姓名：任志刚
职称：教授
直属机构：材料与化学化工学部
学位：
学历：
毕业院校：
毕业专业：
通讯地址：
邮编：
电子邮箱： renzhigang@suda.edu.cn
联系电话：**
传真：
办公地址：材料与化学化工学部


个人简介 个人简介：1996年苏州大学本科毕业，1999年苏州大学硕士研究生毕业并留校任教。2008年在苏州大学在职获得博士学位。2014年晋升教授。中国化学会、江苏省化学会、江苏省“有机化学”重点实验室、江苏省“无机化学”重点学科以及苏州大学“无机化学”精品课程群成员。完成一项国家自然科学基金青年基金项目。现主持两项国家自然科学基金面上项目。在国内外核心化学期刊如Appl. Catal. B Environ., Organometallics，Cryst.Growth Des.，Dalton Trans.等发表正式论文十余篇。获2009年中国石油和化学工业协会科技进步二等奖、2010年江苏省科学技术奖二等奖、2011年教育部高等学校科学研究优秀成果奖(科学技术)自然科学奖二等奖等省部级科研奖励。广泛参与各种学术交流，是多个国内国际学术会议的组织者和分会主持人。


研究领域 研究领域：1 多齿膦配体及其配合物的设计、合成与性能研究；
2 含Mo(W)/S/Cu核心的簇合物的合成。



科研项目 科研项目：
科学研究(旧版)：主持两项国家自然科学基金：
基于多齿膦配体的配位超分子的设计、组装与性能研究（**），已结题；
新型PNP配体的设计、合成及其配合物在催化C-C偶联反应中的应用（**），进行中；
含多膦配体的银、金配合物光催化剂的设计合成及其在催化降解水体芳基污染物中的应用（**），进行中。

在多齿膦配体的设计、合成与性能研究
1 先后开发出了系列四膦，P-N混合配体以及P-S混合配体。利用这些配体与Cu(I)、Ag(I)、Ni(II)等金属进行配位组装，获得了结构丰富的单核、双核配合物和一维、二维、三维配位聚合物。发现设计得到的这些配体多具有较强的配位能力，如与Ag(I)就先后得到了分子花篮状和二维平面型；一维螺旋链、双股链、二维阶梯状；乃至由二维[Ag10(CN)12]n2n-阴离子型网格穿插成的含孔道的三维网络中容纳[Ag4(CN)2(L)4]n2n+的阳离子双股链而得到的离子型一维-二维-三维混合结构。还发现部分配体在反应中可以原位转化为新颖的其它结构并得到新型配合物。
2 对所得配合物的应用性研究。用所得产物开展了催化己内酯聚合、催化Suzuki偶联反应、光催化环境污染物降解等方面的研究。近年来，陆续发现了所得产物与Ag配合物中产生稳定的蓝色有机自由基，与Au所得配合物的独特荧光性质用于溶剂响应和肿瘤细胞标记，以及用于热-小分子气体响应及荧光开关等方面的性能。
3 目前，正致力于新的混合型膦配体的设计合成及其在组装新Au、Ag簇合物方面的研究。


科技成果 软件著作 软件著作： 专利 专利：

论文 论文成果：
M. –S. Jiang, Y. –H. Tao, Y. –W. Wang, C. Lu*, D. J. Young, J. –P. Lang, Z. –G. Ren*, Reversible Solid-State Phase Transitions between Au?P Complexes Accompanied by Switchable Fluorescence, Inorg. Chem., 2020, 59, ASAP article. doi=10.1021/acs.inorgchem.9b03412
M. Yang, X. –Y. Wu, H. –F. Wang, D. J. Young, Z. –G. Ren*, J. –P. Lang, Novel silver-phosphine coordination polymers incorporating a Wurster’s Blue - like radical cation with enhanced photoelectric properties, Chem. Commun., 2019, 55, 6599-6602.
C. –Y. Liu, H. –F. Wang, Z. –G. Ren*, P. Braunstein, J. –P. Lang*, Fine-Tuning of Luminescence through Changes in Au–S Bond Lengths as a Function of Temperature or Solvent, Inorg. Chem.,2019, 58, 8533-8540.
C. –Y. Liu, X. –R. Wei, Y. Chen, H. –F. Wang, J. –F. Ge*, Y. –J. Xu, Z. –G. Ren*, P. Braunstein, J. –P. Lang*, Tetradecanuclear and Octadecanuclear Gold(I) Sulfido Clusters: Synthesis, Structures, and Luminescent Selective Tracking of Lysosomes in Living Cells, Inorg. Chem.,2019, 58, 3690-3697.
X. Zhou, Y. –X. Shi, C. Cao, Z. –G. Ren*, D. J. Young, J. –P. Lang, Nickel(II)-Based Two-Dimensional Coordination Polymer Displaying Superior Capabilities for Selective Sensing of Cr(VI) Ions in Water, Cryst. Growth Des., 2019, 19, 3518-3528.
X. Zhou, D. Liu, F. –F. Lang, Z. –G. Ren*, J. –P. Lang*, Two 2D Zinc(II) Coordination Polymers and Their Orange IV Composites: Preparation, Structures, and Photocurrent Responses, Cryst. Growth Des., 2019, 19, 211-218.
M. –D. Liu, B. F. Abrahams, Z. –G. Ren*, J. –P. Lang*, A 3D [WS₄Cu₄]2+ cluster-based material with high iodine uptake capability, Dalton Trans., 2019, 48, 6695-6699.
C. –F. Liu, C. –F. Liu, Z. –G. Ren*, J. –P. Lang*, Silver(I)-Based Complexes Used as High-Performance Photocatalysts for the Degradation of Organic Dyes in Water, Eur. J. Inorg. Chem., 2019, 1816-1824.
L. –Y. Xu, W. Yang, C. –F. Liu, Z. –G. Ren*, J. –P. Lang*, Assembly of silver-oxo complexes based on N-diphenylphosphanylmethyl-3-aminopyridineand their structures, photocatalysis and photocurrent responses, CrystEngComm.2018, 20, 4049-4057.
T. –Y. Gu, M. Dai, D. J. Young, Z. –G. Ren*, J. –P. Lang*, Luminescent Zn(II) Coordination Polymers for Highly Selective Sensing of Cr(III) and Cr(VI) in Water, Inorg. Chem., 2017, 56, 4668-4678.
D. Liu, F. –F. Lang, X. Zhou, Z. –G. Ren,* D. J. Young, J.–P. Lang*, A Cationic Coordination Polymer and Its Orange II Anion-Exchanged Products: Isolation, Structural Characterization, Photocurrent Responses, and Dielectric Properties,Inorg. Chem.2017, 56,12542?12550.
C.–Y. Liu , L. –Y. Xu, Z. –G. Ren*, H. –F. Wang*, J. –P. Lang*, Assembly of Silver(I)/N,N-Bis(diphenylphosphanylmethyl)-3-aminopyridine/Halide or Pseudohalide Complexes for Efficient Photocatalytic Degradation of Organic Dyes in Water，Cryst. Growth Des., 2017, 17,4826?4834.
S. –Y. Liu, L. –Y. Xu, C. –Y. Liu, Z. –G. Ren*, D. –J. Young*, J. –P. Lang*, Efficient Alkylation of Ketones with Primary Alcohols Catalyzed by Ruthenium(II)/P,N Ligand Complexes, Tetrahedron,2017, 73, 2374-2381.
L. –Y. Xu, C. –Y. Liu, S. –Y. Liu, Z. –G. Ren*, D. J. Young, J. –P. Lang*, Suzuki-Miyaura cross-coupling reaction of aryl chlorides with aryl boronic acids catalyzed by a palladium dichloride adduct of N-diphenylphosphanyl-2-aminopyridine, Tetrahedron, 2017, 73, 3125-3132.
J. Gao, Z. –G. Ren*, J. –P. Lang*, One-pot aqueous-phase synthesis of quinoxalines through oxidative cyclization of deoxybenzoins with 1,2-phenylenediamines catalyzed by a zwtterionic Cu(II)/calix[4]arene complex, Chin. Chem. Lett., 2017, 28, 1087-1092.
W. –H. Zhang, Z. –G. Ren, J. –P. Lang*, Rational construction of functional molybdenum (tungsten)-copper-sulfur coordination oligomers and polymers from preformed cluster precursors, Chem. Soc. Rev., 2016, 45,4995-5019. (共同一作)
J. –F. Wang, S. –Y. Liu, C. –Y. Liu, Z. –G. Ren*, J. –P. Lang, Silver(I) complexes with a P-N hybrid ligand and oxyanions: synthesis, structures, photocatalysis and photocurrent responses, Dalton Trans., 2016, 45, 9294-9306.
X. –Y. Wu, H. –X. Qi, J. –J. Ning, J. –F. Wang, Z. –G. Ren*, J. –P. Lang*, One silver(I)/tetraphosphine coordination polymer showing good catalytic performance in the photodegradation of nitroaromatics in aqueous solution, Appl. Catal. B Environ., 2015, 168, 98-104.
H. –X. Qi, J. –F. Wang, Z. –G. Ren*, J. –J. Ning, J. –P. Lang*, Syntheses and structures of two gold(I) coordination compounds derived from P-S hybrid ligands and their efficient catalytic performance in the photodegradation of nitroaromatics in water, Dalton Trans.,2015, 44,5662-5671.
D. –X. Li, Z. –G. Ren*, D. J. Young, J. –P. Lang*, Synthesis of Two Coordination Polymer Photocatalysts and Significant Enhancement of Their Catalytic Photodegradation Activity by Doping with Co²⁺Ions, Eur. J. Inorg. Chem.2015, 1981-1988.
J. –J. Ning, J. –F. Wang, Z. –G Ren*, D. J. Young, J. –P. Lang*, Versatile palladium(II)-catalyzed SuzukieMiyaura coupling in ethanol with a novel, stabilizing ligand, Tetrahedron, 2015, 71, 4000-4006.
J. Gao, Z. –G. Ren*, J. –P. Lang*, Oxidation of benzyl alcohols to benzaldehydes in water catalyzed by a Cu(II) complex with a zwitterionic calix[4]arene ligand, J. Organomet. Chem.,2015, 792, 88-92.
R. –T. He，J. –F. Wang, H. –F. Wang, Z. –G. Ren*, J. –P. Lang*, Palladium dichloride adduct of N,N-bis-(diphenylphosphanylmethyl)-2-aminopyridine: synthesis, structure and catalytic performance in the decarboxylative crosscoupling of 4-picolinic acid with aryl bromide, Dalton Trans.,2014, 43, 9786-9794.
L. –K. Zhou, Q. Liu, X. Zhao, F. –L. Hu, S. –C. Liu, Z. –G. Ren*, Z. –R. Sun, J. –P. Lang*, Six [Tp*WS₃Cu₂]-based clusters derived from [Et₄N][Tp*WS₃], Cu(I) salts and phosphine ligands: syntheses, structures and enhanced third-order NLO properties, Dalton Trans.,2014, 43, 4734-4744.
X. –Y. Wu, Z. –G. Ren*, J. –P. Lang*, Ni(II) tetraphosphine complexes as catalysts/initiators in the ring opening polymerization of ε-caprolactone, Dalton Trans.,2014, 43, 1716-1723.
M. Dai, X. –R. Su, X. Wang, B. Wu, Z. –G. Ren*, X. Zhou, J. –P. Lang, Three Zinc(II) Coordination Polymers Based on Tetrakis(4-pyridyl)cyclobutane and Naphthalenedicarboxylate Linkers:Solvothermal Syntheses, Structures, and Photocatalytic Properties, Cryst. Growth Des.,2014, 14, 240-248.
L. Li, H. –Y. Li,Z. –G. Ren*, J. –P. Lang*, Unique decanuclear and tetranuclear halocuprate(I) clusters of a quasi-rigid clamp-like ligand: Isolation, structure and luminescent property, Eur. J. Inorg. Chem.2014, 824-830.
B. Wu, Z. –G. Ren*, J. –P. Lang, Three three-dimensional supramolecular networks formed by one-dimensional chains of Ag(I) and N,N’-di(3-pyridyl)succinamide via weak intermolecular interactions, Inorg. Chem. Commun., 2014, 48, 81-85.
J. –H. Yang, X. –Y. Wu, R. –T. He, Z. –G. Ren*, H. –X. Li, H. –F. Wang, J. –P. Lang*, Degradation versus Expansion of the AgX Frameworks: Formation of Oligomeric and Polymeric Silver Complexes from Reactions of Bulk AgX with N-Bis(diphenylphosphanylmethyl)-2-aminopyridine, Cryst. Growth Des., 2013, 13, 2124-2134.
C. Xu, Z. –Y. Zhang, Z. –G. Ren*, L. –K. Zhou, H. –X. Li, H. –F. Wang, Z. –R. Sun*, J. –P. Lang*, Novel [Tp*WS₃Cu₂]-Based Coordination Compounds: Assembly, Crystal Structures and Third-Order Nonlinear Optical Properties, Cryst. Growth Des., 2013, 13, 2530-2539.
Z. –Y. Zhang, W. –J. Gong, F. Wang, M. –M. Chen, L. –K. Zhou, Z. –G. Ren*, Z. –R. Sun, J. –P. Lang*, Assembly of new Mo/Cu/S clusters from [Et₄N][Tp*MoS(S₄)] and Cu(I) salts: syntheses, structures and third-order nonlinear optical properties, Dalton Trans., 2013, 42, 9495-9504.
W. –Y. Yan, R. –T. He, M. Dai, Z. –G. Ren*, H. –X. Li, J. –P. Lang*, Assembly of 1D and 2D zinc(II) coordination polymers from flexible polyimidazolyl-based ligands, Inorg. Chem. Commun., 2013, 35, 51-55.
S. Sun, Z. –G. Ren, J. –H. Yang, R. –T. He, F. Wang, X. –Y. Wu, W. –J. Gong, H. –X. Li, J. –P. Lang*, Formation of N-heterocyclic diphosphine ligands from Ag(I)-assisted Mannich condensation reactions between bdppeda and HCHO and their sandwich-like silver(I) complexes,Dalton Trans., 2012, 41, 8447-8454.
Z. –G. Ren, H. –X. Li, W. –Y. Yan, J. –P. Lang*, Assembly of bicyclic or monocyclic clusters from [(η⁵-C₅Me₅)₂Mo₂(μ₃-S)₄(CuMeCN)₂]²⁺with tetraphosphine or N,P mixed ligands: syntheses, structures and enhanced third-order NLO performances, Dalton Trans, 2011, 40, 8391-8398.
L. –P. Wei, Z. –G. Ren,L. –W. Zhu, W. –Y. Yan, S. Sun, H. –F. Wang, J. –P. Lang*, Z. –R. Sun, Construction of Halide-Bridged Tungsten-Copper-Sulfide Double Cubanelike Clusters from a New Precursor [(Tp*WS₂)₂(μ-S₂)], Inorg. Chem., 2011,50, 4493-4502.
N. –Y. Li, Z. –G. Ren, D. Liu, R. –X. Yuan, L. –P. Wei, L. Zhang, H. –X. Li, J. –P. Lang*, Construction of [Ag₂X₂]-based complexes from reactions of Ag(I) salts with N-diphenylphosphanylmethyl-4-aminopyridine: isolation, structures, and luminescent properties, Dalton Trans., 2010, 39, 4213-4222.
Z. –G. Ren, Y. –L. Song, L. –L. Li, H. –X. Li, Z. –H. Wei, Y. Zhang, J. –P. Lang*, From trans-[(η⁵-C₅Me₅)₂Mo₂S₂(μ-S)₄] to [(η⁵-C₅Me₅)₂Mo₂(μ₃-S)₄(CuMeCN)₂]²⁺to [(η⁵-C₅Me₅)₂Mo₂(μ₃-S)₄Cu₂]-Based Polymeric and Dimeric Clusters: Syntheses, Structures and Enhanced Third-Order Nonlinear Optical Performances, Dalton Trans, 2009,2578-2587.
N. –Y. Li, Z. –G. Ren, D. Liu, J. Wang, H. –X. Li, J. –P. Lang*, Two 1D [Cu_xI_x]-based Coordination Polymers of Tetraphosphine Ligands, Inorg. Chem. Commun., 2009,12, 1031-1034.
L. Li, Z. –G. Ren, N. –Y. Li, Y. Zhang, J. –P. Lang*, Syntheses, crystal structures and luminescent properties of a basket-shaped complex [Ag₂(dppeda)Cl](NO₃) and a 2D polymeric complex [Ag₂(dppeda)(SCN)₂]_n(dppeda = N,N,N’,N’-tetra(diphenylphosphanylmethyl)ethylene diamine), Inorg. Chim. Acta, 2009, 362, 3910-3914.
Z. –G. Ren, H. –X. Li, L. –L. Li, Y. Zhang, J. –P. Lang, J. –Y. Yang, Y. –L. Song,Synthesis, Characterization and Third-order Nonlinear Optical Properties of Heterobimetallic Clusters [(η⁵-C₅Me₅)₂Mo₂(μ₃-S)₃SCu₂X(μ-X)]₂ (X = Cl-, Br-, SCN-) and [(η⁵-C₅Me₅)₂Mo₂(μ₃-S)₄(CuX)₂] (X = Br-, SCN-, CN-), J. Organomet. Chem., 2007,692, 2205.
Z. –G. Ren, H. –X. Li, G. –F. Liu, W. –H. Zhang, J. –P. Lang, Y Zhang, Y. –L. Song, Synthesis of Two Heterobimetallic Cluster Isomers [(η⁵-C₅Me₅)₂ Mo₂(μ₃-S)₃S(CuI)₂] and [(η⁵-C₅Me₅)₂Mo₂(μ₃-S)₄(CuI)₂] from trans-[(η⁵-C₅Me₅)₂Mo₂(μ-S)₂S₂] and Theirtrans-to-cisIsomerization, Structures, and Third-Order NLO Properties. Organometallics,2006, 25, 4351.



荣誉及奖励 荣誉及奖励：1、2009年中国石油和化学工业协会科技进步二等奖（排名3），"含金属硫簇材料的合成及其应用研究"
2、2010年江苏省科学技术奖二等奖（排名2），“团簇配位超分子的设计、组装及其应用研究”
3、2011年教育部高等学校科学研究优秀成果奖(科学技术)自然科学奖二等奖（排名4），“功能配合物的设计、合成及应用”



Teaching 开授课程：课程教学：《无机化学》
《无机与分析化学》
《无机化学实验》
《普通化学》
《环境化学》
2009：获批“苏州大学2009-2010年度化学化工与材料学教学研究项目”（2009适合现代化学技能及环保要求的基础化学新实验的设计）并已结题。
2010：参编《基础化学》教材（化学工业出版社，2010年版，唐迪主编）获得2012年中国石油和化学工业出版物奖（教材奖）二等奖.
2013：获苏州大学第12届青年教师课堂教学竞赛二等奖



招生信息 招生信息： 招生信息1：面向全国招收全日制硕士研究生
专业方向：功能配合物化学，分子材料及分子组装化学；无机-有机光电材料的设计与合成；超分子化学