摘要/Abstract

以弱配位中心丙酮肟醚为导向基团，Rh为催化剂，实现了一种高区域选择性的苯酚类化合物邻位烯基化反应.该策略具有反应条件温和、底物适应性广、区域选择性好等优点.为苯酚的选择性的邻位烯基化提供了一种新的有效方法.
关键词: 苯酚, 丙酮肟醚, 烯基化
A practical rhodium-catalyzed highly regioselective ortho-alkenylation of phenolic compound under the assistance of weak coordination center acetoxime ether was developed. This strategy has advantages of simple and mild reaction conditions, wide scope of substrate and high regioselectivity. This protocol provids an efficient and new method for the regioselective ortho-alkenylation of phenols.
Key words: phenol, acetone oxime ether, alkenylation


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