摘要/Abstract
N-磺酰-1,2,3-三唑是一类重要的五元含氮有机化合物,被广泛应用于合成各类含氮有机化合物,尤其是杂环或氨基取代芳环化合物.介绍了N-磺酰-1,2,3-三唑的主要合成方法,对其作为重氮亚胺和Rh-卡宾亚胺中间体的前体,通过开环构建各类有机化合物在2018~2019年期间的最新研究进展进行了综述.
关键词: N-磺酰-1,2,3-三唑, α-重氮亚胺, Rh-卡宾亚胺
N-Sulfonyl-1,2,3-triazole, an important class of five-membered nitrogen-containing organic compounds, has been found processing widespread application in the synthesis of various nitrogen-containing organic compounds, especially heterocyclic or amino-substituted aromatic rings. The synthetic methods of N-sulfonyl-1,2,3-triazole are introduced. Besides, the progress on constructions of various organic compounds via ring-opening reaction of N-sulfonyl-1,2,3-triazoles as precursor of α-diazoimine and Rh-carbene imine intermediates in the past two years is reviewed.
Key words: N-sulfonyl-1,2,3-triazole, α-diazoimine, Rh-carbene imine
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