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醌亚胺单缩酮的合成以及应用研究进展

本站小编 Free考研考试/2022-02-14

摘要/Abstract



由于醌亚胺单缩酮(QIKs)分子结构中含有多种官能团(C=N,C=C和缩酮等),近年来作为优良的有机合成子被应用于构建复杂的有机分子.探索醌亚胺单缩酮反应位点的选择性(化学选择性、区域选择性和立体选择性)不仅是一项十分有意义的研究课题,同时也是一项富有挑战性的研究工作.对醌亚胺单缩酮的制备方法以及其在有机合成中的应用研究进展进行综述.
关键词: 醌亚胺单缩酮, 有机合成子, 化学选择性, 区域选择性, 立体选择性
In recent years, quinone imine ketals (QIKs) have been used as excellent organic synthons to the construction of complex organic molecules due to containing diverse functional groups (C=N, C=C and ketal etc.). Exploring the site-selectivity (chemo-, regio- and stereo-selectivity) of QIKs is not only a very significant research topic, but also a challenging research work. The preparation methods of QIKs and its applications in organic synthesis are reviewed according to the recent progress.
Key words: quinone imine ketal, organic synthon, chemoselectivity, regioselectivity, stereoselectivity


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