肖义
院系：精细化工国家重点实验室
办公电话：**
电子信箱：xiaoyi@dlut.edu.cn
更新时间：2013-9-5
其他专业：★精细化工



个人简介
1992, 09-1996, 07,天津大学应用化学系精细化工专业, 本科生;
1996, 09-1999, 03,天津大学化工学院精细化工专业, 硕士生;
1999, 03-2003, 02,大连理工大学精细化工系应用化学专业, 博士生；
2003, 03-2004, 01, 日本国立产业技术综合研究所博士后研究员；
2004, 01 -2005, 05， 大连理工大学精细化工系，讲师;
2005, 06 - 2009,12， 大连理工大学精细化工系，副教授;
2009,12 至今 大连理工大学精细化工国家重点实验室，教授;

课题组网站 http://finechem.dlut.edu.cn/xiaoyi/

研究领域（研究课题）
详见课题组网站 http://finechem.dlut.edu.cn/xiaoyi/fields.html

肖义教授领导的课题组主要从事荧光染料、分子探针、有机光电功能材料等方面的研究工作。旨在设计合成结构新颖、高效、多功能荧光发色团；开发高灵敏度、高选择性、具有生物学实用性的分子探针；应用荧光发色团开发高效电致发光、有机固体染料激光器、有机半导体等功能材料(主要包括有机薄膜太阳能电池材料有机场效应晶体管材料)。

承担项目

1）负责人：肖义。项目名称：结构新颖的有机氟硼配合物类强荧光发色团家族的创制于发光性能研究；国家自然科学基金(**)。经费35万。
2）负责人：肖义。项目名称：苊并吡咯类新杂环及其芳香氢亲核取代反应：长波长荧光探针的开发与生物学应用；国家自然科学基金(**)。经费26万。
3）负责人：肖义。项目名称：萘酰亚胺通过键光诱导电子转移荧光分子开关的创制；国家自然科学基金(**)。经费23万。
4）负责人：钱旭红。排序：钱旭红、杨青、肖义、徐玉芳、徐晓勇 等。项目名称：色素衍生的生物客体探针与药物先导；国家自然科学基金重点项目(**)。总经费180万，个人承担38万。
5）负责人：肖义。2008年度“教育部新世纪优秀人才支持计划”，经费50万。


硕博研究方向
详见课题组网站 http://finechem.dlut.edu.cn/xiaoyi/fields.html

在精细化工、应用化学专业招生。


荧光染料与荧光分子探针
分子与聚合物有机半导体材料与器件
光电转换功能性色素

欢迎有志向的青年来一起拼搏奋斗!

非常愿意招收具有半导体器件物理背景的青年学子来攻读博士学位, 或担任师资博士后, 招收科研助手.

出版著作和论文
详见课题组网站 http://finechem.dlut.edu.cn/xiaoyi/publications.html


41.Regioselective Photocyclization To Prepare Multifunctional Blocks for Ladder-Conjugated Materials
Zhenbo Zhao, Youdi Zhang, and Yi Xiao*
J. Org. Chem., 2013, 78 (11), pp 5544–5549
DOI: 10.1021/jo400619u

40.Synthesis of tetraalkyl naphthalene bisanhydride and its model condensations with amines
Kai Xiong, Yi Xiao*
Tetrahedron Letters Volume 54, Issue 24, 12 June 2013, Pages 3171–3175

39.From a BODIPY–rhodamine scaffold to a ratiometric fluorescent probe for nitric oxide
Haibo Yu, Liji Jin,* Yong Dai,* Huaqiang Li and Yi Xiao*
New J. Chem., 2013,37, 1688-1691
DOI: 10.1039/C3NJ41127C

38.Activatable Rotor for Quantifying Lysosomal Viscosity in Living Cells
Lu Wang, Yi Xiao*, Wenming Tian, and Liezheng Deng
J. Am. Chem. Soc., 2013, 135 (8), pp 2903–2906
DOI: 10.1021/ja311688g

37.MODULATION OF FRET THROUGH THE SPECTRAL-OVERLAP STRATEGY
Haibo Yu, Yi Xiao*
Journal of Innovative Optical Health Sciences Volume 05, Issue 03, July 2012

36.meso-Alkoxy BODIPYs with a good balance between larger Stokes shifts and higher fluorescence quantum yields
Lu Wang,Yuhui Zhang andYi Xiao*
RSC Adv., 2013,3, 2203-2206
DOI: 10.1039/C2RA21920D

35.N-type organic semiconductor bisazacoronene diimides efficiently synthesized by a new type of photocyclization involving a Schiff base
Youdi Zhang, Zhenbo Zhao, Xiaomei Huang, Yuanpeng Xie, Chenxi Liu, Jun Li, Xin Guan,Kaichen Zhang, Chuanhui Cheng* and Yi Xiao*
RSC Adv., 2012,2, 12644-12647
DOI: 10.1039/C2RA22488G

34.Synthesis and Optical and Redox Properties of Symmetric and Asymmetric BODIPYs
Inmaculada García-Moreno, Lu Wang, Angel Costela1, Jorge Bauelos*, Iigo López Arbeloa, Yi Xiao*
ChemPhysChem Volume 13, Issue 17, pages 3923–3931, December 7, 2012
DOI: 10.1002/cphc.**

33.A Lysosome-Targetable and Two-Photon Fluorescent Probe for Monitoring Endogenous and Exogenous Nitric Oxide in Living Cells
Yu, Haibo, Xiao, Yi*, Jin, Liji
J. Am. Chem. Soc., 2012, 134 (42), pp 17486–17489
DOI: 10.1021/ja308967u

32.From Spirolactam Mixtures to Regioisomerically Pure 5- and 6-Rhodamines: A Chemodosimeter-Inspired Strategy
Haibo Yu , Yi Xiao *, and Haiying Guo
Org. Lett., 2012, 14 (8), pp 2014–2017
DOI: 10.1021/ol300523m

31.Fusing three perylenebisimide branches and a truxene core into a star-shaped chromophore with strong two-photon excited fluorescence and high photostability
Yuanpeng Xie, Xinfu Zhang, Yi Xiao*, Youdi Zhang, Fan Zhou, Jing Qib and Junle Qu*
Chem. Commun., 2012,48, 4338-4340
DOI: 10.1039/C2CC31261A
Received 20 Feb 2012, Accepted 07 Mar 2012
First published online 08 Mar 2012

30.Replacing Phenyl Ring with Thiophene: An Approach to Longer Wavelength Aza-dipyrromethene Boron Difluoride (Aza-BODIPY) Dyes
Xinfu Zhang, Haibo Yu, and Yi Xiao*
J. Org. Chem., 2012, 77 (1), pp 669–673
DOI: 10.1021/jo201413b
Publication Date (Web): November 23, 2011

29.Soluble Ladder Conjugated Polymer Composed of Perylenediimides and Thieno[3,2-thiophene (LCPT): A Highly Efficient Synthesis via Photocyclization with the Sunlight
Zhongyi Yuan, Yi Xiao*, Yang Yang and Tao Xiong
Macromolecules, 2011, 44 (7), pp 1788–1791
DOI: 10.1021/ma**
Publication Date (Web): March 4, 2011

28.Convenient and Efficient FRET Platform Featuring a Rigid Biphenyl Spacer between Rhodamine and BODIPY: Transformation of ‘Turn-On’ Sensors into Ratiometric Ones with Dual Emission
Haibo Yu, Yi Xiao*, Haiying Guo, Xuhong Qian*
Chemistry - A European Journal
Volume 17, Issue 11, pages 3179–3191, March 7, 2011
Article first published online: 10 FEB 2011
DOI: 10.1002/chem.**

27.Fused perylenebisimide–carbazole: new ladder chromophoreswith enhanced third-order nonlinear optical activities
Yang Yang, Yaochuan Wang, Yuanpeng Xie, Tao Xiong, Zhongyi Yuan, Youdi Zhang, Shixiong Qian and Yi Xiao*
Chem. Commun., 2011,47, 10749-10751
DOI: 10.1039/C1CC14071J
Received 07 Jul 2011, Accepted 15 Aug 2011
First published online 25 Aug 2011

26.Unprecedented laser action from energy transfer in multichromophoricBODIPYcassettes
Yi Xiao*, Dakui Zhang, Xuhong Qian*, Angel Costela, Inmaculada Garcia-Moreno*, Virginia Martin, M. Eugenia Perez-Ojeda, Jorge Bauelos*, Leire Gartziad and Iigo López Arbeload
Chem. Commun., 2011,47, 11513-11515
DOI: 10.1039/C1CC13874J
Received 29 Jun 2011, Accepted 01 Sep 2011
First published online 20 Sep 2011

25.Development of excellent long-wavelength BODIPY laser dyes with a strategy that combines extending π-conjugation and tuning ICT effect
Dakui Zhang, Virginia Martín,* Inmaculada García-Moreno, Angel Costel, M. Eugenia Pérez-Ojed and Yi Xiao*
Phys. Chem. Chem. Phys., 2011,13, 13026-13033
DOI: 10.1039/C1CP21038F
Received 04 Apr 2011, Accepted 31 May 2011
First published online 21 Jun 2011

24.Nonlinear optical properties and ultrafast dynamics of three novel boradiazaindacene derivatives
Yaochuan Wang; Zhang, Dakui ; Hui Zhou ; Jinliang Ding ; Qiang, Chen ; Yi Xiao*;Shixiong Qian
JOURNAL OF APPLIED PHYSICSvolumn:108(3) DOI:10.1063/1.** AUG 1 2010

23.Core-Perfluoroalkylated Perylene Diimides and Naphthalene Diimides: Versatile Synthesis, Solubility, Electrochemistry, and Optical Properties
Zhongyi Yuan , Jing Li , Yi Xiao , Zheng Liand Xuhong Qian
J. Org. Chem., 2010, 75 (9), pp 3007–3016
DOI: 10.1021/jo100231j
Publication Date (Web): April 5, 2010

22.Red-edge laser action from borondipyrromethene dyes
Garcia-Moreno, Inmaculada ; Zhang, Dakui; Costela, Angel; Martin, Virginia ; Sastre, Roberto; Xiao, Yi*
Journal of Applied Physics(Volume:107 ,Issue: 7 ) Page(s):073105 - 073105-7
Date of Publication: Apr 2010
http://dx.doi.org/+10.1063/1.**

21.A design concept of planar conjugated ladder oligomers of perylenebisimides and efficient synthetic strategy via regioselective photocyclization
Zhongyi Yuan, Yi Xiao* and Xuhong Qian*
Chem. Commun., 2010,46, 2772-2774
DOI: 10.1039/B925605A
Received 08 Dec 2009, Accepted 09 Feb 2010
First published online 25 Feb 2010

20.“Alive” dyes as fluorescent sensors: fluorophore, mechanism,receptorand images in livingcells
Xuhong Qian,* Yi Xiao, Yufang Xu, Xiangfeng Guo, Junhong Qian and Weipin Zhua
Chem. Commun., 2010,46, 6418-6436
DOI: 10.1039/C0CC00686F
Received 31 Mar 2010, Accepted 18 May 2010
First published online 29 Jun 2010

19.Switching off FRET byanalyte-induceddecompositionofsquaraineenergy acceptor: A concept to transform ‘turn off’ chemodosimeter into ratiometric sensors
Haibo Yu, Meiyan Fua and Yi Xiao*
Phys. Chem. Chem. Phys., 2010,12, 7386-7391
DOI: 10.1039/C001504K
Received 22 Jan 2010, Accepted 18 May 2010
First published online 10 Jun 2010

18.Novel acenaphtho[1,2-b]pyrrole-carboxylic acid family: Synthesis, cytotoxicity, DNA-binding and cell cycle evaluation
Lijuan Xie, Yi Xiao, Fang Wang, Yufang Xu, Xuhong Qian*, Rong Zhang, Jingnan Cui, Jianwen Liu*
Bioorganic & Medicinal Chemistry
Volume 17, Issue 21, 1 November 2009, Pages 7615–7621
http://dx.doi.org/10.1016/j.bmc.2009.02.031

17.Long-wavelength boradiazaindacene derivatives with two-photon absorption activity and strong emission: versatile candidates for biological imaging applications
Dakui Zhang, Yaochuan Wang, Yi Xiao*, Shixiong Qian, Xuhong Qian
Tetrahedron
Volume 65, Issue 39, 26 September 2009, Pages 8099–8103
http://dx.doi.org/10.1016/j.tet.2009.08.002

16.Efficient Synthesis of Regioisomerically Pure Bis(trifluoromethyl)-Substituted 3,4,9,10-Perylene Tetracarboxylic Bis(benzimidazole)
Zhongyi Yuan, Yi Xiao*, Zheng Li and Xuhong Qian*
Org. Lett., 2009, 11 (13), pp 2808–2811
DOI: 10.1021/ol**
Publication Date (Web): June 9, 2009

15.Bulk heterojunction organic solar cell based on a novel fluorescent fluorine–boron complex
Fen Qiao, Aimin Liu, Ying Zhou, Yi Xiao, Ping Ou Yang
Journal of Materials Science
March 2009, Volume 44, Issue 5, pp 1283-1286

14.Synthesis and characterization offullerenederivatives with perfluoroalkylgroups
Xuemei Wang, Yunlong Guo, Yi Xiao,* Lei Zhang, Gui Yu* and Yunqi Liu*
J. Mater. Chem., 2009,19, 3258-3262
DOI: 10.1039/B823336E
Received 05 Jan 2009, Accepted 05 Mar 2009
First published online 31 Mar 2009

13.Enhanced photovoltaic characteristics of solar cells based on n-type triphenodioxazine derivative
Fen Qiao, Aimin Liu,Yi Xiao, Yang Ping Ou, Ji quan Zhang, Yong chang Sang
Microelectronics Journal
Volume 39, Issue 12, December 2008, Pages 1568–1571

12.Novel angular furoquinolinones bearing flexible chain as antitumor agent: Design, synthesis, cytotoxic evaluation, and DNA-binding studies
Lijuan Xie, Xuhong Qian, Jingnan Cui, Yi Xiao, Kewei Wang, Peichun Wu, Liying Cong
Bioorganic & Medicinal Chemistry
Volume 16, Issue 18, 15 September 2008, Pages 8713–8718

11.Trifluoromethyltriphenodioxazine: Air-Stable and High-Performance n-Type Semiconductor
Chong-an Di , Jing Li , Gui Yu , Yi Xiao , Yunlong Guo , Yunqi Liu , Xuhong Qian and Daoben Zhu
Org. Lett., 2008, 10 (14), pp 3025–3028
DOI: 10.1021/ol**
Publication Date (Web): June 12, 2008

10.2,3,6,7-Tetraamino-9,9-bis(2-ethylhexyl)fluorene: New Multifunctional Monomer for Soluble Ladder-Conjugated Molecules and Polymers
Xichuan Li , Yi Xiaoand Xuhong Qian
Org. Lett., 2008, 10 (13), pp 2885–2888
DOI: 10.1021/ol801081w
Publication Date (Web): June 3, 2008

9.A highly selective Cd2+sensor of naphthyridine: fluorescent enhancement and red-shift by the synergistic action of forming binuclear complex
Ying Zhou, Yi Xiao, Xuhong Qian
Tetrahedron Letters
Volume 49, Issue 21, 19 May 2008, Pages 3380–3384

8.A design concept of long-wavelength fluorescent analogs ofrhodaminedyes: replacement ofoxygenwithsiliconatom
Meiyan Fu, Yi Xiao,* Xuhong Qian,* Defeng Zhao and Yufang Xu
Chem. Commun., 2008, 1780-1782
DOI: 10.1039/B718544H
Received 30 Nov 2007, Accepted 22 Jan 2008
First published online 14 Feb 2008

7.Versatile Nitro-Fluorophore as Highly Effective Sensor for Hypoxic Tumor Cells: Design, Imaging and Evaluation
Min Dai, Weiping Zhu, Yufang Xu, Xuhong Qian, Yan Liu, Yi Xiao, Yin You
Journal of Fluorescence
March 2008, Volume 18, Issue 2, pp 591-597

6.Isomeric BoronFluorine Complexes with DonorAcceptor Architecture: Strong Solid/Liquid Fluorescence and Large Stokes Shift
Ying Zhou, Yi Xiao,* Shaoming Chi and Xuhong Qian*;
Org. Lett., 2008, 10 (4), pp 633–636
DOI: 10.1021/ol702963w
Publication Date (Web): January 18, 2008

5.Novel Fluorescent FluorineBoron Complexes: Synthesis, Crystal Structure, Photoluminescence, and Electrochemistry Properties
Ying Zhou , Yi Xiao,* Dan Li , Meiyan Fu and Xuhong Qian *
J. Org. Chem., 2008, 73 (4), pp 1571–1574
DOI: 10.1021/jo702265x
Publication Date (Web): January 15, 2008

4.Synthesis, Herbicidal Activity, and Structure-Bioactivity Relationship of Pyridyl-Containing 2-Phenyliminothiazolidines
Gangyue Li, Xuhong Qian, Shenggang Yan, Jingnan Cui, Rong Zhang, Yi Xiao
Monatshefte für Chemie - Chemical Monthly
February 2008, Volume 139, Issue 2, pp 169-178

3.Highly Efficient Energy Transfer in the Light Harvesting System Composed of Three Kinds of BoronDipyrromethene Derivatives
Xiaolin Zhang , Yi Xiao,* and Xuhong Qian
Org. Lett., 2008, 10 (1), pp 29–32
DOI: 10.1021/ol702381j
Publication Date (Web): December 11, 2007

2.A Ratiometric Fluorescent Probe Based on FRET for Imaging Hg2+Ions in Living Cells
Xiaolin Zhang, Yi Xiao, Xuhong Qian
Angewandte Chemie International Edition
Volume 47, Issue 42, pages 8025–8029, October 6, 2008

1.Bulky4-tritylphenylethynylsubstitutedboradiazaindacene: pure red emission, relatively large Stokes shift and inhibition of self-quenching
Dakui Zhang, Yugeng Wen, Yi Xiao,* Gui Yu,* Yunqi Liu and Xuhong Qian*
Chem. Commun., 2008, 4777-4779
DOI: 10.1039/B808681H
Received 22 May 2008, Accepted 30 Jun 2008
First published online 06 Aug 2008

工作成果（奖励、专利等）
项目名称“生物功能色素及荧光分子传感器”，获奖人：钱旭红，肖义，崔京南，徐玉芳。2008年度上海市自然科学一等奖，省部级奖。获奖时间：2008年12月。

在读学生人数
13

毕业学生人数
20