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内蒙古大学化学化工学院研究生导师简介- 张浩

内蒙古大学 /2014-07-07

 张浩,教授,博士生导师。

 
2009-现在            内蒙古大学,教授。
 
2006,8-2009          日本理化学研究所,协力研究员
 
2004,5-2006,7        日本学术振兴会(JSPS)博士后 日本奈良先端科学技术大学院大学
 
2000,12-2004,1       博士 华东理工大学(专业:应用化学)
 
1997,9-2000,7        硕士 内蒙古工业大学(专业:化学工艺)
 
 
 
通信地址:中国 内蒙古  呼和浩特市大学西路235号 内蒙古大学化学化工学院 
 
办公室:内蒙古大学化学化工学院南楼317室
 
实验室:化学楼 511
 
电话: 86-0471-4993227
 
传真: 86-0471-4993227
 
E-mail: zh_hjf@hotmail.com;haozhang@imu.edu.cn
 
 
 
教学工作: 主要承担了化学化工学院本科生的《有机化学一》、《有机化学二》和硕士研究生《金属有机化学》课程。
 
 
 
研究方向: 
 
1.  烯烃聚合、开环移位聚合导向的金属有机化学
 
2.  金属有机导向的有机合成方法学
 
 
 
近期发表文章:
 
 
 
1) Hao Zhang, Yunjie Luo, Zhaomin Hou* 
 
“Scandium-Catalyzed Syndiospecific Copolymerization of Styrene with Isoprene” 
 
 Macromolecules 2008, 41, 1064-1066.
 
 
 
2) Hao Zhang, Shohei Katao, Kotohiro Nomura*, Jiling Huang* 
 
“Synthesis of Nonbridged hlaf-titanocenes containing phenoxy-imine ligands and their use in catalysis for olefin polymerization”. 
 
Organometallics 2007, 26, 5967-5977. 
 
 
 
3) Hao Zhang, Doo-Jin Byun, and Kotohiro Nomura*
 
“Tuning the active species from syndiospecific styrene polymerisation to ethylene/styrene copolymerisation by (aryloxo)(cyclopentadienyl)titanium complexes - MAO catalysts” 
 
Dalton Trans. 2007, 18. 1802-1806.(cover article).
 
 
 
4) Hao Zhang, Kotohiro Nomura*
 
“Ligand effect in syndiospecific styrene polymerization and ethylene/styrene copolymerization by some nonbridged half-titanocenes containing anionic donor ligands”
 
Studies in Surface Science and Catalysis, 2006,161, 145-152.
 
 
 
5) Hao Zhang, Kotohiro Nomura*
 
Living Copolymerization of Ethylene with Styrene Catalyzed by (Cyclopentadienyl)(ketimide) titanium(IV) Complex - MAO Catalyst System: Effect of Anionic Ancillary Donor Ligand” 
 
Macromolecules 2006, 39, 5266-5274.
 
 
 
6) Hao Zhang, Kotohiro Nomura*
 
“Living Copolymerization of Ethylene with Styrene Catalyzed by (Cyclopentadienyl)(ketimide) titanium(IV) Complex - MAO Catalyst System” 
 
J. Am. Chem. Soc. 2005, 127, 9364-9365.SCI, 
 
 
 
7) Kotohiro Nomura,* Hao Zhang, and Doo-Jin Byun
 
“Factors Affecting Product Distributions in Ethylene/Styrene Copolymerization by (Aryloxo)(cyclopentadienyl)titanium Complexes - MAO Catalyst Systems”
 
J. Polym. Sci. PartA: Polym. Chem., , 2008, 46, 4162-4174.
 
 
 
8) Hao Zhang, Jun Ma, Yanlong Qian, Jiling Huang*
 
“Synthesis and Characterization of Cyclopentadienylchromium Complex Bearing Pendant Pyridine Group as Catalyst for Ethylene Polymerization” 
 
Organometallics. 2004, 23, 5681-5688.
 
 
 
9) Xueqin Sun, Jun Xie, Hao Zhang, Jiling Huang*
 
“Various silyl-substituted cyclopentadienyl titanium complexes [CpSi(CH3)2X]TiCl3 as catalysts for syndiotactic polystyrene” 
 
Eur. Polym. J. 2004, 40, 1903-1908. 
 
 
 
10) Yanlong Qian*, Hao Zhang, Junxia Zhou, Wei Zhao, Xueqin Sun, Jiling Huang*
 
“Synthesis and polymerization behavior of various substituted half-sandwich titanium complexes Cp´TiCl2(OR*) as catalysts for syndiotactic polystyrene” 
 
J. Mol. Catal. A: Chem. 2004, 208(1-2), 45-54.
 
 
 
11) Yanlong Qian*, Jiling Huang, Muhammad D.Bala, BingLian, Hao Zhang, Hao Zhang
 
“Synthesis, Structures, and Catalytic Reactions of Ring-Substituted Titanium(IV) Complexes”,  
 
Chem. Rev. 2003, 103 (7), 2633-2690. 
 
 
 
12) Quanling Suo*, Hao Zhang, Yibing Wang, Li Wang, Linhong Wen, Xuebing Leng 
 
“Synthesis and structural characterization of {μ3-H(Ph)C=C}FeCo2(CO)7dppm(dppm=Ph2PCH2PPh2) and {μ3-H(Ph)C=C}FeCo2(CO)9-nLn [L=PPh3(n=1,2),AsPh3(n=1)]”
 
J. Organomet. Chem. 2001, 63, 87-93.
 
 
 
13) Yanlong Qian*, Hao Zhang, Jiling Huang,
 
“Synthesis and Characterization of Cyclopentadienylchromium Complexes Bearing Pendant o-Me2N-C6H4-C(CH3)(CH3)- Group as Catalysts for Ethylene Polymerization”
 
Chinese Journal of Catalysis 2003, 21(7), 487-488.
 
 
 
14) Quanling Suo*, Hao Zhang, Yibing Wang, Jiehui Yan, Liming Han, Linghong Weng, Xuebing Leng 
 
“Synthesis and Molecular Structure of Substituted Derivatives of the Mixed-metal Carbonyl Clusters Bearing µ3-vinylidene Moiety” 
 
Chinese Journal of Inorganic Chemistry 2003, 19(5), 506-508.
 
 
 
15) Hao Zhang, Jiling Huang, Yanlong Qian*,  
 
“Progress in Synthesis of Chromium Catalysts and Their Application in Olefin Polymerization” 
 
Chinese Journal of Organic Chemistry 2003, 22(12), 981-989.
 
 
 
16) Hao Zhang, Quanling Suo*, Yibing Wang, LiWang, Linghong Weng,, Xuebing Leng
 
 “Synthesis and Crystal Structure of (μ3-S)FeCo2(CO)7dppfe”
 
Acta Phys.-Chim. Sin. 2002, 18(8), 746-749.
 
 
 
Manuscripts in preparation (tentative title)
 
 
 
17) Hao Zhang, Jun Ma, Yanlong Qian, Jiling Huang, 
 
“Synthesis and Characterization of Cyclopentadienylchromium Complex Bearing Pendant Furan Group as Catalyst for Olefin Polymerization” 
 
(To be submitted J. Organomet. Chem.)
 
 
 
Conferences attended
 
1) K. Nomura, H. Zhang, D.-J. Byun, K. Fujita, M. Fujiki,
 
“Syndiospecific styrene polymerization and ethylene/styrene copolymerization catalyzed by Nonbridged half-titanocenes - MAO catalyst systems ”
 
34th Petrochemical Symposium, The Japan Petroleum Institute, D37, November 2004,
 
Matsuyama, Japan(Oral contribution by Z.H.).
 
2) K. Nomura, K. Itagaki, H. Zhang
 
“Precise ethylene copolymerizations catalyzed by half-titanocenes containing anionic ancillary donor ligand”
 
16th International Symposium on Olefin Metathesis and Related Chemistry, August,2005, Poznań, Poland, (Oral contribution by K.N.).
 
 
 
3) H. Zhang, K. Nomura
 
“Effect of anionic ancillary donor ligand in ethylene-styrene copolymerization catalyzed by nonbridged half-titanocenes Cp*TiCl2(L). ”
 
96th Symposium in Catalysis Society of Japan, 4K18,September,2005,Kumamoto, Japan (Oral contribution by Z.H.).
 
 
 
4) H. Zhang, K. Nomura, J. Huang
 
“Effect of anionic ancillary donor ligand in ethylene copolymerization catalyzed by nonbridged half-titanocenes”
 
Asian Polyolefin Workshop 2005, December 2005 Nara, Japan (Oral contribution by Z.H).
 
 
 
5) H. Zhang, K. Nomura
 
“Effect of anionic ancillary donor ligand in ethylene-styrene copolymerization catalyzed by nonbridged half-titanocenes”
 
Pacifichem 2005, Organometallic Chemistry of Early Transition Metals and Lanthanides (#51), December, 2005, Hawaii, USA (Poster presentation by Z.H.).
 
 
 
6) Yibing Wang, Hao Zhang, Wu Ren, Quanling Suo*, Linhong Wen, Xuebing Leng 
 
“Synthesis and crystal structure of  {μ3-H(Ph)C=C}FeCo2(CO)7dppe (dppe= Ph2PCH2CH2PPh2) and (μ3-S)FeCo2(CO)7dppfe”
 
The 11th International symposium of Fine Chemistry and Functional Polymers (FCFD-XI), July 28-31(2001), Hailar, Inner Mongolia, P. R. China (p192-193).
 
 
 
7) Yibing Wang, Hao Zhang, Quanling Suo*, Linhong Wen.
 
“Synthesis and crystal structure of hetero-nuclear FeCo2 cluster”
 
The 4th Symposium of Coordination Chemistry of China, Oct. 23-26(2001), Guilin, Guangxi, P. R. China (p239).
 
 
 
Patent
 
1).黄吉玲*,张浩,马俊,钱延龙“侧链含吡啶基茂基金属铬化合物制备方法和用途”,中国专利,专利申请号:200310109170.5.
 
2). 黄吉玲*,陈伟,张浩,郑刚,钱延龙,徐歆,刘东兵,邱波“侧基含杂原子的茂金属铬催化剂、其制备方法和用途”,中国专利,专利申请号:200310115036.6.
 
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