张兆国 (化学系兼职教授，2004，9-）

Tel: 021-54748925

Email: zhaoguo@mail.sioc.ac.cn

简历：

1968年11月出生于山东
1987-1991：山东大学化学系毕业，获学士学位
1991-1994：南京大学化学系毕业，获硕士学位 导师：徐建华教授
1994-1997：中国科学院上海有机化学研究所毕业，获博士学位 导师：陆熙炎院士
1997-2000：宾西法尼亚州立大学化学系博士后 导师：张绪穆教授
2000，6- ：中国科学院上海有机化学研究所研究员
2000年度中国科学院百人计划
2002年上海市科技启明星
研究方向

金属参与或催化的碳-碳键形成反应，尤其注重后过渡金属催化的碳-碳键形成方法的研究。

有机膦化学，手性膦配体的设计、合成及产业化研究。

工业均相催化剂的设计，精细有机合成及不对称合成方法的研究。

发表论文

Wang, D.; Zhang, Z. “Activation and reaction of carboxylic anhydride catalyzed by palladium ” Chin. J. Org. Chem.2004, 24, 258-269.

Guo, M.; Li, D.; Sun, Y.; Zhang, Z. “Selective Reduction of the Carbonyl Group in b,g-Unsaturated a-Ketoesters by Transfer Hydrogenation with Ru-TsDPEN” Synlett, 2004, 741-743

Luo, Y.; Wang, F.; Zhu, G.; Zhang, Z. “A concise synthesis of 2-diarylphosphino-20-methoxy-1,10-binaphthalenes (MOPs) by simple resolution”, Tetrahedron Asymm. 2004, 15, 15-17.

Guo, M.; Li, D.; Zhang, Z. “Novel Synthesis of 2-Oxo-3-butynoates by Copper-Catalyzed Cross-Coupling Reaction of Terminal Alkynes and Monooxalyl Chloride”, J. Org. Chem. 2003, 68, 10172-10175.

Wang, D.; Zhang, Z. “Palladium-Catalyzed Cross-Coupling Reactions of Carboxylic Anhydrides with Organozinc Reagents”, Org. Lett., 2003, 5, 4645-4648.

Zhu, G.; Zhang, Z. “Palladium-Catalyzed Tandem Cyclization/Suzuki Coupling of 1,6-Enynes”, Org. Lett., 2003, 5, 3645-3648.

Cheng, J.; Wang, F.; Xu, J.-H.; Pan, Y.; Zhang, Z. “Palladium-catalyzed Suzuki–Miyaura reaction using aminophosphine as ligand”, Tetrahedron Lett., 2003, 44, 7095-7098.

Tong, X., Zhang, Z., Zhang, X., “Novel Rhodium-Catalyzed Cycloisomerization of 1,6-Enynes with an Intramolecular Halogen Shift” J. Am. Chem. Soc. 2003, 125, 6370-6371.

Zhang, Z.; Lu, X*. and Lang, S. “An Unexpected Reaction of Allyl Propynoate under Palladium Catalysis” Chin. J. Chem. 2002, 20, 1287-1290.

Wang, F. and Zhang Z.* “Palladium Catalyzed Amidocarbonylation”, Chin. J. Org. Chem. 2002, 22, 536-542.

Tian, J. Z.; Zhang, Z. G.; Yang, X. L.; Fun, K. H. and Xu*, J. H “Photooxygenation of Indolizines via Selective Excitation of Their Charge Transfer Complexes with Molecular Oxygen” J. Org. Chem. 2001, 66, 8230-8235

Zhang,Z.; Lu, X.*; Xu, Z.; Zhang, Q. and Han, X. “Role of Halide Ions in Divalent Palladium-Mediated Reactions: Competition between ?-Heteroatom Elimination and ?-Hydride Elimination of a Carbon-Palladium Bond”, Organometallics 2001, 20, 3724-3728

Zhang, Z.; Qian, H.; Longmire, J. and Zhang, X*. “Synthesis of Chiral Bisphosphines with Tunable Bite Angles and Their Applications in Asymmetric Hydrogenation of –Ketoesters”, J. Org. Chem. 2000; 65; 6223-6226.

Li, W.; Zhang, Z.; Xiao, D. and Zhang, X*. “Synthesis of Chiral hydroxl Phosphines from D-Mannitol and Their Use in Asymmetric Catalytic Reactions” J. Org. Chem., 2000, 65, 3489-3496.

Wang, Z.; Zhang, Z.; Lu, X*. “Effect of Halide Ligands on the Reactivity of Carbon-Palladium Bonds: Implications for Designing Catalytic Reactions” Organometallics, 2000, 19, 775-780.

Li, W.; Zhang, Z.; Xiao, D.; Zhang, X*. “Rhodium-hydroxyl bisphospholane catalyzed highly enantioselective hydrogenation of dehydroamino acids and esters” Tetrahedron Lett., 1999, 40, 6701-6704.

Jiang, Q.; Xiao, D.; Zhang, Z.; Cao, P.; Zhang, X*. “Highly enantioselective hydrogenation of cyclic enol acetates catalyzed by a Rh-PennPhos complex” Angew. Chem., Int. Ed., 1999, 38, 516-518.

Zhang, Z.; Zhu, G.; Jiang, Q.; Xiao, D.; Zhang, X*. Highly Enantioselective Hydrogenation of Cyclic Enamides Catalyzed by a Rh-PennPhos Catalyst” J. Org. Chem., 1999, 64, 1774-1775.

Xiao, D.; Zhang, Z.; Zhang, X*. “Synthesis of a Novel Chiral Binaphthyl Phospholane and Its Application in the Highly Enantioselective Hydrogenation of Enamides” Org. Lett., 1999, 1, 1679-1681.

Xiao, D.; Zhang, Z.; Jiang, Q.; Zhang, X.. “Syntheses of novel chiral 2,5-dialkyl-7- azabicyclo[2.2.1]heptanes and 2,5-dialkyl-7-thiobicyclo[2.2.1]heptanes” Tetrahedron Lett., 1998, 39, 5331-5334.

Wang, Z.; Lu, X*.; Lei, A.; Zhang, Z. “Efficient Preparation of Functionalized (E,Z) Dienes Using Acetylene as the Building Block” J. Org. Chem., 1998, 63, 3806-3807.

Lu, X*.; Zhu, G.; Wang, Z.; Ma, S.; Ji, J.; Zhang, Z. “Enyne cyclization methodology for the synthesis of bioactive lactones” Pure Appl. Chem., 1997, 69, 553-558.

Lu, X.; Zhu, G.; Wang, Z.; Ma, S.; Ji, J.; Zhang, Z. “Enyne cyclization methodology for the synthesis of bioactive lactones” Youji Huaxue, 1997. 17, 8-11.

Zhang, Z.; Lu, X*. “Total synthesis of phaseolinic acid by enyne cyclization” Tetrahedron: Asymm. 1996, 7, 1923-1928.

Xu, J.; Song, Y.; Zhang, Z.; Wang, L.; Xu, J*. “Photoinduced addition reactions of chloranil with alkenes - factors influencing the reaction site” Tetrahedron, 1994, 50, 1199-1210.

Chen, C.; Zhang,Z.; Yan, B.; Xu, J*. “Phtoinduced Reactions of Chloranil with Aromatic Imines” Tetrahedron Lett. 1994, 35, 9221-9224.

Yan, B.; Zhang, Z.; Yuan, H.; Wang, L. and Xu, J*. “Photoinduced Electron- transfer Reactions of Chloranil with Benzodioxoles” J. Chem. Soc. Perk. T 2, 1994, 2545-2550.