）
不对称磷氢化反应及相关手性含磷化合物的制备方法研究（国家自然科学基金面上项目）
获奖情况
论著一览
1. T. Chen,C.-Q. Zhao, L.-B. Han,Hydrophosphorylation of Alkynes Catalyzed by Palladium: Generality and Mechanism,J. Am. Chem. Soc.2017, 139,in press.
2. L.-J. Liu, W.-M. Wang, L. Yao, F.-J. Meng, Y.-M. Sun, H. Xu, Z.-Y. Xu, Q. Li,C.-Q. Zhao*and L.-B. Han, Reinvestigation of the Substitutions Reaction of Stereogenic Phosphoryl Compounds: Stereochemistry, Mechanism and Applications,J. Org. Chem.,2017,82, in press.
3. Jing-Jing Ye, Shao-Zhen Nie, Ji-Ping Wang, Jing-Hong Wen, Yu Zhang, Mao-Ran Qiu, andChang-QiuZhao*Nucleophilic Substitution ofP-Stereogenic Chlorophosphines: The Mechanism, Stereochemistry and Stereoselective Conversions of Diastereomeric Secondary Phosphine Oxides to Tertiary Phosphines,Org. Lett.,2017,19(19), 5384–5387.
4. Shao-Zhen Nie?, Zhong-Yang Zhou?, Ji-Ping Wang, Hui Yan, Jing-Hong Wen, Jing-Jing Ye, Yun-Yao Cui, andChang-Qiu Zhao*Non-epimerizing Alkylation of H-P Species to Stereospecifically Generate P-Stereogenic Phosphine Oxides: A Shortcut to Bidentate Tertiary Phosphine Ligands,J. Org. Chem.,2017,82(18), 9425–9434.
5. Ji-Ping Wang, Shao-Zhen Nie, Zhong-Yang Zhou, Jing-Jing Ye, Jing-Hong Wen, andChang-Qiu Zhao*Preparation of Optically Pure Tertiary Phosphine Oxides via the Addition of P?Stereogenic Secondary Phosphine Oxide to Activated Alkenes,J. Org. Chem.2016,81, 7644?7653.
6. Meng Yang, Hao Xu, Zhong-Yang Zhou, He Zhang, Li-Juan Liu, Yong-Ming Sun, Shao-Zhen Nie,Chang-Qiu Zhao*Asymmetric induction in the addition of enantiomerically pure H-phosphinate to chiral aldimines: diastereoselective generation of a-amino phosphinates with P,C-stereogenic centers,Tetrahedron: Asymmetry,2016,27, 815–822.
7. Wei-Min Wang, Li-Juan Liu, Lan Yao, Fan-Jie Meng, Yong-Ming Sun,Chang-Qiu Zhao*, Qing Xu, and Li-Biao Han, Stereospecific Preparations ofP-Stereogenic Phosphonothioates and Phosphonoselenoates,J. Org. Chem.2016,81, 6843?6847.
8. Lan Yao, Li-Juan Liu, Zhong-Yuan Xu, Shao-Zhen Nie, Xiao-Qing Xiao and Chang-Qiu Zhao, Variable mechanism of nucleophilic substitution ofP-stereogenic phosphoryl chloride with alkynyl metallic reagents,Org. Biomol. Chem.2016,14, 1702–1706.
9. Zhong-Yang Zhou, He Zhang, Lan Yao, Jing-Hong Wen, Shao-Zhen Nie, andChang-Qiu Zhao* Double Asymmetric Induction During the Addition of (RP)-Menthyl Phenyl Phosphine Oxide to Chiral Aldimines,Chirality,2016,28, 132–135.
10. He Zhang, Meng Yang, Lan Yao, Si-Yu Ji, Zhong-Yuan Xu, Yong-Ming Sun, andChang-Qiu Zhao* A Facile Synthesis of Novel Allenylphosphinates Containing Multi Potential Asymmetric Centers,J. Heterocyclic Chem.,2016,54, 1155-1158.
11. H. Zhang, Y.-M. Sun, Y. Zhao, Z.-Y. Zhou, J.-P. Wang, N. Xin, S.-Z. Nie,C.-Q. Zhao*and L.-B. Han, One-Pot Process That Efficiently Generates Single Stereoisomers of 1,3-Bisphosphinylpropanes Having Five Chiral Centers，Org. Lett.,2015,17, 142-145.
12. W.-M. Wang, L.-J. Liu,C.-Q. Zhao*, L.-B. Han Diastereoselective Hydrolysis of Asymmetric P–Cl Species and Synthesis of Optically Pure (RP)-(–)-Menthyl H-Phenylphosphinate,Eur. J. Org. Chem.,2015, 2342–2345.
13. Y. Zhao, T. Chen, D. Han,C.-Q. Zhao*, L.-B. Han, Facile Base-Mediated Redox Transformation: An Efficient Strategy for the Synthesis of α-Acyloxyphosphoryl Compounds,Org. Lett.,2014,16, 6152–6155.
14. Y.-M. Sun, N. Xin, Z.-Y. Xu, L.-J. Liu, F.-J. Meng, H. Zhang, B.-C. Fu, Q.-J. Liang, H.-X. Zheng, L.-J. Sun,C.-Q. Zhao*, L.-B. Han, Addition of optically pureH-phoshphinate to ketones: selectivity, stereochemistry and mechanism,Org. Biomol. Chem.,2014,12, 9457–9465.
15. S.-Y. Ji, Y.-M. Sun, H. Zhang, Q.-G. Hou,C.-Q. Zhao*Phosphonium salt induced stereoselective allylic rearrangement during chlorination of α-hydroxyallylphosphinates,Tetrahedron Lett.,2014,55, 5742-5744.
16. Y.-M. Sun, Z.-Y. Xu, L.-J. Liu, F.-J. Meng, H. Zhang, B.-C. Fu, L.-J. Sun, M.-J. Niu, S.-W. Gong,C.-Q. Zhao*, L.-B. Han, Preparation of enantiomerically pure a-hydroxyl phosphinates via hydrophosphorylation of aldehydes withH-phosphinate,Tetrahedron: Asy.,2014,25, 1520–1526.
17. H. Zhang, Y.-M. Sun, L. Yao, S.-Y. Ji,C.-Q. Zhao*, L.-B. Han, Stereogenic Phosphorus-Induced Diastereoselective Formation of Chiral Carbon during Nucleophilic Addition of Chiral H–P Species to Aldehydes or Ketones,Chem. Asian J.,2014,9, 1329?1333.
相关成果