高恩庆
教授
化学系

上海市绿色化学与化工过程绿色化重点实验室

联系电话：021－62233404

办公时间：周一至周六
传真：021－62233404

主页网址：
办公地点：化学馆B203

电子邮箱：eqgao@chem.ecnu.edu.cn
通讯地址：中山北路3663号华东师范大学化学系


研究方向
硕士/博士研究生招生专业及方向：无机化学‚配合物功能材料。

1.分子磁性材料
基于配位化合物尤其是配位聚合物的分子基磁体、纳米磁体的合成、结构与磁性
2.分子多孔材料
具有开放骨架的多孔配位聚合物（或金属－有机骨架材料‚MOF)的合成、结构、功能化及其应用
3.多功能分子材料
在配位聚合物中引入两种或多种功能‚获得复合功能材料

上述研究得到国家自然科学基金委重大及面上项目、教育部新世纪优秀人才支持计划、上海市“曙光学者”计划、上海市科委等各方面的经费支持

可接收无机化学、有机化学、催化化学专业的博士进站作博士后研究

社会兼职
学术成果
发表论文100多篇‚以下为2003年以来发表的主要论文。
1.YuMa‚Ai-LingCheng‚andEn-QingGao‚*Ferromagneticinteractionsthroughtriplehydrogenbondsinthecoordinationpolymersofa‚a¢-dihydroxy-bibenzyl-4‚4¢-dicarboxylate‚DaltonTrans.‚2010‚39(14)‚3521-3526
2.Yan-QinWang‚Qin-XiangJia‚Kun-Wang‚Ai-LingChengandEn-QingGao*‚DiverseManganese(II)CoordinationPolymerswithMixedAzideandZwitterionicDicarboxylateLigands:StructureandMagneticProperties‚Inorg.Chem.2010‚49(4)‚1551-1560.
3.QiYue‚QianSun‚AiLingCheng‚En-QingGao‚*Metal–OrganicFrameworkBasedon[Zn₄O(COO)₆]Clusters:Rare3DKagoméTopologyandLuminescence‚Cryst.GrowthDes.2010‚10(1)‚44-47.
4.YuMa‚Yan-QingWen‚Jian-YongZhang‚En-QingGao‚*andCai-MingLiu‚Structuresandmagnetismofazide-andcarboxylate-bridgedmetal(II)systemsderivedfrom1‚2-bis(N-carboxymethyl-4-pyridinio)ethane‚DaltonTrans.‚2010‚39(7)‚1846–1854
5.Yan-QinWang‚KunWang‚QianSun‚HuaTian‚En-QingGao*andYouSong‚Novelmanganese(II)andcobalt(II)3Dpolymerswithmixedcyanateandcarboxylatebridges:crystalstructureandmagneticproperties.DaltonTrans.2009‚9854–9859
6.Wei-WeiSun‚Chun-YanTian‚Xue-HuiJing‚Yan-QinWangandEn-QingGao*‚Solvent-modulatedmetamagnetisminanickel(II)coordinationpolymerwithmixedazideandcarboxylatebridges.Chem.Commun.‚2009‚4741-4743.
7.En-QingGao‚*Pei-PeiLiu‚Yan-QinWang‚QiYue‚Qing-LunWang‚Complexlong-rangemagneticorderingbehaviorsintheanisotropiccobalt(II)-azidemultilayersystems‚Chem.Eur.J.2009‚15‚1217–1226
8.YuMa‚Jian-YongZhang‚Ai-LingCheng‚QianSun‚En-QingGao*andCai-MingLiu‚Antiferro-andFerromagneticInteractionsinMn(II)‚Co(II)‚andNi(II)CompoundswithMixedAzide-CarboxylateBridges‚Inorg.Chem.2009‚48(13)‚6142-6151
9.Chun-YanTian‚Wei-WeiSun‚Qin-XiangJia‚HuaTian‚En-QingGao*‚Anovelmanganese(II)complexwithazideandneutraldicarboxylateligands:helicalstructureandmagneticpropertiesDaltonTrans.2009‚(31)‚6109-6113
10.LiYan‚QiYue‚Qin-XiangJia‚GillesLemercier‚andEn-QingGao*‚Aluminescenteuropium(III)metal-organicframeworkwithararenettopologyofoctahedralsecondarybuildingunits‚Cryst.GrowthDes.2009‚9(7)‚2984-2987
11.Yan-QinWang‚Jian-YongZhang‚Qin-XiangJia‚En-QingGao‚*Cai-MingLiu‚andDe-QingZhang‚Unprecedentedself-penetratingeight-connectednetworkbasedonnovelazide-bridgedtetramanganese(II)clusters‚Inorg.Chem.2009‚48(3)‚789-791
12.QianSun‚QiYue‚Jian-YongZhang‚LiWang‚XueLi‚En-QingGao*‚Hydrothermalsynthesis‚structures‚andpropertiesofmanganese(II)andZinc(II)coordinationpolymerswithdifferentphenylenediacrylates.Cryst.GrowthDes.2009‚9(5)‚2310-2317
13.Qin-XiangJia‚Wei-WeiSun‚Cheng-FuYao‚Hai-HongWu‚En-QingGao‚*Cai-MingLiu‚Coordinationchemistryoftetrazolate-5-carboxylatewithmanganese(II):synthesis‚structureandmagnetism‚DaltonTrans.2009‚(15)‚2721-2730
14.YuMa‚Ai-LingCheng‚Jian-YongZhang‚QiYue‚andEn-QingGao*‚One-‚Two-andThree-DimensionalCoordinationPolymersofStilbenedicarboxylatewithDifferentMetalIons‚Cryst.GrowthDes.2009‚9(2)‚867-873.
15.Qin-XiangJia‚Yan-QinWang‚QiYue‚Qing-LunWang‚andEn-QingGao‚*IsomorphousCo^IIandMn^IImaterialswithtetrazolate-5-carboxylatewithanunprecedentedself-penetratingnet:cantedantiferromagnetismandmetamagnetismonlyintheCo^IIsystem‚Chem.Commun.‚2008‚(40)‚4894-4896
16.Wei-WeiSun‚QiYue‚Ai-LingCheng‚andEn-QingGao*‚SupramolecularNetworksAssembledfromBinuclearComplexeswithPyridazine-3‚6-dicarboxylate‚CrystEngComm‚2008‚10‚1384-1394.
17.NaLiu‚QiYue‚Yan-QinWang‚Ai-LingCheng‚andEn-QingGao‚*Coordinationcompoundsofbis(5-tetrazolyl)aminewithmanganese(II)‚zinc(II)andCadmium(II):synthesis‚structureandmagneticproperties‚DaltonTrans.‚2008‚(34)‚-4629
18.Jian-YongZhang‚Qi-Yue‚Qin-XiangJia‚Ai-LingCheng‚andEn-QingGao*‚Syntheses‚StructuresandLuminesencePropertiesofCadmium(II)CoordinationPolymerswithInSituFormedOxalateandBis(chelating)BridgingLigand‚CrystEngComm‚2008‚10‚1443-1449.
19.NaLiu‚Yan-QinWang‚En-QingGao‚*Zhen-XiaChen‚andLin-HongWeng‚Supramoleculararchitecturesbasedontransitionmetalcomplexeswith1-(3-pyridyl)-2-(4’-pyrimidyl)ethane‚CrystEngComm‚2008‚10‚915-922.
20.Pei-PeiLiu‚Ai-LingCheng‚QiYue‚NaLiu‚Wei-WeiSun‚En-QingGao*‚Cobalt(II)coordinationnetworksdependentuponthespacerlengthofflexiblebis(tetrazole)ligands‚Cryst.GrowthDes.2008‚8(5)‚1668–1674
21.Jian-YongZhang‚Ai-LingCheng‚QiYue‚Wei-WeiSunandEn-QingGao‚*Eightcoordinationwithbis(bidentate)bridgingligands:zeolitictopologyversussquaregridnetworks‚Chem.Commun.‚2008‚(7)‚847-849.
22.Jian-YongZhang‚YuMa‚Ai-LingCheng‚QiYue‚QianSunandEn-QingGao*‚Amanganese(II)coordinationpolymerwithmixedpyrimidine-2-carboxylateandoxalatebridges:synthesis‚structure‚andmagnetism‚DaltonTrans.‚2008‚2061-2066.
23.Ai-LingCheng‚YuMa‚Jian-YongZhang‚andEn-QingGao‚*Towardstuningthepackingandentanglementofzigzagcoordinationchainsbyterminalligands‚DaltonTrans.2008‚1993-2004.
24.Wei-WeiSun‚Ai-LingCheng‚Qin-XiangJia‚andEn-QingGao*‚Metal-coordination-directedassemblyofbinucleartrigonalprismsandthree-dimensionalhydrogen-bondednetworks‚Inorg.Chem.‚2007‚46(14)‚5471-5473.
25.En-QingGao‚*NaLiu‚Ai-LingCheng‚andSongGao‚Novelfrustratedmagneticlatticebasedontriangular[Mn₃(m₃-F)]clusterswithtetrazoleligands.Chem.Commun.‚2007‚(24)‚2470–2472.
26.Pei-PeiLiu‚Ai-LingCheng‚NaLiu‚Wei-WeiSun‚andEn-QingGao*‚Towardstuningthebulkmagneticbehaviorsofmetal-azidomaterialsbyorganicpillars.Chem.Mater.2007‚19(11)‚2724-2726
27.Ai-LingCheng‚NaLiu‚Yan-FengYue‚Yong-WenJiang‚En-QingGao*‚Chun-HuaYanandMing-YuanHe‚Unprecedented3Dentanglementof1Dzigzagcoordinationpolymersleadingtoarobustmicroporousframework‚Chem.Commun.‚2007‚407-409
28.Ai-LingCheng‚NaLiu‚Jian-YongZhang‚En-QingGao*‚andMing-YuanHeAssemblingthecage-basedmetal-organicnetworkfromacubicmetalloligand‚Inorg.Chem.2007‚46.1034-1035
29.En-QingGao*‚Ai-LingCheng‚Yan-XiaXu‚Ming-YuanHe‚Chun-HuaYan‚Fromlow-dimensionalmanganese(II)azidomotifstohigher-dimensionalmaterials:Structureandmagneticproperties‚Inorg.Chem.2005‚44(24)‚8822-8835
30.En-QingGao‚Shi-QiangBai‚ZhengHeandChun-HuaYan‚“Thefirsttetramanganese(II)clusterwithcenteredtrigonaltopology:structureandmagneticproperties”‚Inorg.Chem.2005‚44(3)‚677-682
31.En-QingGao*‚Ai-LingCheng‚Yan-XiaXu‚Chun-HuaYan‚Ming-YuanHe‚“Newinorganic-organichybridsupramoleculararchitecturesgeneratedfrom2‚5-Bis(3-pyridyl)-3‚4-diaza-2‚4-hexadiene”Cryst.GrowthDesign.2005‚5(3)‚1005-1011.
32.En-QingGao‚Yan-FengYue‚Shi-QiangBai‚ZhengHeandChun-HuaYan‚“Novelone-dimensionalcopper(II)complexeswithend-onsingleazidobridges:structuralandmagneticproperties”Cryst.GrowthDesign.2005‚5(3)‚1119-1124
33.En-QingGao‚Yan-FengYue‚Shi-QiangBai‚ZhengHe‚andChun-HuaYan‚“FromAchiralLigandstoChiralCoordinationPolymers:SpontaneousResolution‚WeakFerromagnetismandTopologicalFerrimagnetism”‚J.Am.Chem.Soc.2004‚126(4)‚1419-1429.
34.En-QingGao‚Yan-FengYue‚Shi-QiangBai‚ZhengHe‚andChun-HuaYan“Newtwo-dimensionalmanganese(II)-azidopolymerswithbidentatecoligands:structureandmagneticproperties”‚Chem.Mater.2004‚16(8)‚1590-1596.
35.En-QingGao‚Yan-XiaXu‚Chun-HuaYan‚Twosquaregridcoordinationpolymerswithmanganese(II)and1‚4-Bis(imidazole-1-ylmethyl)benzene‚CrystEngComm‚2004‚6(52)‚298-302.
36.Yan-FengYue‚En-QingGao*ZhengHe‚Shi-QiangBai‚Chun-HuaYan*‚‘High-dimensionalazido-bridgedcadmium(II)polymericcomplexeswithbis(bidentate)diazineligands’‚CrystEngComm‚2004‚6(89)‚549-555.
37.En-QingGao‚Shi-QiangBai‚Zhe-MingWang‚Chun-HuaYan.“Two-dimesionalhomochiralmanganese(II)-azidoframeworksincorporatinganachiralligand:partialspontaneousresolutionandweakferromagnetism”J.Am.Chem.Soc.‚2003‚125(17)‚4984-4985.
38.En-QingGao‚Zhe-MingWang‚Chun-HuaYan."FromManganese(II)-AzidoLayerstoaNovelThree-DimensionalMolecularMagnet:SpinCantingandMetamagnetism"‚Chem.Commun.2003‚(14)‚1748-1749.
39.En-QingGao‚Shi-QiangBai‚Feng-YanYue‚Zhe-MingWang‚Chun-HuaYan."Newone-dimensionalazido-bridgedmanganese(II)coordinationpolymersexhibitingalternatingferromagnetic-antiferromagneticinteractions:structuralandmagneticstudies"‚Inorg.Chem.2003‚42(11)‚3642-3649.
40.En-QingGao‚Shi-QiangBai‚Chuan-FengWang‚Zhe-MingWang‚Chun-HuaYan."structuralandmagneticpropertiesofthreeone-dimensionalazido-bridgedcopper(II)andmanganese(II)coordinationpolymers"‚Inorg.Chem.2003‚42(25)‚8456-8464.
41.En-QingGao‚Shi-QiangBai‚Zhe-MingWang‚Chun-HuaYan.“Newone-andtwo-dimensionalmetal-dicyanamidocomplexeswithaflexiblebridgingco-ligand:structuralandmagneticproperties”DaltonTrans.2003(9)‚1759-1764.