摘要/Abstract

氢甲酰化反应是工业上最重要的均相反应之一.该反应被广泛应用于醛的生产，生产的醛还可以进一步转为具有高附加值的醇、酸等衍生物.与均相反应相比，多相催化在催化剂循环、产物和催化剂分离等方面具有优势.近年来，有机聚合物负载铑催化剂在非均相的甲酰化反应中表现出优秀的催化活性、高的选择性和好的循环性等优点，因而受到广泛关注.总结了有机聚合物负载催化剂在氢甲酰化反应中应用研究进展，主要介绍了催化剂的合成、材料特点和应用，最后对发展前景进行了展望.
关键词: 铑, 氢甲酰化, 有机聚合物, 非均相催化剂
Hydroformylation is considered one of the most important homogenously catalyzed processes in dustry. Hydroformylation has been widely used in the production of aldehydes, and aldehydes can also be further converted into high value-added alcohols, acids and other derivatives. Compared with the homogeneous reaction, the heterogeneous catalysts present significant advantages in terms of recyclability, separation of catalysts and products and so on. In recent years, organic polymer-supported rhodium catalysts have shown excellent catalytic activity, high selectivity, and good recycleability in heterogeneous hydroformylation, and have attracted widespread attention. The research progress of the application of organic polymer supported catalysts in hydroformylation is summarized, including synthesis, material characteristics and application of supported catalysts. Finally, the prospect of the reaction is discussed.
Key words: rhodium, hydroformylation, organic polymers, heterogeneous catalysts


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