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内蒙古大学化学化工学院研究生导师简介- 刘志亮

内蒙古大学 /2014-07-07

 主 要 简 历:

 刘志亮   博士,教授
 
1999.09-2002.07
 南开大学, 博士
 
2002.07-2004.06
 中国科学院化学研究所,博士后 
 
2004.07-2005.12
 荷兰Leiden大学,博士后; Sappi公司研发部研究员
 
2006.01---至 今
 内蒙古大学化学化工学院,教授;材料物理与化学专业硕士生导师,学科负责人
 
通信地址:
 内蒙古呼和浩特大学西路235号 010021
 
内蒙古大学化学化工学院
 
 
办 公 室:
 化学南楼204
 
实 验 室:
 化学楼304、308
 
电话(传真):
 0086-0471-4995414
 
E-mail:
 cezlliu@imu.edu.cn
 
 
  
 
讲授课程: 
 
1. 无机合成与制备化学(本科生)
 
2. 生物材料概论(本科生)
 
3. 新型功能材料(研究生)
 
研究方向: 分子磁体;功能配位聚合物
 
1. 分子磁体的构筑与性能研究: 
 
建立和发展磁分子固体材料的合成与制备新方法,研究和揭示磁分子固体材料的分子/晶体结构。深入了解结构-磁性的关联性,并以此为指导设计合成新型分子磁体。研究思路:(1)遵循逆向而行的原则,设计、合成磁功能分子。运用自组装技术,研制功能有序分子体系(薄膜和晶体),得到新型磁功能分子材料。(2)在分子水平上研究分子(自旋)之间的相互作用、结构-性能关系以及有序体系的构造规律。
 
2. 功能配位聚合物的设计、合成及性能研究
 
设计合成具有类沸石(zeolite-like)微孔结构的金属-有机网格状结构配位聚合物(metal-organic frameworks, MOFs),在深入了解其结构的基础上,探索这类材料在气体吸附与分离、磁性、荧光、非线性光学、催化等方面的性能。
 
 
 
 
 
研究项目: 
 
(1)“手性MOFs结构配位聚合物的设计、合成及其在不对称催化中的应用”国家自然科学基金项目: [批准号:21061009];2011年1月-2013年12 月
 
(2)“光磁功能分子材料的组装及其磁性调控” 内蒙古自治区自然科学基金项目: [批准号:2010MS0201];2010年1月-2012年12 月
 
(3)“多元异自旋磁耦合体系的组装及其磁性研究”国家自然科学基金项目: [批准号:20761004];2008年1月-2010年12 月
 
(4)“环氧树脂EPON828的绿色合成途径研究”, 教育部春晖计划,2010年1月-2011年12月
 
(5) 中国高等教育学会 “十一五”教育科学研究规划重点研究课题[批准号:06AIL0670265];2006 年 9 月至2009 年 8 月
 
(6)“分子固体材料及其磁相关性质”子课题—“手性单分子磁体研究”负责人, 国家自然科学基金重大项目[批准号:20391001];2004年1月-2007年12 月
 
(7)“功能材料的有序组装及性能研究”, 内蒙古大学纳米功能材料实验室启动基金 [批准号:10013-121008];2006年12月-2010年12月
 
(8)“新型信息存储材料的分子组装及其磁性研究”, 内蒙古自治区高等学校科学研究项目[批准号:NJ06046];2007年1月-2008年12月
 
(9)“手性单分子磁体的合成与结构”, 内蒙古大学513人才基金[批准号:206075];2006年1月-2008年12月
 
(10)“手性单分子磁体的磁性研究”, 内蒙古大学高层次人才引进基金[批准号:206050];2006年1月-2008年12月 
 
(11)“新型异自旋磁耦合体系的组装与磁性研究”,教育部科学技术研究重点项目,2006 年 9 月至2009 年 8 月
 
(12)The Netherlands technology foundation (STW) in the priority program materials.
 
(13)The program from South Africa Pulp & Paper Industry, Netherlands Services.
 
获奖情况: 中国科学院K. C. Wang优秀博士后奖(2002年)
 
内蒙古大学青年骨干教师奖(2008年)
 
出版专著:
 
刘彩明, 刘志亮, 张德清, 朱道本, 第二章 分子磁体的研究进展,《功能材料化学进展》(化学进展丛书),朱道本 主编,化学工业出版社,北京, 2005年, PP69-112.
 
 
 
 
 
近期发表文章: 
 
1. Yajie Gao, Yufei Ji, Shuai Ding, Zhiliang Liu,* and Jinkui Tang*
 
Syntheses, Crystal Structures and Magnetic Properties of "-O/"-Cl Bridged Dinuclear MnII and CuII Complexes with Schiff base Ligand HL [HL = 2- (benzothiazol-2-yl-hydrazonomethyl) -6-methoxyphenol], Z. Anorg. Allg. Chem. 2011, In press (SCI收录)
 
2. Lei Yan, Shuai Ding, Yufei Ji, Zhiliang Liu*, Caiming Liu*
 
Crystal structure and magnetic properties of two dinuclear iron(III) complexes with multidentate Schiff-base ligands, J. Coord. Chem., 2011, In press (SCI收录)
 
3. Xuebin Xu, Lang Zhao, Gong-Feng Xu, Yun-Nan Guo, Jinkui Tang* and Zhiliang Liu*
 
A diabolo-shaped Dy9 cluster: synthesis, crystal structure and magnetic properties,Dalton Trans., 2011, 40, 6440-6444(SCI收录)
 
4. Yajie Gao, , Lang Zhao, , Xuebin, Gong-Feng Xu , Yun-Nan Guo, Jinkui Tang, Zhiliang Liu
 
Heterometallic Cubanes: Syntheses, Structures, and Magnetic Properties of Lanthanide(III)-Nickel(II) Architectures, Inorg. Chem., 2011,50(4)1304-1308(SCI收录)
 
5.0Shuai Ding, Congjun Xia, Yufei Ji, Zhiliang Liu* and Yong Ding
 
Bis[(2-pyridyl)(2-pyridylamino)-methanolato]manganese(III) nitrate, Acta Crystallographica Section E, (2011). E67, m622–m623 (SCI收录)
 
6. Xuebin Xu, Shuai Ding, Si Shen, Jinkui Tang and Zhiliang Liu*
 
Bis(l-2-{[2-(1,3-benzothiazol-2-yl)-hydrazinylidene]methyl}-6-methoxyphenolato)bis[dinitratodysprosium(III)] methanol disolvate, Acta Crystallographica Section E, (2011). E67, m796–m797 (SCI收录)
 
7. Shengli Liang, Zhiliang Liu*, Naren Liu, Caiming Liu, Xiawei Di, Jun Zhang Structural determinations and magnetic studies of two new binuclear complexes: azido-bridged Ni(II) dimmer and di-(m-hydroxo)-bridged Cr(III) dimmer, J. Coord. Chem., 2010, 63, 3441-3452 (SCI收录)
 
8. Yajie Gao, Gong-Feng Xu, Lang Zhao, Jinkui Tang* and Zhiliang Liu*,Observation of Slow Magnetic Relaxation in Discrete Dysprosium Cubane,Inorg. Chem., 2009, 48, 11495–11497
 
9. Zhiliang Liu*, Weihua Han, Caiming Liu, Xiaowei Di, Jun Zhang, Deqing Zhang,In Situ Self-Assembly of 1D Copper(II) Coordination Polymer Containing EO Azide and Phenolate Bridges,Bull. Chem. Soc. Jpn. 2009, 82(5), 582–584 (SCI收录)
 
10. Shengli Liang, Zhiliang Liu*, Caiming Liu, Xiaowei Di, Jun Zhang, and Deqing Zhang,Synthesis, Crystal Structure and Magnetic Properties of a New 3D Framework Coordination Polymer,Z. Anorg. Allg. Chem. 2009, 635, 549-553 (SCI收录)
 
11. Naren Liu, Shengli Liang, Weihua Han, Zhiliang Liu*,Synthesis, Crystal Structure and Magnetic Properties of a New 2D Coordination Polymer [Cu2(anol)2(µ1,3-N3)2]n,Chinese J Inorg. Chem., 2009,25(10)1858-1863 (SCI收录)
 
12. 韩纬华,梁胜利,刘娜仁,刘志亮*,Zig-Zag链状配位聚合物{[Cu (L)(4,4′-bpy)]•ClO4}n的合成、晶体结构及磁性,南开大学学报(自然科学版),2009,42(2)29-34
 
13. Jun Zhang, Eerdemutu, Chengxu Yang, Jianyong Feng, Xiaowei Di, Zhiliang Liu. and Gang Xu, “Size and Shape Controlled Synthesis of Monodisperse Vanadium Dioxide Nanocrystals”, Journal of Nanoscience and Nanotechnology, 2010, 10, 2092-2098. ( SCI收录)
 
14. Jun Zhang, Ying Jin, Changyan Li, Yuenian Shen, Li Han, Zhongxue Hu, Xiaowei Di, Zhiliang Liu, “Creation of Three Dimensionally Ordered Macroporous Au/CeO2 Catalysts with Controlled Pore Sizes and Their Enhanced Catalytic Performance for Formaldehyde Oxidation”, Applied Catalysis B: Environmental, 2009, 91, 11.(SCI收录)
 
15. Zhiliang Liu *, Shengli Liang, Xiaowei Di, Jun Zhang,A manganese(III) complex that exhibits spin crossover behavior,Inorg. Chem. Commun. 2008, 11, 783–786
 
16. Jun Zhang, Qian Li, Xiaowei Di, Zhiliang Liu, Gang Xu, “Layer-by-layer Assembly of Multicolored Semiconductor Quantum Dots towards Efficient Blue, Green, Red and Full Color Optical Films”, Nanotechnology. 2008, 19, 435606. (SCI收录)
 
17. Zhiliang Liu, Huub Kooijman, Anthony L. Spek, Elisabeth Bouwman,New manganese-based catalyst systems for alkyd paint drying,Progress in Organic Coatings, 2007, 60 343–349
 
18. Jun Zhang, Xiaowei Di, Zhiliang Liu, Gang Xu, Shengming Xu, Xingping Zhou, “Multicolored Luminescent CdS Nanocrystals”, Transactions of Nonferrous Metal Society of China, 2007, 17, 1367. (SCI收录)
 
19.Zhengliang Lu,Xinyi Wang, Zhiliang Liu, Fuhui Liao, Song Gao, Rengen Xiong, Hongwei Ma, Deqing Zhang, and Daoben Zhu,Tuning the Magnetic Behavior via Dehydration/Hydration Treatment of a New Ferrimagnet with the Composition of K0.2Mn1.4Cr(CN)6·6H2O,Inorg. Chem. 2006, 45 (3): 999-1004. (SCI收录)
 
20. Zhi-Liang Liu, Li-Cun Li, Dai-Zheng Liao, Zong-Hui Jiang, Shi-Ping Yan,Oxamido–bridged dimetallic complexes involving nitronyl nitroxide radical ligands: Crystal structure and magnetic behaviour,Crystal Growth & Design, 2005, 5(2), 783-787. (SCI收录)
 
21. Lu Zhengliang, Liu Zhiliang, Zhang Deqing,Tris(2,2 '-bioxazoline-kappa N-2,N ')-copper(II) diperchlorate and tris(2,2 '-bioxazoline-kappa N-2,N ') nickel(II) diperchlorate,Acta crystallographica section C-Crystal Structure Commun, 2005, 61(3) 147-150. (SCI收录)
 
22.  Liu Caiming, Gao Song, Zhang Deqing, Liu Zhiliang, Zhu Daoben,Solvothermal synthesis, crystal structure and magnetic property of a new dinuclear manganese(II)-azido complex: [Mn(2,2 '-dpa)(N-3)(2)](2) (2,2 '-dpa=2,2 '-dipicolylamine),Inorg. Chim. Acta. 2005, 358 (3): 834-838. (SCI收录)
 
23. Zhiliang Liu, Zhengliang Lü, Deqing Zhang, Zonghui Jiang, Licun Li, Caiming Liu, and Daoben Zhu,New Type of Heterospin Complexes Assembled from trans Oxamido-Bridged Copper(II) Binuclear Units and Nitronyl Nitroxide Radicals: Crystal Structure and Magnetic Characterization,Inorg. Chem. 2004, 43 (21): 6620-6627. (SCI收录)
 
24.  Zhiliang Liu, Deqing Zhang, Caiming Liu, Daoben Zhu,An novel 1D ladder coordination polymer [Eu(dipic)1.5(H2O)4·3H2O]¥,Chem. Lett.  2004, 33(2), 180. (SCI收录)
 
25.  Zhiliang Liu, Deqing Zhang, Jianlin Luo, Zonghui Jiang, Daizheng Liao, Daoben Zhu,A Novel Heterospin Tetranuclear MnIICuII3-Type Complex Incorporating Macrocyclic Oxamide [Mn(CuL)3](ClO4)2: Synthesis, Crystal Structure and Magnetic Properties,J. Coord. Chem. 2004, 57 (8): 647-655. (SCI收录)
26.  Zhiliang Liu, Deqing Zhang, Hongmei Wang, Daoben Zhu,A novel supramolecular assembly of nitronyl nitroxides with ladder framework: crystal structure and magnetic property,Journal De Physique, 2004, 114: 655-657. (SCI收录)
 
27.  Hongmei Wang, Zhiliang Liu, Caiming Liu, Deqing Zhang, Zhengliang Lü, Daoben Zhu,New Coordination Complexes of 2-(4-Quinolyl)nitronyl Nitroxide with M(hfac)2 [M = Mn(II), Co(II), and Cu(II)]:  Syntheses, Crystal Structures and Magnetic Characterization,Inorg. Chem. 2004, 43 (13): 4091-4098. (SCI收录)
 
28. Caiming Liu, Song Gao, Deqing Zhang, Rengeng Xiong, Zhiliang Liu, Daoben Zhu,A unique three-dimensional alternation ferro- and antiferromagnetic manganese-azide system with threefold interpenetration (10, 3)-a nets,Angew. Chem. Int. Ed. 2004, 43, 990. (SCI收录)
 
29. Guo XF, Zhou YC, Zhang DQ, Bing Y, Liu ZL, Liu CM, Lu ZL, Huang YH, Zhu DB,7-trifluoromethylquinoline-functionalized luminescent photochromic spiropyran with the stable merocyanine species both in solution and in the solid state,J. Org. Chem , 2004, 69,  (25): 8924-8931. (SCI收录)
 
30.  Liu Zhi-Liang, Li Li-Cun, Zhang Lei, et al. A novel heterospin polynuclear complex containing both macrocyclic and imino nitroxide radical ligands: {[CuL(H2O)](CuL)-Mn(IM-2Py)}{[CuL(MeOH)](CuL) -Mn(IM-2Py)}(ClO4)4 MeOH,New J. Chem. , 2003, 27 (3): 583-587. (SCI收录)
 
31.  Liu Zhi-Liang, Li Li-Cun, Liao Dai-Zheng, et al.,Exchange interaction of a novel heterospin polynuclear complex containing transition metals and imino nitroxide radicals: {[(CuL)Ni(IM-2Py)2] (ClO4)2}2 2H2O,Chinese J. Chem. , 2003, 21 (2): 133-138. (SCI收录)
 
32.   Zhang Cheng-Xi, Liu Zhi-Liang, Liao Dai-Zheng.,Synthesis, crystal structure and magnetic properties of a novel complex [Cu(NIT2Py)(PDA)(H2O)]center dot(CH3OH)(H2O),J. Mol. Struct. , 2003, 650 (1-3): 21-26. (SCI收录)
 
33.   Wang Li-Ya, Liu Zhi-Liang, Liao Dai-Zheng.,Synthesis, structure and magnetic behavior of a novel 1-D chain tethered by nickel(II)-4-pyridyl-substituted nitronyl nitroxide radical complex and TCB,Inorg. Chem. Commun. , 2003, 6 (6): 630-633. (SCI收录)
 
34.   Li Li-Cun, Liu Zhi-Liang, Turner S,,The first one-dimensional copper(II)-radical system with alternating double end-on and end-to-end azido bridges,New J. Chem. , 2003, 27 (4): 752-755. (SCI收录)
 
35. Li Li-Cun, Liu Zhi-Liang, Turner S, Unique magnetic behavior in a one-dimensional coordination polymer [Co(tmpyim)(2)(tp)],Eur. J. Inorg. Chem. , 2003, (1): 62-65. (SCI收录)
 
36. Wang Li-Ya, Liu Zhi-Liang, Liao Dai-Zheng, Synthesis, structure and magnetic behavior of a novel Manganese(II)-nitronyl nitroxide-azido(m1, 1 and m1, 3) one-dimensional complex,Science In China (Series B), 2003, 46(6): 533-541. (SCI收录)
 
37. Liu Zhi-Liang, Liao Dai-Zheng, Jiang Zong-Hui, Progress of research on magnetic coupling system including nitronyl nitroxide radicals,Chemical Journal of Chinese University , 2002, 23(5): 843-848. (SCI收录)
 
38.  Liu Zhi-Liang, Zhao Qi-Hua, Li Shu-Qi, et al. Structure and magnetic properties of ferrimagnetic chain formed by manganese(II) and nitronyl nitroxides,Inorg. Chem, Commun. , 2001, 4 (6): 322-325. (SCI收录)
 
39.  Liu Zhi-Liang, ZHAO Bin, JIANG Zong-Hui, YAN Shi-Ping, Synthesis, Crystal Structure and Quantum Chemistry Calculation of 2-(2-benzimidazlyl)-4,4,5,5-tetramethyl- 4,5-dihydro-1H-imidazolyl-3-oxide-1-oxy,Chemical Journal of Chinese University , 2001, 22(4): 5-8. (SCI收录)
 
40. Zhang L, Liu ZL, Weng LH, Crystal structure, magnetic exchange interaction, and DFT study of 2,2 -(1-oxidopyridine-2,6-diyl)bis[4,5-dihydro-4,4,5,5-tetramethyl-3-oxido-1H-imidazol-1-oxyl] hydrate,Helv. Chim. Acta, 2001,  84 (4): 834-841. (SCI收录)
 
41.   Zhao QH, Fang RB, Sun BW, Liu ZL, Synthesis, characterization and magnetic properties of metal pentafluoropropionates complexes with an alkyl nitronyl nitroxide biradical,Pol. J. Chem. , 2000, 74 (12): 1797-1801. (SCI收录)
 
 
 
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