删除或更新信息,请邮件至freekaoyan#163.com(#换成@)

N-磺酰-1,2,3-三唑的合成方法及其在有机合成中的应用研究进展

本站小编 Free考研考试/2022-02-14

摘要/Abstract



N-磺酰-1,2,3-三唑是一类重要的五元含氮有机化合物,被广泛应用于合成各类含氮有机化合物,尤其是杂环或氨基取代芳环化合物.介绍了N-磺酰-1,2,3-三唑的主要合成方法,对其作为重氮亚胺和Rh-卡宾亚胺中间体的前体,通过开环构建各类有机化合物在2018~2019年期间的最新研究进展进行了综述.
关键词: N-磺酰-1,2,3-三唑, α-重氮亚胺, Rh-卡宾亚胺
N-Sulfonyl-1,2,3-triazole, an important class of five-membered nitrogen-containing organic compounds, has been found processing widespread application in the synthesis of various nitrogen-containing organic compounds, especially heterocyclic or amino-substituted aromatic rings. The synthetic methods of N-sulfonyl-1,2,3-triazole are introduced. Besides, the progress on constructions of various organic compounds via ring-opening reaction of N-sulfonyl-1,2,3-triazoles as precursor of α-diazoimine and Rh-carbene imine intermediates in the past two years is reviewed.
Key words: N-sulfonyl-1,2,3-triazole, α-diazoimine, Rh-carbene imine


PDF全文下载地址:

点我下载PDF
相关话题/介绍 亚胺 有机化合物 开环 氨基