摘要/Abstract

α，α，γ，γ-四氟-β-羟基酮和α-氟代苯乙酮两类化合物被广泛运用于有机化学、农业化学以及制药等领域.开发了一种从1，3-二芳基-1，3-二酮合成α，α，γ，γ-四氟-β-羟基酮和α-氟代苯乙酮的温和且有效的方法.通过改变反应条件，可以分别以中等至良好的产率获得两种不同的产物.
关键词: α,α,γ,γ-四氟-β-羟基酮, α-氟代苯乙酮, 1,3-二芳基-1,3-二酮
α,α,γ,γ-Tetrafluoro-β-hydroxy ketones and α-fluoroacetophenones are widely used in the fields of organic chemistry, agrochemicals, and pharmaceuticals. A mild and excellent method to synthesize α,α,γ,γ-tetrafluoro-β-hydroxy ketones and α-fluoroacetophenones via various 1,3-diaryl-1,3-diketones has been developed. With the modification of reaction conditions, two different products could be obtained in moderate to good yields, respectively.
Key words: α,α,γ,γ-tetrafluoro-β-hydroxy ketones, α-fluoroacetophenones, 1,3-diaryl-1,3-diketones


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