郑思珣
郑思珣教授、博士生导师。1997年获中国科技大学高分子化学与物理专业博士学位。1992年7月起任中国科技大学高分子科学与工程系助教、讲师(1995年)、副教授(1998年)。分别于1996年和1998年两次赴香港科技大学化学工程系做访问****。1999年1月, 获德意志研究联合会资助，赴德国高分子研究所(Deutsches Kunststoff-Institut, Darmstadt, Germany)及达姆施塔特工业大学(Technische Universitaet Darmstadt, Germany)物理系从事博士后研究。1999年9月转至美国加州大学欧文分校(University of California, Irvine, USA)化学系，为National Science Foundation (NSF)博士后研究员。2001年9月加入上海交通大学任高分子科学与工程系教授。先后承担或参加国家自然科学基金、中科院院长基金以及国家部委科研基金的研究工作; 2002年获“教育部优秀青年教师资助计划”基金支持，2004年获上海市“曙光****”称号，2009年获上海市“育才”奖。已在Advanced Materials, Chemistry of Materials, Macromolecules, Journal of Physical Chemistry, Polymer, Journal of Polymer Science等国际学术期刊发表SCI收录的论文180余篇，论文被国际同行引用(SCI他引) 超过3500次。

主要研究方向：

1、热固性聚合物的结构与性能：反应诱致微相分离、自组装行为以及材料断裂力学;
2、含笼型硅氧烷(Polyhedral Oligomeric Silsesquioxanes, POSS)的聚合物的结构与性能;
3、有机-无机复合聚合物水凝胶的微结构与凝胶行为;
4、具有拓扑结构高分子的合成及其微结构研究;
5、高分子固体核磁共振波谱研究(H-1、H-2、Si-29、C-13 CP/MAS NMR等)：a)多组分高分子体系的 相结构及其大分子动力学研究；b)有机/无机纳米复合材料中的组分间相互作用研究。

近年来发表的部分论文
1.Kun Wei, Lei Wang, Lei Li, Sixun Zheng*, Synthesis and Characterization of Bead-like Poly(N-isopropylacrylamide) with Double Decker Silsesquioxanes in the Main Chains, Polymer Chemistry, 2015, 6, 256-269

2. Houluo Cong, Jingang Li, Lei Li, Sixun Zheng*, Dielectric Constant Enhancement of Epoxy Thermosets via Formation of Polyelectrolyte Nanophases, Journal of Physical Chemistry B, 2014, 118, 14703

3.Jingang Li, Houluo Cong, Lei Li, Sixun Zheng*, Thermoresponse Improvement of Poly(N-isopropylacrylamide) Hydrogels via Formation of Poly(sodium p-styrene sulfonate) Nanophases, ACS Applied Materials & Interfaces, 2014, 16, 13677

4.Yulin Yi, Lei Li, Sixun Zheng*, Poly(epsilon-caprolactone)-block-poly(N-vinylpyrrolidone) Diblock Copolymers Grafted from Macrocyclic Oligomeric Silsesquioxane, Polymer, 2014, 55, 3925

5.Houluo Cong, Lei Li, Sixun Zheng*, Formation of Nanostructures in Thermosets Containing Block Copolymers: From Self-assembly to Reaction-induced Microphase Separation Mechanism, Polymer, 2014, 55, 1190

6.Chongyin Zhang, Lei Li, Houluo Cong, Sixun Zheng*, Poly(methyl methacrylate)-block-poly(N-vinyl pyrrolidone) Diblock Copolymer: a Facile Synthesis via Sequential Radical Polymerization Mediated by Isopropylxanthic Disulfide and Its Nanostructuring Polybenzoxazine Thermosets, Journal of Polymer Science, Part A: Polymer Chemistry, 2014, 52, 952

7.Kun Wei, Lei Li, Sixun Zheng*, Organic-Inorganic Random Copolymers from Methacrylate-terminated Poly(ethylene oxide) with 3-Methacryloxypropyl heptaphenyl Polyhedral Oligomeric Silsesquioxane: Synthesis via RAFT Polymerization and Self-assembly Behavior, Soft Matter, 2014, 10, 383

8.Kun Wei, Lei Wang, Sixun Zheng*, Organic-inorganic copolymers with double-decker silsesquioxane in the main chains by polymerization via click chemistry, Journal of Polymer Science, Part A: Polymer Chemistry, 2013, 51, 4221

9.Lei Wang, Chongyin Zhang, Houluo Cong, Lei Li, Sixun Zheng*, Xiuhong Li, Jie Wang, Formation of nanophases in epoxy thermosets containing amphiphilic block copolymers with linear and star-like topologies, Journal of Physical Chemistry B, 2013, 117(27), 8256

10. Chongyin Zhang, Lei Li, Sixun Zheng*, "Formation and Confined Crystallization of Polyethylene Nanophases in Epoxy Thermosets", Macromolecules, 2013, 46, 2740.

11. Lei Wang, Jingang Li, Lei Li, Sixun Zheng*, Organic-inorganic Hybrid Diblock Copolymer Composed of Poly(ε-caprolactone) and Poly(MA POSS): Synthesis and Its Nanocomposites with Epoxy Resin, Journal of Polymer Science, Part A: Polymer Chemistry, 2013, 51, 2079

12. Kun Wei, Lei Wang, Sixun Zheng*, Organic-Inorganic Polyurethanes with 3,13-Dihydroxypropyloctaphenyl Double-Decker Silsesquioxane Chain Extender, Polymer Chemistry, 2013, 4, 1501

13. Houluo Cong, Lei Li, Sixun Zheng*, Poly(N-isopropylacrylamide)-block-poly(vinyl pyrrolidone) Block Copolymer Networks: Synthesis and Rapid Thermoresponse of Hydrogels, Polymer, 2013, 54, 1370.

14. Rentong Yu, Sixun Zheng*, Xiuhong Li, Jie Wang, Reaction-induced Microphase Separation in Epoxy Thermosets Containing Block Copolymers Composed of Polystyrene and Poly(e-caprolactone): Influence of Copolymer Architectures on Formation of Nanophases, Macromolecules, 2012, 45, 9155.

15.Liliang Zhu, Chongyin Zhang, Jin Han, Sixun Zheng*, Formation of Nanophases in Epoxy Thermosets Containing Organic-Inorganic Macrocyclic Molecular Brush with Poly(ε-caprolactone)-block-polystyrene Side Chains, Soft Matter, 2012, 8, 7062.

16.Qinqin Zheng, Sixun Zheng*, From Poly(N-isopropylacrylamide)-block-poly(ethylene oxide)-block- poly(N-isopropylacrylamide) Triblock Copolymer to Poly(N-isopropylacrylamide)-block-poly(ethylene oxide) Hydrogels: Synthesis and Rapid Deswelling and Reswelling Behavior of Hydrogels, Journal of Polymer Science, Part A: Polymer Chemistry, 2012, 50, 1717

17.Lei Wang, Chongyin Zhang, Sixun Zheng*, Organic-inorganic Poly(hydroxyether of bisphenol A) with Double-decker Silsesquioxane in the Main Chains, Journal of Materials Chemistry, 2011, 21, 19344.

18. Fangping Yi, Rentong Yu, Sixun Zheng*, Self-organized Thermosets from Epoxy and Poly(2,2,2-trifluoroethyl acrylate)-block-poly(glycidyl methacrylate) Diblock Copolymer: Demixing of Reactive Blocks and Thermomechanical Properties, Polymer, 2011, 52, 5669.

19.Rentong Yu, Sixun Zheng*, Morphological Transition from Spherical to Lamellar Nanophases in Epoxy Thermosets Containing Poly(ethylene oxide)-block-poly(ε-caprolactone)-block-polystyrene Triblock Copolymer by Hardeners, Macromolecules, 2011, 44,8546.

20. Ke Zeng, Lei Wang, Sixun Zheng*, Nanostructures and Surface Hydrophobicity of Epoxy Thermosets Containing Hepta(3,3,3-trifluropropyl) Polyhedral Oligomeric Silsesquioxane-capped Poly(hydroxyether of bisphenol A) Telechelics, Journal of Colloid and Interface Science, 2011, 363, 250.

21.Junzhang Song, Rentong Yu, Lei Wang, Sixun Zheng*, Poly(N-vinylpyrrolidone)-grafted Poly(N-isopropylacrylamide) Copolymers: Synthesis, Characterization and Rapid Deswelling and Reswelling Behavior of Hydrogels, Polymer, 2011, 52, 2340

22. Lei Wang, Ke Zeng, Sixun Zheng*, Hepta(3,3,3-trifluoropropyl) Polyhedral Oligomeric Silsesquioxane-capped Poly(N-isopropylacrylamide) Telechelics: Synthesis and Behavior of Physical Hydrogels, ACS Applied Materials & Interfaces, 2011, 3, 898

23.Wenchun Fan, Lei Wang, Sixun Zheng*, Double Reaction-induced Microphase Separation in Epoxy Resin Containing Polystyrene-block- poly(ε-caprolactone)-block-poly(n-butyl acrylate) ABC Triblock Copolymer, Macromolecules, 2010, 43, 10600

24.Di Hu, Sixun Zheng*, Reaction-induced Microphase Separation in Polybenzoxazine Thermosets Containing Poly(N-vinyl pyrrolidone)-block- polystyrene Diblock Copolymer, Polymer, 2010,51, 6346

25.Di Hu, Chongyin Zhang, Rentong Yu, Lei Wang, Sixun Zheng*, Self-Organized Thermosets Involving Epoxy and Poly(ε-caprolactone)-block-poly(ethylene-co- ethylethylene)-block-poly(ε-caprolactone) Amphiphilic Triblock Copolymer, Polymer, 2010, 51, 6047

26.Di Hu, Zhiguang Xu, Ke Zeng, Sixun Zheng*, From Self-organized Novolac Resins to Ordered Nanoporous Carbons, Macromolecules, 2010, 43, 2960

27.Lei Wang, Sixun Zheng*, Morphology and Thermomechanical Properties of Main-chain Polybenzoxazine-block-Polydimethylsiloxane Multiblock Copolymers, Polymer, 2010, 51, 1124

28.Jin Han, Sixun Zheng*, Organic-inorganic Hybrid Brushes Consisting of Macrocyclic Oligomeric Silsesquioxane and Poly(ε-caprolactone): Synthesis, Characterization andSupramolecular Inclusion Complexation with alfa-Cyclodextrin, Journal of Polymer Science Part A: Polymer Chemistry, 2009, 47, 6894

29.Ke Zeng, Lei Wang, Sixun Zheng*, Rapid Deswelling and Reswelling Response of Poly(N-isopropylacrylamide) Hydrogels via Formation of Interpenetrating Polymer Networks with Polyhedral Oligomeric Silsesquioxane-capped Poly(ethylene oxide) Amphiphilic Telechelics, Journal of Physical Chemistry B, 2009, 113, 11831

30.Xingtian Yang, Fangping Yi, Zhirong Xin, Sixun Zheng*, Morphology and Mechanical Properties of Nanostructured Blends of Epoxy Resin with Poly(epsilon-caprolactone)-block-Poly(butadiene-co-acrylonitrile)- block-Poly(epsilon-caprolactone) Triblock Copolymer, Polymer, 2009, 50, 4089

31.Fangping Yi, Sixun Zheng*, Tianxi Liu, Nanostructures and Surface Hydrophobicity of Self-assembled Thermosets involving Epoxy Resin and Poly(2,2,2-trifluoroethyl acrylate)-block-poly(ethylene oxide) Amphiphilic Diblock Copolymer, Journal of Physical Chemistry B, 2009, 113, 1857

32.Ke Zeng, Lei Wang, Sixun Zheng*, Xuefeng Qian, Self-assembly Behavior of Hepta(3,3,3-trifluropropyl) Polyhedral Oligomeric Silsesquioxane-capped Poly(epsilon-caprolactone) in Epoxy Resin : Nanostructures and Surface Properties, Polymer, 2009, 50, 685

33.Fangping Yi, Sixun Zheng*, Effect of Hydrophobic Polystyrene Microphases on Temperature-responsive Behavior of Poly(N-isopropylacrylamide) Hydrogels, Polymer, 2009, 50, 670

34.Wenchun Fan, Lei Wang, Sixun Zheng*, Nanostructures in Thermosetting Blends of Epoxy Resin with Polydimethylsiloxane-block-Poly(epsilon-caprolactone) -block-Polystyrene ABC Triblock Copolymer, Macromolecules, 2009, 42, 327

35.Wei Gong, Ke Zeng, Lei Wang, Sixun Zheng*, Poly(hydroxyether of bisphenol A)-block-Polydimethylsiloxane Alternating Block Copolymer and Its Nanostructured Blends with Epoxy Resin, Polymer, 2008, 49, 3318

36.Wenchun Fan, Sixun Zheng*, Reaction-induced Microphase Separation in Thermosetting Blends of Epoxy Resin with Poly(methyl methacrylate)-block- Polystyrene Block Copolymers: Effect of Topologies of Block Copolymers on Morphological Structures, Polymer, 2008,49, 3157

37.Jin Han, Sixun Zheng*, Highly Porous Polysilsesquioxane Networks via Hydrosilylative Polymerization of Macrocyclic Oligomeric Silsesquioxanes, Macromolecules, 2008, 41, 4561

38.Fanliang Meng, Zhiguang Xu, Sixun Zheng*, Microphase Separation in Thermosetting Blends of Epoxy Resin and Poly(epsilon-caprolactone)- block-Polystyrene Diblock Copolymers, Macromolecules, 2008, 41, 1411



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上海交通大学化学化工学院
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Email: szheng AT sjtu DOT cn
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