姓名

华远照

性别

男

出生年月

1979/07

职称

讲师

民族

汉

籍 贯

河南南阳

电子邮箱

hyzhao@zzu.edu.cn

最终学位

博士

学术头衔/兼职

无

研究方向

新手性配体的设计与合成、不对称催化合成方法学研究

主要学习、科研和工作经历

教育经历：

2011/09—2015/07：郑州大学化学与分子工程学院，有机化学，理学博士；

2002/09—2005/07：郑州大学化学系，有机化学，理学硕士；

1998/09—2002/07：郑州大学化学系，化学本科。

工作经历：

2016/08—至今，郑州大学，化学学院，讲师（校聘副教授）

2008/07—2011/09，新乡医学院，基础医学院，讲师；

2005/07—2008/07，新乡医学院，基础医学院，助教；

代表性

教学成果与荣誉

多次获网评优秀教师

代表性

科研成果

主持或参加科研项目：

1.国家自然科学基金面上项目，**，双核锌协同催化的不对称串联反应研究，2019/01—2022/12，65万元，在研，参与

2.中国博士后科学基金面上二等资助，2017M622361，半冠状多齿双噁唑啉手性配体的设计、合成及应用，2018/01-2019/12，5万元，在研，主持

3.国家自然科学基金面上项目，**，二氧化碳与环氧化物的催化不对称交替共聚反应研究，2012/01—2016/12，80万元，已结项，参与

科研论文：

1. Ya-Jun Guo, Xin Guo, De-Zhi Kong, Hui-Jie Lu, Lan-Tao Liu, Yuan-Zhao Hua,⁽*⁾ and Min-Can Wang⁽*⁾. Catalytic Asymmetric Synthesis of Tetrahydrofuran Spirooxindoles 2 via a Dinuclear Zinc Catalyst[J]. J. Org. Chem. 2020, 85, doi.org/10.1021/acs.joc.9b03378

2. Xiao-Chao Yang, Meng-Meng Liu, François Mathey, Hua Yang, Yuan-Zhao Hua⁽*⁾, Min-Can Wang⁽*⁾. Access to Chiral 2,5-Pyrrolidinyl Dispirooxindoles via Dinuclear Zinc-Catalyzed Asymmetric Cascade Reactions[J]. J. Org. Chem. 2019, 84, 7762−7775.

3. Meng-Meng Liu, Xiao-Chao Yang, Yuan-Zhao Hua,⁽*⁾ Jun-Biao Chang⁽*⁾, Min-Can Wang.⁽*⁾ Dinuclear Zinc-Catalyzed Asymmetric Tandem Reaction of α-Hydroxy-1-indanone: Access to Spiro[1-indanone-5,2′-γ-butyrolactones][J]. Org. Lett. 2019, 21, 7089-7093.

4. Meng-Meng Liu, Xiao-Chao Yang, Yuan-Zhao Hua, Jun-Biao Chang⁽*⁾, Min-Can Wang⁽*⁾. Synthesis of Chiral Bispirotetrahydrofuran Oxindoles by Cooperative Bimetallic-Catalyzed Asymmetric Cascade Reaction[J]. Org. Lett. 2019, 21, 2111−2115.

5. Bing-Kai Tao, Hua Yang, Yuan-Zhao Hua⁽*⁾, Min-Can Wang⁽*⁾. Dinuclear zinc synergistic catalytic asymmetric phospha-Michael/Michael cascade reaction: synthesis of 1,2,3-trisubstituted indanes bearing phosphoryl groups[J]. Org. Biomol. Chem. 2019, 17, 4301−4310.

6. Yu-Hang Miao, Yuan-Zhao Hua and Min-Can Wang⁽*⁾. Dinuclear zinc cooperative catalytic three-component reactions for highly enantioselective synthesis of 3,3’-dihydrofuran spirooxindoles[J]. Org. Biomol. Chem. 2019, 17, 7172–7181.

7. Yuan-Zhao Hua, Jun-Wei Chen, Hua Yang^(*), and Min-Can Wang^(*). Asymmetric Friedel–Crafts Alkylation of Indoles with Trifluoromethyl Pyruvate Catalyzed by a Dinuclear Zinc Catalyst[J]. J. Org. Chem. 2018, 83, 1160–1166.（中科院化学二区）

8. Yuan-Yuan Gao, Yuan-Zhao Hua^(*), Min-Can Wang^(*). Asymmetric 1,6-Conjugate Addition of para-Quinone Methides for the Synthesis of Chiral β,β-Diaryl-α-Hydroxy Ketones[J]. Adv. Synth. Catal. 2018, 360, 80–85.

9. Na Shao, Yong-Yang Luo, Hui-Jie Lu, Yuan-Zhao Hua⁽*⁾, Min-Can Wang^(*). Enantioselective phospha-Michael reaction of diethyl phosphonate with exocyclic α,β-unsaturated benzocyclic ketones catalyzed by a dinuclear zinc−AzePhenol catalyst[J]. Tetrahedron 2018, 74, 2130-2142.

10. Yuan-Zhao Hua, Xing-Wang Han, Li-Hua Huang^(*), Min-Can Wang^(*). Asymmetric Friedel-Crafts Alkylation of Pyrrole with Chalcones Catalyzed by a Dinuclear Zinc Catalyst[J]. Chin. J. Org. Chem. 2018, 38, 237–248.

11. Xin-Wei Wang, Yuan-Zhao Hua^(*), Min-Can Wang^(*). Synthesis of 3-Indolylglycine Derivatives via Dinuclear Zinc Catalytic Asymmetric Friedel-Crafts Alkylation Reaction[J]. J. Org. Chem. 2016, 81, 9227–9234.

12. Yuan-Zhao Hua, Xiao-Chao Yang, Meng-Meng Liu, Xixi Song, Min-Can Wang^(*) and Jun-Biao Chang^(*). Asymmetric Copolymerization of Cyclopentene Oxide and CO₂ Using a Dinuclear Zinc-AzePhenol Catalyst: Enlightened by DFT Calculations[J]. Macromolecules 2015, 48, 1651–1657.

13. Yuan-Zhao Hua, Meng-Meng Liu, Pei-Jin Huang, Xi-Xi Song, Min-Can Wang^(*), and Jun-Biao Chang^(*).A New Strategy for Enantioselective Construction of Multisubstituted Five-Membered Oxygen Heterocycles via a Domino Michael/Hemiketalization Reaction [J]. Chem.–Eur. J. 2015, 21, 11994–11998.

14. Yuan-Zhao Hua, Liu-Jie Lu, Pei-Jin Huang, Dong-Hui Wei, Ming-Sheng Tang, Min-Can Wang^(*), and Jun-Biao Chang^(*). Highly Enantioselective Catalytic System for Asymmetric Copolymerization of Carbon Dioxide and Cyclohexene Oxide[J]. Chem.–Eur. J. 2014, 20, 12394–12398.

15. Yuan-Zhao Hua, Xing-Wang Han, Xiao-Chao Yang, Xixi Song, Min-Can Wang^(*), and Jun-Biao Chang^(*). Enantioselective Friedel−Crafts Alkylation of Pyrrole with Chalcones Catalyzed by a Dinuclear Zinc Catalyst[J]. J. Org. Chem. 2014, 79, 11690–11699.

专利申请：

1. 华远照，杨小超，王瑞丽，刘萌萌，耿宇欢，郭亚军，王敏灿。一种手性氮杂半冠醚多齿配体及其制备方法与应用。中国专利，申请号：**5729.6

2. 华远照，杨小超，耿宇欢，刘萌萌，王瑞丽，郭亚军，王敏灿。一种手性3,2’-四氢吡咯双螺氧化吲哚衍生物及其制备方法。中国专利，申请号：**4305.8