职务：
联系电话： +86-
办公地址： 化学化工学院C505
电子邮箱： hbdu@nju.edu.cn

课题组主页： http://hysz.nju.edu.cn/duhongbin/





个人简介


1992和1997年在吉林大学化学系分别获得学士与博士学位，从事新型无机微孔晶体的合成与表征研究。1997年至1998年在美国The Ohio State University 化学系从事博士后研究，开发研究高温气体传感器；1998年至2000年为加拿大University of New Brunswick 博士后，从事第16和17族聚多原子簇阳离子的合成、结构和成键研究；2000年至2002年为加拿大National Research Council Canada 访问****，从事空气分离及氢气储存研究。2002年至2005年任加拿大Alberta Research Council研究员，从事重油加工的应用开发研究；2005年9月起回国任南京大学化学化工学院教授，从事多孔晶体材料的晶体工程、能源存储和转化材料化学研究。

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工作经历


2005-9至现在, 南京大学, 化学化工学院, 教授
2002-2005, Natural Resources Canada, NCUT技术中心, 研究员
1997-1998、1998-2000、2000-2002年分别在美国The Ohio State University,加拿大University of New Brunswick、National Research Council Canada从事博士后研究
1992-1997, 吉林大学化学系, 博士, 导师: 庞文琴
1988-1992, 吉林大学化学系, 学士


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研究方向


课题组的研究方向主要是通过开发新的合成方法和策略，辅以计算化学方法，制备在气体吸附、分离、催化、光电以及能源存储和转化等领域有应用前景的新型多孔材料和能源材料。
当前研究课题:
1.分子筛催化剂：着重研究具有超大孔道、交叉孔道等特殊孔道结构的新型硅铝酸盐沸石分子筛材料的设计合成，开发其在石油和精细化工中催化裂解、催化加氢等领域的应用性能。
分子筛（molecular sieves）是一类具有规则的、分子尺寸大小孔道结构的多孔材料（porous materials），通常是由TO4（T = Si, Al 等）四面体结构单元连接形成的晶体材料，其中最为人们所熟悉的是硅铝酸盐沸石（zeolites）。该类材料具有非常高的比表面积、有序的孔道结构、离子交换性能等，在吸附、分离、催化 、离子交换等领域具有重要的工业应用价值，并被广泛应用于石油冶炼、有机化工、吸附剂、气体分离、添加剂、农业园艺、颜料、珠宝等行业（人工合成沸石每年的销售市值达20亿美元以上）。自上世纪五十年代分子筛被应用以来，这类材料一直是科学研究和应用技术领域关注的热点，被称为二十一世纪对人类社会具有重大贡献的材料之一。
分子筛的结构与其性能密切相关。随着对沸石分子筛应用过程，尤其是其催化性能与结构关系的了解进一步地深入，人们对沸石分子筛的结构也提出了新的需求，例如，需要合成可以提高催化效能的多维交叉孔道、可用于大分子催化的超大孔道以及可用于手性催化和分离的手性孔道等特殊孔道沸石分子筛。工业中大规模应用的分子筛材料如ZSM-5（孔道由10个TO4四面体围成，10-membered ring channel/pore，简记为10R）和Y型沸石（12R）等，其孔道大小通常都处于1 nm以下，这大大限制了吸附、分离、催化等过程中分子的大小和形状，成为分子筛材料实际应用中的一个掣肘。为加快反应中反应物与产物的传输，从而进一步提高性能，以及满足重油、药物等大分子催化合成的需要，工业上迫切需求具有交叉孔道结构的超大孔（>12R）甚至介孔（孔径大于2 nm）沸石分子筛。
由于硅酸盐具有良好的化学和水热稳定性，超大孔硅酸盐沸石分子筛材料具有重要应用前景，受到人们额外的关注。但是，超大孔硅酸盐沸石分子筛结晶非常困难，一直是化学家面临的巨大挑战。近二十年来人们开发出了有机 阳离子结构导向剂法和无机结构单元导向法（如利用Ge、B、Ga、Be等杂原子）等多种合成策略，在合成大孔和超大孔硅酸盐沸石分子筛方面取得了突出进展。但合成的超大孔沸石分子筛数目依然很少（目前仅17个），并且得到的超大孔沸石分子筛绝大多数由于含有杂原子等原因而不稳定，在有机结构导向剂去除后骨架结构便塌陷，影响了其应用。同时，大多数超大孔沸石分子筛的合成需要使用刚性的大尺寸有机结构导向剂，这些有机结构导向剂的合成步骤多、产量低，导致这些超大孔沸石分子筛难以合成和应用。合成开发价格便宜、热稳定性良好的新型超大孔沸石分子筛，既具有科学意义，又具有应用价值。
本课题拟结合计算机理论模拟，设计新型有机季铵结构导向剂，通过控制其空间几何结构、亲疏水性等，调变有机结构导向剂与无机结构单元的相互作用，合成具有大孔交叉孔道、超大孔和手性等特殊孔道结构的新型沸石分子筛，获得一些合成经验规律，为进一步定向设计合成具有特定孔道结构的新型微孔晶体提供一定的实验数据和指导。近年来，我们开发了一种利用 廉价的小尺寸有机阳离子的超分子自组装体为结构导向剂合成超大孔沸石分子筛的方法，制备出了系列大孔和超大孔沸石分子筛，为进一步合成具有特殊孔道结构的新型沸石、筛选出具有实际应用价值的超大孔沸石分子筛奠定了基础（Angew. Chem. Int. Ed.,2014, 53, 9592；Angew. Chem. Int. Ed., 2020, 59, 3948; CrystEngComm, 2016, 18, 2735；Chem. Eur. J., 2016, 22, 14367.）。

图1. 我课题组合成的新型分子筛
2.能源储存材料：针对锂离子电池、超级电容器等储能体系，研究开发新型高性能电极材料、电解质材料和新技术，以期获得具有应用价值的能源储存系统和技术。
硅作为地球上丰度排名第二的元素，不仅价格低廉，而且具有独特的性能。单质硅是性能优异的窄带半导体，作为一类工业上最为重要的电子材料，被广泛应用于晶体管、逻辑开关、传感器、太阳能电池、光探测器等领域。然而，单质硅是一种间接带隙型半导体，它对光子的吸收和发射过程涉及需要改变动量的声子，这样能量通常转换成热能（即晶格振动）等非辐射形式，导致单晶硅发光效率低或不发光，不能用作光电器件，从而限制了硅基电子器件的多功能化和性能的进一步提高。
1990年L. Canham利用电化学法在氢氟酸中刻蚀单晶硅片制备多孔硅时首次发现了单质硅的可见光发光现象，该现象被归因于多孔硅中存在量子尺寸的硅纳米线。通过调控孔道大小，多孔硅的光发射可在整个可见光区移动。但由于刻蚀法制备多孔硅的不便性、多孔硅本身的化学活波性和易脆性，其实际应用受到很大限制。于是，人们把注意力转向了同样具有量子尺寸效应的硅纳米颗粒。硅纳米晶的表面可以被各种配体钝化而稳定，它们的发光光谱可以通过改变颗粒大小、钝化层、表面氧化度、结晶度等从近红外调变到可见区，发光量子效率可达1.6%。发光的硅纳米晶可以被集成到微电子电路上，制成硅基发光二极管或激光器件，显示了巨大的应用前景。
硅材料不像其它许多含金属材料，它在人体内毒性很低、可以降解，因此发光的硅材料可以用于生命医学研究。作为荧光显影剂，可见光区吸收、红光或近红外区发光的硅纳米粒子特别适合用于活体的疾病诊断和检测。由于部分光子的能量转换为热能，硅纳米粒子也可作为光热疗剂，用于杀死癌细胞。另外，多孔硅可作为载体，输运和缓释药物到发病区，是一种集疾病检测、药物输运、光热治疗于一体的多功能材料，受到人们的极大关注。然而，目前的多孔硅材料制备过程复杂、孔道大小不均一、比表面积和孔体积小、颗粒不能纳米化且大小不均匀，其应用受到很大影响。最近，人们利用硅纳米线为载体，通过表面修饰或包覆有机聚合物，然后装载药物分子，所得材料具有良好的药物缓释和荧光显影性能，但硅纳米线长短不易操控，在应用上受到一定限制。
硅纳米材料在能源领域也具有巨大的应用前景。在能源转换方面，单晶硅光伏电池已大规模工业应用，为降低成本，人们正在开发多晶硅和无定型硅基光伏电池。基于硅纳米晶和硅纳米线的光伏电池也表现出了优异的性能。在能源储存方面，Si作为锂电池的负极材料受到极大关注。硅的锂离子电池理论电容量可达~4200 mA h/g（商品化石墨负极仅为372 mA h/g），有望成为新一代高容量电池的电极材料。然而由于Li和Si反应生成Li4.4Si时体积膨胀300%，导致充放电过程中电极断路而使电池性能急剧降低。为此，人们利用纳米化技术，以硅的纳米点、纳米线等作电极材料，以纳米颗粒间空隙来缓解锂嵌入和脱出前后的体积变化，同时在硅纳米材料表面包覆导电的碳材料、金属银等改善颗粒间的导电性，较为有效地缓解了电池的性能衰减问题，为其实际应用奠定了基础，然而其循环寿命仍有待于进一步提高。
实验室中单质硅纳米材料大多采用化学气相沉积法（CVD）制备。CVD合成单质硅材料一般使用SiCl4, SiH4, Si2H6等挥发性气体为原料，在高温（>500°C）或激光照射等条件下前驱物分解而得，方法操作简单、可连续操作，因此应用较为广泛。缺点是部分设备昂贵、反应条件苛刻、硅烷易燃易爆等，另外对产物的形貌规整度控制以及大规模制备上也有待进一步改进和提高。溶液合成法一般具有方法简便、适合大规模制备、产物结构和形貌可控性强等特点。但由于常见的硅前驱物中Si为+4价，且与O、C等形成很强的共价键，所以溶液法应用于制备单质硅的报道并不多。迄今，人们开发的溶液法制备单质硅材料的方法可分为超临界溶液法、四价硅还原法、金属硅化物氧化法等，尽管合成条件需要无水无氧等苛刻条件，溶液法在合成硅材料方面仍然显示了具有巨大的潜力。
多孔硅一般通过干法或湿法刻蚀获得。干法刻蚀又称反应性离子蚀刻法，是当今微电子加工中常用的物理技术。湿法刻蚀是在碱性溶液或酸性溶液中，通过添加氧化剂、HF等来实现对单晶硅片的化学腐蚀，所得多孔硅的孔道形状和大小可以通过改变电流、硅片掺杂类型和掺杂量、硅片的晶体生长取向、电解液浓度、电解池构型、硅片表面预处理、反应时间等来控制。刻蚀法制备多孔硅的操作复杂、重复性差、不能得到孔道和颗粒大小均匀的材料，严重限制了其应用。另一种制备多孔硅的方法是固相法，即在高温下利用金属Mg还原特定形貌的SiO2而生成Si，控制合适的条件，其前驱物的形貌可以保持不变。例如我们利用该方法，将介孔SiO2纳米球还原成了具有高比表面积和较窄孔道分布的介孔单质硅空心纳米球（Chem. Commun. 2012, 48, 4950）。
总之，目前纳米结构硅材料的制备还不成熟，缺乏一种简单、快速、便宜的制备方法，致使这类材料的应用受到的很大限制，特别是在具有有序孔道和规则形貌的单质硅合成上，目前还鲜有报道。因此，开发新的合成方法和策略，合成具有有序孔道结构的介孔硅和规则形貌的单质硅半导体材料，在合成化学和材料应用研究上具有重要意义。
本课题将开辟新合成方法与策略，合成类沸石分子筛 结构的多孔硅晶体与介孔硅、具有特定形貌的单质硅纳米结构材料等。该类新材料集多孔性与导电性能于一体，在传感、能源（如锂电池 、超级电容器、光解水制氢、二氧化碳光还原）、医学（药物输送和诊断）等领域中有重要应用价值。近年来，我们通过采用自上而下（top-down）和自下而上（bottom-up）的策略，利用镁热还原、剥离和自组装等方法，制备出了单质硅空心纳米球、硅纳米管、硅纳米棒、硅纳米颗粒、硅纳米片以及具有介孔的多孔硅材料，它们在电容器、锂离子电池等方面显示了优异性能，为进一步合成具有特定形貌和孔道结构的新型硅材料以及研究其在清洁能源、能源存储和转化中的应用奠定了基础（Chem. Commun., 2016, 52, 4341；Phys. Chem. Chem. Phys., 2016, 18, 1521；Dalton Trans., 2016, 45, 2369；RSC Advances, 2016, 6, 4063）。
在以上研究的基础上，利用开发的新合成方法与策略，合成具有不同组成和结构的新型离子导体和半导体材料，例如C材料、金属硫化物或磷化物等，研究其在传感、能源等领域中的重要应用。
图2. 我课题组合成的具有特定形貌和多孔结构的半导体硅材料
欢迎有兴趣者来课题组交流、学习、合作研发！
我课题组开发出了具有应用价值的超大孔硅铝酸盐分子筛、用作锂离子电池负极材料的多孔硅、纳米硅、多孔碳球等材料，欢迎联系洽谈应用推广！



学术成果


Papers (* = Corresponding Author)
100. Fei Wang,^aSiyu Chen,^aChangsheng Song,^aBaoxun Zhao,^aHongbin Du,*^aMin Fang*^b, Solvent-induced growth of free-standing two-dimensional Si nanosheets, Small, 2020, in press.
99. Wenwen Zi, Xianshu Cai, Feng Jiao, Hongbin Du*, Synthesis, structure and properties of an extra-large-pore aluminosilicate zeolite NUD-6, Chemistry - A European Journal, 2020, 26, in press.


98. Wen-Wen Zi,^aJun Zhang,^bXian-Shu Cai,^aFeng Jiao,^aHong-Bin Du*^a, Synthesis and characterization of a layered aluminosilicate NUD-11 and its transformation to a 3D stable zeolite, Dalton Trans., 2020, 49, 11682-11688.


97. Baoxun Zhao, Changsheng Song, Fei Wang, Wenwen Zi, Hongbin Du*, Facile synthesis of microporous N-doped carbon material and its application in supercapacitor, Microporous and Mesoporous Materials, 2020, 306, 110483.


96. Wen-Wen Zi,^+aZi-Hao Gao,^+aJun Zhang,^bBao-Xun Zhao,^aHong-Bin Du,*^aFei-Jian Chen*^c, An extra-large-pore pure silica zeolite with 16x8x8-membered ring channels synthesized by using an aromatic organic directing agent,Angew. Chem. Int. Ed., 2020, 59, 3948-3951.


95. Fei Wang, Changsheng Song, Baoxun Zhao, Lin Sun, Hongbin Du*, One-pot solution synthesis of carbon-coated silicon nanoparticles as an anode material for lithium-ion batteries, Chem. Commun., 2020, 56, 1109-1112.
94. Wen-Wen Zi,^aZi-Hao Gao,^aJun Zhang,^bJing-Hui Lv,^cBao-Xun Zhao,^aYu-Fei Jiang,^aHong-Bin Du,*^aFei-Jian Chen*^d, Designed synthesis of an extra-large pore zeolite with a 14-membered ring channel via supramolecular assembly templating approach, Microporous and Mesoporous Materials, 2019, 290, 109654.
93. Fei Wang, Bao Xun Zhao, Wenwen Zi, Hong Bin Du*, Ionothermal synthesis of crystalline nanoporous silicon and its use as anode materials in lithium ion batteries, Nanoscale Research Letters, 2019, 14, 196.
92. Fei Wang, Lin Sun, Wenwen Zi, Bao Xun Zhao, Hong Bin Du*, Solution synthesis of porous silicon particles as an anode material for lithium ion batteries, Chemistry - A European Journal, 2019, 25, 9071 – 9077.
91. Dai-Rong Liu,^a+Zi-Hao Gao,^a+Wen-Wen Zi,^aJun Zhang,^cHong-Bin Du,*^aand Fei-Jian Chen*^ab, Facile synthesis of large-pore zeolite ITQ-26 by using an easily-available imidazolium as structure-directing agent, Microporous and Mesoporous Materials, 2019, 276, 232-238.
90. Fei Wang, Wenwen Zi, Bao Xun Zhao and Hong Bin Du*, Facile solution synthesis of red phosphorus nanoparticles for lithium ion battery anodes, Nanoscale Research Letters, 2018,13, 356.
89. JunRan Jia,^aMengKe Zhai,^aJingJing Lv,^bBaoXun Zhao,^aHongBin Du,*^aJunJie Zhu*^b, Nickel molybdenum nitride nanorods grown on Ni foam as efficient and stable bifunctional electrocatalysts for overall water splitting, ACS Appl. Mater. Interfaces, 2018, 10 (36), 30400–30408.
88. Mengke Zhai, Fei Wang, Hongbin Du*, Transition metal phosphide-carbon nanosheet composites derived from 2-dimensional metal-organic frameworks for highly efficient electrocatalytic water-splitting, ACS Appl. Mater. Interfaces, 2017, 9(46), 40171–40179.
87. Lin Sun, Fei Wang, Tingting Su, and Hongbin Du*, Room-temperature solution synthesis of mesoporous silicon for lithium ion battery anodes, ACS Appl. Mater. Interfaces, 2017, 9(46), 40386–40393.
86. Lin Sun, Fei Wang, Tingting Su and Hongbin Du*, Step-by-step assembly preparation of core-shell Si-mesoporous TiO₂composite nanospheres with enhanced lithium-storage properties, Dalton Trans., 2017, 46, 11542–11546.
85. Lei Xu, Meng-Ke Zhai, Xin-Chao Lu, Hong-Bin Du*, A robust indium-porphyrin framework for CO2capture and chemical transformation, Dalton Trans., 2016, 45, 18730–18736.
84. Lei Xu, Meng-Ke Zhai, Fei Wang, Lin Sun, Hong-Bin Du*, A series of robust metal-porphyrinic frameworks based on rare earth clusters and their application in N-H carbene insertion, Dalton Trans., 2016, 45, 17108–17112.
83. Zihao Gao,⁺Fei-Jian Chen,⁺Lei Xu, Lin Sun, Yan Xu,* and Hong-Bin Du*, A stable, extra-large-pore zeolite with intersecting 14- and 10-membered ring channels, Chem. Eur. J., 2016, 22, 14367–14372.
82. Fei-Jian Chen, Qing-Fang Lin, Zi-Hao Gao, Fu-Zhi Shen, Li-Li Liang, Zhen Yang,* Hong-Bin Du*, Synthesis of large zeolite crystals through slow release of structure-directing agents, Chin. J. Inorg. Chem., 2016, 32(7), 1283–1292.
81. Lei Xu, Yanping Luo, Lin Sun, Shan Pu, Min Fang,* Rong-Xing Yuan, Hong-Bin Du*, Tuning the properties of metal-organic framework UiO-67-bpy via post-synthetic N-quaternization of pyridine sites, Dalton Trans., 2016, 45, 8614–8621.
80. Fei-Jian Chen, Zi-Hao Gao, Li-Li Liang, Jun Zhang and Hong-Bin Du*, Facile preparation of extra-large pore zeolite ITQ-37 based on supramolecular assemblies as structure-directing agents, CrystEngComm, 2016, 18, 2735–2741.
79. Lei Xu, Yan-Ping Luo, Lin Sun, Yan Xu, Zhong-Sheng Cai, Min Fang*, Rong-Xin Yuan, Hong-Bin Du*, Highly stable mesoporous zirconium porphyrinic frameworks with distinct flexibility, Chem. Eur. J., 2016, 22, 6268–6276.
78. Lin Sun, Tingting Su, Lei Xu, Meipin Liu and Hong-Bin Du*, Two-dimensional ultra-thin SiO_x(0 < x < 2) nanosheets with long-term cycling stability as lithium ion battery anodes , Chem. Commun., 2016, 52, 4341–4344.
77. Lin Sun, Tingting Su, Lei Xu and Hong-Bin Du*, Preparation of uniform Si nanoparticles for high-performance Li-ion battery anodes, Phys. Chem. Chem. Phys., 2016, 18(3), 1521–1525.
76. Mei-Pin Liu, Yan-Ping Luo, Lei Xu, Lin Sun and Hong-Bin Du*, Hollow-structured Si/SiC@C nanospheres as highly active catalysts for cycloaddition of epoxides with CO₂under mild conditions, Dalton Trans., 2016, 45(6), 2369–2373.
75. Mei-Pin Liu, Tingting Su, Lin Sun and Hong-Bin Du*, Facile preparation of yolk-shell structured Si/SiC@C@TiO₂nanocomposites as highly efficient photocatalysts for degrading organic dye in wastewater, RSC Advances, 2016, 6(5), 4063–4069.
74. Li-Li Liang, Lei Xu, Yan-Chun Xue, Fei-Jian Chen, Hong-Bin Du*, An unprecedented twelve-connected 3D metal-organic framework based on heptanuclear cobalt cluster building blocks, Inorg. Chem. Commun., 2015, 62, 98–102.
73. Shan Pu, Lei Xu, Lin Sun, Hongbin Du*, Tuning the optical properties of the zirconium–UiO-66 metal–organic framework for photocatalytic degradation of methyl orange, Inorg. Chem. Commun., 2015, 52, 50–52.
72. Mei-Pin Liu, Yu-Xiang Hu, Hong-Bin Du*, Layered titanosilicates as energy storage anode materials for lithium Ion batteries, Chin. J. Inorg. Chem., 2015, 31(12), 2425–2431.
71. Yun-Shan Xue, Yan Xu, Hong-Bin Du*, Structural diversity of coordination polymers built from a rigid from a rigid silicon-based tetracarboxylate Linker, Chin. J. Inorg. Chem., 2015, 31(5), 981–988.
70. Fei-Jian Chen, Yan Xu, and Hong-Bin Du*, An extra-large pore zeolite with intersecting 18-, 12- and 10-membered ring channels, Angew. Chem. Int. Ed.,2014, 53, 9592–9596.
69. Lian Zhou, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Synthesis and properties of four coordination polymers built from a semi-rigid tripod carboxylic acid, CrystEngComm., 2013, 15, 8989–8997.
68. Lian Zhou, Cheng-Cheng Zhu, Yun-Shan Xue, Wei-Jiang He, Hong-Bin Du,* Xiao-Zeng You and Yi-Zhi Li, Two fluorescent 2,6-substituted pyridyl boron-dipyrromethene dyes for selective sensing of cuprous ions, Inorg. Chem. Commun., 2013, 35, 355–359.
67. Lian Zhou, Yun-Shan Xue, Yan Xu, Jun Zhang, Hong-Bin Du*, Two photoluminscent metal-organic frameworks based on a BODIPY-derived bipyridine ligand, CrystEngComm, 2013, 15, 7315–7320.
66. Lian Zhou, Yun-Shan Xue, Jun Zhang, Hong-Bin Du,* Xiao-Zeng You, Construction of three-dimensional metal-organic frameworks in the presence of a tetrahedral ligand and a secondary bidentate linker, CrystEngComm, 2013, 15, 6199–6206.
65. Yun-Shan Xue, Lian Zhou, Mei-Pin Liu, Su-Meng Liu, Yan Xu, Hong-Bin Du,* Xiao-Zeng You, Construction of lanthanide metal-organic frameworks with highly-connected topology based on a tetrapodal linker, CrystEngComm, 2013, 15, 6229–6236.
64. Yun-Shan Xue, Yabing He, Lian Zhou, Fei-Jian Chen, Yan Xu, Hong-Bin Du,* Xiao-Zeng You, Banglin Chen, A photoluminescent microporous metal organic anionic framework for nitroaromatic explosive sensing, J. Mater. Chem. A, 2013, 1, 4525–4530.
63. Gen-Wu Ge, Zhi-Yuan Qi, Yu-Run Miao, Hong-Bin Du,* Xiao-Zeng You, The synthesis, structure and magnetism studies of two manganese sulfates with a 3D zeolite GIS framework and 1D chain structure, CrystEngComm, 2013, 15, 423–630. (Inside front cover)
62. Yun-Shan Xue, Feng-Yan Jin, Lian Zhou, Mei-Pin Liu, Yan Xu, Hong-Bin Du,* Min Fang,* Xiao-Zeng You, Structural diversity and properties of coordination polymers built from a rigid octadentenate carboxylic acid, Cryst. Growth Des., 2012, 12, 6158?6164.
61. Jun Zhang, Yun-Shan Xue, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Four cluster-based coordination polymers built on a semirigid tripod tricarboxylate ligand, CrystEngComm, 2012, 14, 8215–8221.
60. Jun Zhang, Yun-Shan Xue, Hong-Mei Wang, Min Fang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Three open-framework coordination polymers with new topological structures built on two tripod ligands, Inorg. Chim. Acta2012, 392, 148–152.
59. Gen-Wu Ge, Zhi-Yuan Qi, Zhi-Gang Ni, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Solvothermal synthesis, structure and characterization of 1D chain and 2D layered rare earth sulfates in the presence of cyclic diamines,Inorg. Chem. Commun. 2012, 20, 228–233.
58. Mei-Pin Liu, Cheng-Hui Li, Hong-Bin Du,* Xiao-Zeng You, Facile preparation of silicon hollow spheres and their use in electrochemical capacitive energy storage, Chem. Commun. 2012, 48, 4950–4952. (Back cover)
57. Gen-Wu Ge, Yu-Xiang Hu, Mei-Pin Liu, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, The crystal structure and characterization of 2-D and 3-D indium phosphates synthesized from a water/ethylene glycol mixed-solvent system, Inorg. Chem. Acta2012, 385, 39–44.
56. Yun-Shan Xue, Yanfeng Yue, Shi-Bin Ren, Le Zhou, Jun Zhang, Yi-Zhi Li, Hong-Bin Du,* Xiao-Zeng You, Banglin Chen*, Flexible octadentate ligand based robust microporous metal-organic frameworks with high gas storage and selective adsorption properties, J. Mater. Chem. 2012, 22, 10195–10199.
55. Ling-Ling Qu, You-Long Zhu, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Structural diversity and properties of coordination polymers built from a semirigid tetradentenate carboxylic acid, CrystEngComm2012, 14, 824–831. (Top 10 Most Accessed Articles in November 2011).
54. Hong-Bin Du, Xiao-Zeng You, Design and synthesis of functional coordination compounds with optoelectronic properties (Review), Huaxue Tongbao, 2011, 74(11), 989–994(Invited, in Chinese)（国际化学年在中国专栏）.
53. Jun Zhang, Yun-Shan Xue, Jing Bai, Min Fang, Yi-Zhi Li, Hong-Bin Du,* Xiao-Zeng You, An unprecedented (3,7)-connected microporous solvatochromic coordination polymer built on a semirigid tripod pyridinium-4-olate ligand, CrystEngComm, 2011, 13, 6010–6012.
52. You-Long Zhu, Ling-Ling Qu, Jun Zhang, Gen-Wu Ge, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, In situ formation of an unprecedented 3D microporous CuCN coordination polymer based on a semirigid tetrahedral linker, Inorg. Chem. Commun., 2011, 14, 1644–1647.
51. Ling-Ling Qu, You-Long Zhu, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Solvent-controlled synthesis of zinc(II) and manganese(II) coordination polymers with a semirigid tetracarboxylic acid, Crystal Growth & Design, 2011, 11(6), 2444–2452. ( Top 10 Most Read Articles for Q2 2011)
50. Gen-Wu Ge, Mei-Pin Liu, Zhi-Gang Ni, Hong-Bin Du*, Synthesis, characterization and fluorescent study of two 3-D open-framework rare-earth sulfates [Ln₄(H₂O)₄(SO₄)₁₀] (C₄N₂H₁₂)₄(H₂O)₄(Ln = Gd, Eu), Chemical Journal of Chinese Universities, 2011, 32(3), 644–649(Invited, in Chinese) .
49. Jun Zhang, Yun-Shan Xue, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Cuprous iodide coordination polymers (CuI)_x(L)_y.z(solvent) built on linear thioether linkers, CrystEngComm, 2011, 13, 2578–2585.
48. Shi-Bin Ren, Le Zhou, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, A Cu₄(SCN)₄Cubane Cluster-Based Microporous Coordination Polymer with a Diamond Net, Inorg. Chem. Commun., 2011, 14, 558–561.
47. Li-Li Liang, Shi-Bin Ren, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Two Thermostable Three-Dimensional Homochiral Metal-Organic Polymers with Quartz Topology, Crystal Growth & Design, 2010, 10(3), 1307–1311.
46. Shi-Bin Ren, Le Zhou, Jun Zhang, You-Long Zhu, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, A 4-connected 3D porous coordination polymer with a binodal 6^2.8^4 net built on tetrahedral quadridentate and bidentate linkers, CrystEngComm, 2010, 12(5), 1635–1638.
45. Xiao-Li Yang, Jun Zhang, Yi-Zhi Li, Hong-Bin Du,* Xiao-Zeng You*, Synthesis and characterization of two 2D layered new coordination polymers of Co/Ni with the ligand of 1,4-bis(imidazol-1-ylmethyl)benzene, Chinese Journal of Inorganic Chemistry, 2010, 26(3), 374–378(in Chinese).
44. Xiao-Li Yang, Jun Zhang, Shi-Bin Ren, Yi-Zhi Li, Hong-Bin Du,* Xiao-Zeng You*, A three-dimensional semiconducting superlattice built up of neutral [Zn₁₀(μ3-S)₄(SPhMe-4)₁₂(DMF)₄] supertetrahedral clusters, Inorg. Chem. Commun. 2010, 13(4), 546–549.
43. Li-Li Liang, Jun Zhang, Shi-Bin Ren, Gen-Wu Ge, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Rational synthesis of a microporous metal-organic framework with PtS topology using a semi-rigid tetrahedral linker, CrystEngComm, 2010, 12(7), 2008–2010.(CDG Structure of the Week)
42. Li-Li Liang, Shi-Bin Ren, Jun Wang, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, A 3-dimensional coordination polymer with a fluorite structure constructed from a semi-rigid tetrahedral ligand, CrystEngComm, 2010, 12, 2669–2671.
41. Li-Li Liang, Shi-Bin Ren, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Two unprecedented NLO-active coordination polymers constructed by a semi-rigid tetrahedral linker, Dalton Trans., 2010, 39(33), 7723–7726.
40. Jun Zhang, Yun-Shan Xue, Li-Li Liang, Shi-Bin Ren, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Porous Coordination Polymers of Transition Metal Sulfides with PtS Topology Built on a Semi-rigid Tetrahedral Linker, Inorg. Chem., 2010, 49, 7685–7691.
39. Xiao-Li Yang, Jun Zhang, Shi-Bin Ren, Yi-Zhi Li, Wei Huang, Hong-Bin Du*, Xiao-Zeng You, A Two-Dimensional Layered Cadmium Sulfide Superlattice Constructed from Capped-Supertetrahedral C1 Clusters, Inorg. Chem. Commun. 2010, 13(11), 1337–1339.
38. Shi-Bin Ren, Xiao-Li Yang, Jun Zhang, Yi-Zhi Li, You-Xuan Zheng, Hong-Bin Du*, Xiao-Zeng You, An infinite photoluminescent coordination nanotube [CuSCN(L)].(DMF)(0.5), CrystEngComm, 2009, 11(2), 246–248.
37. Shi-Bin Ren, Jun Zhang, Xiao-Li Yang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, A single-helix copper-containing coordination polymer of dihydroglyoxaline sulfide formed in situ through oxidation of 1,3-imidazolidine-2-thione, J. Mol. Structr., 2009, 923(1-3), 90–93.
36. Shi-Bin Ren, Le Zhou, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, A photoluminescent interpenetrating diamondoid metal–organic framework based on Cu₄I₄clusters with high thermal stability, CrystEngComm, 2009, 11, 1834–1836.
35. Xiao-Li Yang, Shi-Bin Ren, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Syntheses and structures of three coordination polymers based on 4-methylbenzenethiolates of Zn(II) and Cd(II) and bipyridine, J. Coord. Chem., 2009, 62(23), 3782–3794.
34. Yan Liu, Xiao-Li Yang, Jun Zhang, Yi-Zhi Li, You Song, Hong-Bin Du*, Xiao-Zeng You, Synthesis of an open-framework copper–germanium phosphate [Cu(H₂O)₂(OH)]₂Ge(PO₄)₂, Chem. Commun., 2008, (17), 3145–3147.
33. Yan Liu, Xiao-Li Yang, Gui-Li Wang, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, Synthesis and characterization of a cadmium germanium phosphate CdGe(OH)₃PO₄with an open framework, J. Solid State Chem.2008, 181, 2542– 2546.
32. Gui-Li Wang, Xiao-Li Yang, Yan Liu, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, A 3d–3d heterometallic organic framework consisting of two cross-linked coordination polymers, Inorg. Chem. Commun., 2008, 11, 814–817.
31. Gui-Li Wang, Xiao-Li Yang, Jun Zhang, Yi-Zhi Li, Hong-Bin Du*, Xiao-Zeng You, The syntheses of 3d–3d mixed heterometallic coordination polymers with magnetic properties, Inorg. Chem. Commun., 2008, 11, 1430–1430.
Papers before joining Nanjing University：
30. Hong Yang,* Honglin Chen, Hongbin Du, Randall Hawkins, Fairbridge Craig, Zbigniew Ring, Oladipo Omotoso, Vicente Munoz, Randy Mikul, Incorporating platinum precursors into a NaA-zeolite synthesis mixture promoting the formation of nanosized zeolite, Microporous and Mesoporous Materials, 2009, 117, 33-40.
29. Scott Brownridge, Margaret-Jane Crawford, Hongbin Du, Richard D. Harcourt*, Carsten Knapp, Risto S. Laitinen, Jack Passmore,* J. Mikko Rautiainen*, Reijo J. Suontamo, Jussi Valkonen, Accounting for the Differences in the Structures and Relative Energies of the Highly Homoatomic npi-npi (n>=3)-Bonded S₂I₄²⁺, the Se-I pi-Bonded Se₂I₄²⁺, and Their Higher-Energy Isomers by AIM, MO, NBO, and VB Methodologies, Inorg. Chem. 2007, 46(3): 678-699.
28. Nobumasa Nakajima, Cecile Lay, Hongbin Du, Zbigniew Ring*, Prediction of Gas Chromatographic Retention Times of Carbazoles in Light Cycle Oil, Energy & Fuels, 2006, 20(3), 1111-1117.
27. Hongbin Du*, Craig Fairbridge, Hong Yang, Zbigniew Ring, The Chemistry of Selective Ring Opening Catalysts (Review), Applied Catalysis A: General, 2005, 294(1): 1-21.
26. Scott Brownridge, T. Stanley Cameron, Hongbin Du, Carsten Knapp, Ralf K?ppe, Jack Passmore*, J. Mikko Rautiainen, Hansgeorg Schn?ckel, The Highest Bond Order between Heavier Main-Group Elements in an Isolated Compound? Energetics and Vibrational Spectroscopy of S₂I₄(MF₆)₂(M = As, Sb), Inorg. Chem.2005, 44(6): 1660-1671. (Reported by C&EN2005, March 21, p49-50; Canadian Chemical News2005, May, p17).
25. Hongbin Du*, Zbigniew Ring, Yevgenia Briker, Patricia Arboleda, Prediction of gas chromatographic retention times and indices of sulfur compounds in light cycle oil, Catalysis Today2004, 98(1-2): 217-225.
24. Hongbin Du, Robert C. Haddon, Ingo Krossing, Jack Passmore*, Jeremy M. Rawson, Melbourne J. Schriver, Thermally hysteresis in dithiadiazolyl and dithiazolyl radicals induced by supercooling of paramagnetic liquids close to room temperature: A study of F₃CCNSSN and an interpretation of the behaviour of F₃CCSNSCCF₃, Chem. Commun. 2002, 1836-1837.
23. Hongbin Du, Victor V. Terskikh, Christopher I. Ratcliffe*, John A. Ripmeester, Distinguishing surface versus buried cation sites in aluminosilicate mesoporous materials, J. Am. Chem. Soc. 2002, 124, 4216-4217.
22. Nicholas F. Szabo, Hongbin Du, Sheikh A. Akbar, Ahmed Soliman, Prabir K. Dutta*, Microporous zeolite modified yttria stabilized zirconia (YSZ) sensors for nitric oxide (NO) determination in harsh environments, Sensors and Actuators B: Chemicals, 2002, 82, 142-149.
21. Victor V. Terskikh, Igor L. Moudrakovski, Hongbin Du, Christopher I. Ratcliffe*, John A. Ripmeester, The ¹²⁹Xe chemical shift tensor in a silicalite single crystal from hyperpolarized ¹²⁹Xe NMR spectroscopy, J. Am. Chem. Soc. 2001, 123, 10399-10400.
20. T. Stanley Cameron, Robert J. Deeth, Isabelle Dionne, Hongbin Du, H. Donald B. Jenkins, Ingo Krossing, Jack Passmore,* Helen K. Roobottom, Bonding, structure, and energetics of gaseous E₈²⁺and of solid E₈(AsF₆)₂(E = S, Se),Inorg. Chem. 2000, 39 (25): 5614-5631.
19. Scott Brownridge, Hongbin Du, Shirley A. Fairhurst, Robert C. Haddon, Heinz Oberhammer, Simon Parsons, Jack Passmore*, Melbourne J. Schriver, Leslie H. Sutcliffe, Nicholas P. C. Westwood, The isolation, characterisation, gas phase electron diffraction and crystal structure of the thermally stable radical [CF₃CSNSCCF₃], J. Chem. Soc., Dalton Trans. 2000, (19): 3365-3382.
18. Yunling Liu, Hongbin Du, Feng-Shou Xiao, Guangshan Zhu, Wenqin Pang*, Synthesis and characterization of a novel microporous titanosilicate JLU-1, Chem. Mater. 2000, 12(3): 665-670.
17. F.S. Xiao, R. Yu, H. Du, S. Qiu, W. Pang*, R. Xu, Catalytic activity in phenol conversion over novel catalysts of microporous lead titante (JPT-1) and layered titanosilicate (JDF-L1), Proceedings of the 12th International Zeolite Conference, Editors: M. M. J. Treacy, B. K. Marcus, M. E. Bisher, J. B. Higgins, 1999, Vol. 2, 1277-1282.
16. Yunling Liu, Hongbin Du, Yihua Xu, Hong Ding, Wenqin Pang*, Yong Yue, Synthesis and characterization of a novel microporous titanosilicate with a structure of penkvilksite-1M, Microporous and Mesoporous Materials1999, 28, 511–517.
15. Ian D. Williams*, Jihong Yu, Hongbin Du, Jiesheng Chen, Wenqin Pang*, A metal-rich fluorinated indium phosphate, 4[NH₃(CH₂)₃NH₃]*3[H₃O]*[In₉(PO₄)₆(HPO₄)₂F₁₆]*3H₂O, with 14-membered ring channels, Chem. Mater.1998, 10(3), 773-776.
14. Hongbin Du, Jiesheng Chen,Wenqin Pang*, Synthesis of various indium phosphates in the presence of amine templates, Stud. Surf. Sci. Catal. 1997, 105, 397-404.
13. L.L. Koh, Yan Xu, Hongbin Du,W.Q. Pang*, New insights into the study of indium phosphate molecular sieves, Stud. Surf. Sci. Catal. 1997, 105, 373-380.
12. Yunlin Liu, Hongbin Du, Fengqi Zhou,Wenqin Pang*, Synthesis of a new titanosilicate: an analogue of the mineral penkvilksite, J. Chem. Soc., Chem. Commun.1997, 1467-1468.
11. Hongbin Du, Jiesheng Chen, Wenqin Pang*, Jihong Yu, Ian D. Williams*, Synthesis and structural characterization of 2-D and 3-D fluorinated indium phosphates, J. Chem. Soc., Chem. Commun.1997, 781-782.
10. Hongbin Du, Min Fang, Yunling Liu, Shilun Qiu,Wenqin Pang*, Synthesis and characterization of large pore vanadium aluminosilicate Beta molecular sieves, Zeolites, 1997, 18(5/6), 334-339.
9. Hongbin Du, Min Fang, Wenguo Xu, Xianping Meng,Wenqin Pang*,Preparation by microwave irradiation of nanometer sized AlPO₄-5 molecular sieve, Journal of Materials Chemistry,1997, 7(3), 551-556.
8. Min Fang, Hongbin Du, Wenguo Xu, Xianping Meng, Wenqin Pang*,Microwave preparation of molecular sieve AlPO₄-5 with nanometer sizes,Microporous Materials, 1997, 9, 59-61.
7. Hongbin Du, Min Fang, Jiesheng Chen,Wenqin Pang*, Synthesis and characterization of a novel layered titanium silicate JDF-L1, Journal of Materials Chemistry, 1996, 6(11), 1827-1830.
6. M.A. Roberts, G. Sankar, J.M. Thomas*, R.H. Jones, H. Du, J. Chen, W. Pang,*R. Xu, Synthesis and structure of a layered titanosilicate catalyst with five-coordinate titanium,Nature, 1996, 381, 401-404.(Reported byC&EN1996, July 29, 47-49Highlighted by Angew. Chem. Int. Ed. Engl. 1997, 36(5), 477-479).
5. Hongbin Du, Fengqi Zhou, Wenqin Pang,*Yong Yue,Synthesis and characterization of titanium silicate molecular sieves with zorite-type structure, Microporous Materials, 1996, 7, 73-80.
4. Yunlin Liu, Du Hongbin, Zhou Fengqi, Pang Wenqin*, Synthesis of titanium silicalite-I zeolite using n-butylamine as a templating agent, Acta Petroleum Sinica (Petroleum Processing Section), 1996, 12(4), 26-29 (in Chinese).
3. Du Hongbin, Qiu Shilun, Pang Wenqin*, Syntheses of ferrerite and mordenite zeolites from dried gel in alcoholic system, Chemical Research in Chinese Universities, 1995, 11(4), 364-366.
2. Du Hongbin, Zhou Qun, Zhou Fengqi, Pang Wenqin*,Study on the synthesis and structure of Cu-ZSM-5 type molecular sieve, Wuli Huaxue Xuebao (Acta Physico-Chimica Sinica), 1994, 10(7), 635-638 (in Chinese).
1. Du Hongbin, Tu Kungang, Zhou Qun, Zhou Fengqi, Pang Wenqin*, Synthesis and characterization of V-ZSM-5 zeolites in weak acidic medium, Chemical Journal of Chinese Universities, 1994, 15(4), 473-477 (in Chinese).
Patent Applications:
1. Poteniometric NOx sensors based on yttria-stablized zirconia with zeolites modified electrode, Prabir K. Dutta, Nicholas F. Szabo, Hongbin Du, Sheikh A. Akbar, US Patent 6,843,900, 2005. (Licensed)
2. 一种空心球状硅纳米材料的制备方法, 刘美玭, 杜红宾, 游效曾, 申请号: 2.8, 2011.
3. 一种硅纳米管的制备方法, 刘美玭, 杜红宾, 游效曾, 申请号: 0.X, 2011. 授权公告号CN B (2012.10.17).
4. 一种钛硅酸锂及其制法和作为锂电池电极材料的用途, 杜红宾, 胡宇翔, 刘美玭, 申请号: 4.2, 2012.
5. 一种超大孔硅酸盐分子筛NUD-1及其制备方法, 杜红宾, 陈飞剑, 申请号: 7.2, 2014.授权公告号CN B (2016.05.11).
6. 一种硅纳米材料及其用途, 杜红宾, 孙林, 申请号: 2.5, 2015.授权公告号CN B (2017.10.20).
7. 一种二维纳米硅片的制备方法及其用途, 杜红宾, 孙林, 申请号: 7.1, 2015.授权公告号CN B (2017.10.20)
8. 一种多孔硅纳米材料及其制备方法和用途, 杜红宾, 孙林, 申请号: 1.5, 2016.授权公告号CN B (2019.8.2)
9. 一种大孔硅酸盐分子筛及其制备方法, 杜红宾, 陈飞剑, 刘代融, 高子豪, 胡诗宇, 訾文文, 申请号: 3.8, 2017.授权公告号CN B (2019.7.16)
10. 一种超大孔硅酸盐分子筛的制备方法, 杜红宾, 陈飞剑, 高子豪, 刘代融, 訾文文, 申请号: 5.2, 2017.授权公告号CN B (2019.10.01)
11. 一种氮化钼纳米棒电极材料及其制备方法和用途, 杜红宾, 贾珺然, 朱俊杰, 申请号: 1.8, 2017.授权公告号CN B (2020.4.24)
12. 一种硅纳米材料及其制备方法和用途, 杜红宾, 汪飞，申请号: 20**280, 2018.
13. 一种超大孔硅酸盐分子筛NUD-6及其制备方法, 杜红宾, 陈飞剑, 高子豪, 訾文文，申请号: 20**710, 2018.
14. 一种硅石墨烯框架复合材料的制备方法和用途, 杜红宾, 宋长生，申请号: 3X, 2020.




课程名称、上课时间地点


大学化学IB （春季）
化学与材料 （秋季）

教学大纲、考试要求




教学资源（上课讲义、参考资料等）





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