张绪穆
出生年月：1961.10
学历与职称：所长、教授、博士生导师
专业方向：有机化学
电话：**
Email：xumu@whu.edu.cn
教育与研究经历
1978-1982武汉大学学士；

1982-1985中国科学院福建物质结构研究所硕士；

1985-1987加利福尼亚州立大学圣地亚哥分校硕士；

1987-1992斯坦福大学博士；

1992-1994斯坦福大学博士后；

1994-2006美国宾夕法尼亚州州立大学教授；

2007-美国新泽西州立罗格斯大学杰出教授；

2005-武汉大学****讲座教授；

2008-武汉大学“高等学校学科创新引智计划”学术大师；

2005-武汉大学化学与分子科学学院绿色催化研究所所长；

2011-武汉大学国家“****”特聘专家。
研究领域与兴趣
1、发展高效、高选择性不对称催化反应手性配体工具箱；

2、发展高效、高选择性的化学催化反应（不对称氢化、不对称氢甲酰化、线性氢甲酰化、酯基以及酰胺类化合物的绿色还原等）；

3、催化反应在重要的药物中间体和生物活性天然产物合成中的应用。
武汉大学绿色催化研究所招聘信息

招聘对象：

A.以张绪穆老师领导的青年“千人”（教授），独立研究方向

B.张绪穆实验小组的副教授（工作助手）

C.张绪穆实验小组的博士后（国内工作一段时间后可推荐至国外知名院校继续博士后研究工作）

D.有致力于绿色催化研究的博士生
教学情况
承担项目与课题
学术兼职
代表性成果
1.CatalyticEnantioselectiveDesymmetrizationofMesoCyclicAnhydridesviaIridium-CatalyzedHydrogenation.Liu,T.L.;Li,W.;Geng,H.L.;Wang,C.J.;Zhang,X.M.OrganicLetters.2013,15,1740.
2.Rhodium-CatalyzedAsymmetricHydroformylationof1,1-DisubstitutedAllylphthalimides:ACatalyticRoutetoβ3-AminoAcids.Zheng,X.;Cao,B.N.;Liu,T.L.;Zhang,X.M.AdvancedSynthesis&Catalysis.2013,355,679.
3.CascadeSynthesisofFenpipraneandRelatedPharmaceuticalsviaRhodium-CatalyzedHydroaminomethylation.Li,S.K.;Huang,K.X.;Zhang,J.W.;Wu,W.J.;Zhang,X.M.OrganicLetters.2013,15,1036.
4.ANovelTriphosphoramiditeLigandforHighlyRegioselectiveLinearHydroformylationofTerminalandInternalOlefinsChen,C.Y.;Qiao,Y.;Geng,H.L.;Zhang,X.M.OrganicLetters.2013,15,1048.
5.Rhodium-CatalyzedEnantioselectiveHydrogenationofOximeAcetates.Huang,K.X.;Li,S.K.;Chang,M.X.;Zhang,X.M.OrganicLetters.2013,15,484.
6.Highlyenantioselectivehydrogenationofβ,β-disubstitutednitroalkenes.Li,Shengkun;Huang,Kexuan;Cao,Bonan;Zhang,Jiwen;Wu,Wenjun;Zhang,Xumu.Angew.Chem.Int.Edit.2012,51,10679.DOI:10.1002/anie.**
7.Newtetraphosphorusligandsforhighlylinearselectivehydroformylationofallylandvinylderivatives.Cai,Chaoxian;Yu,Shichao;Cao,Bonan;Zhang,Xumu.Chem.Eur.J.2012,18,DOI:10.1002/chem.**.
8.Accesstobothenantiomersofα-chloro-β-ketoesterswithasinglechiralligand:highlyefficientenantioselectivechlorinationofcyclicβ-ketoesterscatalyzedbychiralcopper(II)andzinc(II)complexesofaspiro-2,2'-bischroman-basedbisoxazolineligand.Li,Jie;Pan,Wei;Wang,Zheng;Zhang,Xumu;Ding,Kuiling.Adv.Synth.Catal.2012,354,1980.
9.Highlyenantioselectivehydrogenationofβ-ketoenamideswiththeRh-ZhangPhoscatalyst.Huang,Kexuan;Zhang,Xiaowei;Geng,Huiling;Li,Sheng-kun;Zhang,Xumu.ACSCatalysis2012,2,1343.
10.Highlyregioselectiveisomerization-hydroaminomethylationofinternalolefinscatalyzedbyRhcomplexwithTetrabi-typephosphorusligands.Liu,Guodu;Huang,Kexuan;Cao,Bonan;Chang,Mingxin;Li,Shengkun;Yu,Shichao;Zhou,Le;Wu,Wenjun;Zhang,Xumu.Org.Lett.2012,14,102.
11.HighlyregioselectivehydroaminomethylationofterminalolefinstolinearaminesusingRhcomplexeswithaTetrabiphosphorusligand.Liu,Guodu;Huang,Kexuan;Cai,Chaoxian;Cao,Bonan;Chang,Mingxin;Wu,Wenjun;Zhang,Xumu.Chem.Eur.J.2011,17,14559.
12.Ruthenium-catalyzedasymmetrichydrogenationofβ-ketoenamines:anefficientapproachtochiralγ-aminoalcohols.Geng,Huiling;Zhang,Xiaowei;Chang,Mingxin;Zhou,Le;Wu,Wenjun;Zhang,Xumu.Adv.Synth.Catal.2011,353,3039.
13.Highlyregioselectiveisomerization-hydroformylationofinternalolefinscatalyzedbyRhodium/tetraphosphinecomplexes.Cai,Chaoxian;Yu,Shichao;Liu,Guodu;Zhang,Xiaowei;Zhang,Xumu.Adv.Synth.Catal.2011,353,2665.
14.Ahighlyefficientandenantioselectiveaccesstotetrahydroisoquinolinealkaloids:asymmetrichydrogenationwithanIridiumcatalyst.Chang,Mingxin;Li,Wei;Zhang,Xumu.Angew.Chem.Int.Edit.2011,50,10679.
15.Spiro-2,2'-bichroman-basedbisoxazoline(SPANbox)ligandsforZn(II)-catalyzedenantioselectivehydroxylationofβ-ketoestersand1,3-diester.Li,Jie;Chen,Gang;Wang,Zheng;Zhang,Ruzhou;Zhang,Xumu;Ding,Kuiling.Chem.Sci.2011,2,1141.
16.Newsyntheticstrategyforhigh-enantiopurityN-protectedα-aminoketonesandtheirderivativesbyasymmetrichydrogenation.Sun,Tian;Hou,Guohua;Ma,Miaofeng;Zhang,Xumu.Adv.Synth.Catal.2011,353,253.
17.Enantioselectivesynthesisofopticallypureβ-aminoketonesandγ-arylaminesbyRh-catalyzedasymmetrichydrogenation.Geng,Huiling;Huang,Kexuan;Sun,Tian;Li,Wei;Zhang,Xiaowei;Zhou,Le;Wu,Wenjun;Zhang,Xumu.J.Org.Chem.2011,76,332.
18.SynthesisofenamidesviaCu(I)-catalyzedreductiveacylationofketoximeswithNaHSO3.Guan,Zheng-Hui;Zhang,Zhi-Yuan;Ren,Zhi-Hui;Wang,Yao-Yu;Zhang,Xumu.J.Org.Chem.2011,76,339.
发明专利：
1.“NewChiralFerrocenePhosphinesandTheirApplicationsforAsymmetricCatalyticReactions”X.Zhang,USpatent09/781,083,filedFebruary9,2001andPCT/US01/044.
2."3,3'-SubstitutedChiralBiarylPhosphinesandPhosphintesforAsymmetricCatalyticReactions”X.Zhang,U.S.Patent,filedNovember16,2001andPCTApplication.
3."NewTransitionMetalCatalyzedReactions”A.Lei,X.Zhang,U.S.ProvisionalPatent,filedMarch30,2001.
4.“NewChiralPhospholanesforAsymmetricCatalysis”X.Zhang,USPatentfiledNovember6,2001.
5.“P-chiralPhospholanesandPhosphocycliccompoundsandtheiruseinasymmetriccatalyticreactions”W.Tang,X.Zhang,USprovisionalPatent,November10,2001.
6.“AsymmetricReductiveAminationofKetones”X.Zhang,USProvisionalPatent,filedOctober25,2002.
7.“P-chiralPhospholanesandPhosphocycliccompoundsandtheiruseinasymmetriccatalyticreactions”W.Tang,X.Zhang,USPatent,November10,2002.
8.“NewChiralOxazolineLigandsforAsymmetricCatalysis”D.Liu,X.Zhang,USProvisionalPatent,December17,2003.
9.“AsymmetricHydrogenationofAlpla-aminoCarbonylCompounds”X.Zhang,USProvisionalPatent,January10,2004
10.“Preparationofchiralcyclicaminoacidsandderivatives”X.Zhang,W.Tang,USPatent**.
11.“P-ChiralPhospholanesandPhosphocyclicCompoundsandtheiruseinAsymmetricCatalyticReactionss”X.Zhang,W.Tang,USpatent**.
12.“CatalyticAsymmetricReductiveAminationofKetonesViaTransitionMetalComplexCatalystwithChiralPhosphineLigands”X.Zhang,PCT,2004,WO**.
13.“PreparationofChiralPhosphorusCyclicCompoundsforTransitionMetal-CatalyzedAsymmetricReactions”X.Zhang,USpatent,2004,**.
14.“Apreparationofaminoalcoholsviaasymmetrichydrogenationofbeta-aminocarbonylcompounds”Zhang,
15.Xumu.US**A**PatentwritteninEnglish.Application:US2**50114.
16.“Newoxazolineligandsforasymmetriccatalysis”Zhang,Xumu;Liu,Duan.U.S.Pat.Appl.Publ.(2005),**A**.
17.“ChelatingTetraphosphorusLigandswith1,1’-biphenylbackbonefortransitionMetal-catalyzedhydroformylationofAlkenesandRelatedReactions”X.Zhang;Y.Yan,PCTInt.Appl.(2007)**.A**.
18.新型三齿膦配体及其在线性氢甲酰化及类似反应中的应用（P）.张绪穆，陈才友.中国发明专利，CN**.2013-01-16.

获奖与荣誉
FranklinVeatchGraduateFellowship,1991,StanfordUniversity
TheCamilleandHenryDreyfusFoundationNewFacultyAward,1994
DuPontYoungFacultyAward,1996
OfficeofNavalResearchYoungInvestigatorAward,1996
TheCamilleandHenryDreyfusFoundationTeacher-ScholarAward,1998
TheJohnSimonGuggenheimFoundationFellow,2000
TheOutstandingOverseaChineseYoungScientistB,ChineseAcademyofSciences,2000
ThePennStateFacultyScholarMedal,2001
TheYoungInnovationAwardofChiTec(ChineseHighTech)inChemistry,2001
TheAmericanChemicalSocietyArthurC.CopeScholarAward,2002

TheSDCA(SanDiegoChineseAssociation)AchievementAward,2002
GuestProfessorofShanghaiInstituteofOrganicChemistry
GuestProfessorofDalianInstituteofChemicalPhysics
GuestProfessorofWuhanUniversity
2008年，苏州工业园区第二届科技领军人才
2008年，“江苏省高层次创新创业人才引进计划”引进人才；
2009年，姑苏创新创业领军人才；
2011年,获2010年度“中国经济十大创新人物”。