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西北师范大学化学化工学院导师教师师资介绍简介-张博生

本站小编 Free考研考试/2021-07-16


张博生 副教授
西北师范大学,化学化工学院,甘肃,兰州,730070
学科专业:有机化学
Email:zhangbsh@foxmail.com,zhangbsh@nwnu.edu.cn

【简历】
博士,校聘副教授,2020年6月毕业于兰州大学功能有机分子化学国家重点实验室,获理学博士学位(导师:梁永民 教授);同年入职西北师范大学化学化工学院。从事过渡金属催化和有机方法学研究,在Catellani反应和自由基反应研究中取得了一系列成果,发表学术论文二十篇余篇。其中,第一作者在J. Am. Chem. Soc., ACS Catal., Chem. Commun., Org. Chem. Front., Org. Lett. 等重要学术期刊发表SCI论文7篇,其中有两篇被被国际著名评述杂志《Synfact》选为亮点并作重要评论,Web of Science个人H因子为10。博士论文《钯催化C-H活化串联反应及烯炔的氟烷基化研究》入选2019-2020学年甘肃省优秀博士论文。
【研究项目】
西北师范大学青年教师科研能力提升计划(骨干)项目(No. NWNU-LKQN2020-04),主持。
【研究兴趣】
1. 过渡金属催化的C-H活化串联反应(Pd/NBE化学)
2. 过渡金属迁移反应,如1,4-钯迁移

【代表论文】
1. Zhang, B.-S.; Li, Y.; Zhang, Z.; An, Y.; Wen, Y.-H.; Gou, X.-Y.; Quan, S.-Q.; Wang, X.-G.; Liang, Y.-M.*, Synthesis of C4-Aminated Indoles via a Catellani and Retro-Diels–Alder Strategy. J. Am. Chem. Soc. 2019,141(24), 9731-9738. (SCI 一区, IF 14.612)(Hightlighted byCBG and huaxuejia)
2. Zhang, B.-S.; Li, Y.; An, Y.; Zhang, Z.; Liu, C.; Wang, X.-G.; Liang, Y.-M., Carboxylate Ligand-Exchanged Amination/C(sp3)–H Arylation Reaction via Pd/Norbornene Cooperative Catalysis. ACS Catal. 2018,8(12), 11827-11833. (SCI 一区, IF 12.350) (Hightlighted by Synfacts andX-Mol)
3. Zhang, B.-S.; Gao, L.-Y.; Zhang, Z.; Wen, Y.-H.; Liang, Y.-M., Three-component difluoroalkylation and trifluoromethylthiolation/trifluoromethylselenolation of π-bonds. Chem. Commun. 2018,54(10), 1185-1188. (SCI 一区, IF 5.996) (Hightlighted by Synfacts)
4. Zhang, B.-S.; Hua, H.-L.; Gao, L.-Y.; Liu, C.; Qiu, Y.-F.; Zhou, P.-X.; Zhou, Z.-Z.; Zhao, J.-H.; Liang, Y.-M., Palladium-catalyzed arene C–H activation/ketone C–H functionalization reaction: route to spirodihydroindenones. Org. Chem. Front. 2017,4(7), 1376-1379. (SCI 一区, IF 5.155,中国TOP期刊)
5. Zhang, B.-S.#*; Wang, F.; Yang, Y.-H.; Gou, X.-Y.; Qiu, Y.-F.; Wang, X.-C.; Liang, Y.-M.*; Li, Y.*; Quan, Z.-J.,*Synthesis of C4-Substituted Indoles via a Catellani and C–N Bond Activation Strategy.,Org. Lett.2020, 22(21), 8267-8271. (SCI 一区, IF 6.091)
6. Zhang, B.-S.#*; Yang, Y.-H.#; Wang, F.; Gou, X.-Y.; Wang, X.-C.*; Liang, Y.-M.*; Li, Y.*; Quan, Z.-J.,*Reductive Coupling of Aryl Halides via C‐H Activation of Indene.Chin. J. Chem. 2021, doi.org/10.1002/cjoc.. (SCI 二区, IF 3.826, 中国期刊)
7. Zhang, B.-S.; Li, Y.; Gou, X.-Y.; Zhang, Z.; An, Y.; Wang, X.-G.; Liang, Y.-M.*,DMAP and PivOH-promoted amination/allenization reaction. Chem. Commun. 2020, 56 (64), 9202-9205. (SCI 一区, IF 5.996)
8. Gou, X.-Y.#; Zhang, B.-S.#; Wang, X.-G.; Shi, W.-Y.; Liu, H.-C.; An, Y.; Zhang, Z.; Liang, Y.-M.* Visible-light-induced ligand-free RuCl3 catalyzed C–H phosphorylation in water. Chem. Commun. 2020,56, 4704-4707. (SCI 一区, IF 5.996)
9. Wang, X.-G.; Li, Y.; Liu, H.-C.; Zhang, B.-S.; Gou, X.-Y.; Wang, Q.; Ma, J.-w.; Liang, Y.-M., Three-Component Ruthenium-Catalyzed Direct meta-Selective C-H Activation of Arenes: A New Approach to The Alkylarylation of Alkenes. J. Am. Chem. Soc. 2019, 141, 13914-13922. (SCI 一区, IF 14.612) (Hightlighted by X-Mol)
10. An, Y.; Zhang, B.-S.; Zhang, Z.; Liu, C.; Gou, X.-Y.; Ding, Y.-N.; Liang, Y.-M.*A carboxylate-assisted amination/unactivated C(sp2)–H arylation reaction via a palladium/norbornene cooperative catalysis.Chem. Commun. 2020, 56 (44), 5933-5936. (SCI 一区, IF 5.996)
11. Zhang, Z.; Zhang, B.-S.; Li, K.-L.; An, Y.; Liu, C.; Gou, X.-Y.; Liang, Y.-M.*,Palladium-Catalyzed Amination/Dearomatization Reaction of Indoles and Benzofurans.J. Org. Chem. 2020, 85 (12), 7817-7839. (SCI 二区,IF4.335)
12. Ding, Y.-N.; Shi, W.-Y.; Liu, C.; Zheng, N.; Li, M.; An, Y.; Zhang, Z.; Wang, C.-T.; Zhang, B.-S.; Liang, Y.-M.*, Palladium-Catalyzed ortho-C–H Glycosylation/ipso-Alkenylation of Aryl Iodides.J. Org. Chem. 2020, 85 (17), 11280-11296. (SCI 二区,IF4.335)
13. Zheng, N.; Liu, C.; Ding, Y.-N.; Shi, W.-Y.;Zhang, B.-S.; Liang, Y.-M.*, Copper-Catalyzed Three-Component Redox-Neutral Ring Opening of Benzothiazoles to 1-Amino-N-(2-(phenylthio)phenyl)methanimine.J. Org. Chem. 2020, 85 (12), 7666-7673. (SCI 二区,IF4.335)
14. Hua, H.-L.; Zhang, B.-S.; He, Y.-T.; Qiu, Y.-F.; Hu, J.-Y.; Yang, Y.-C.; Liang, Y.-M.*, Copper-catalyzed difluoromethylation of propargylamide-substituted indoles: synthesis of mono- and bis-difluoromethylated indoloazepinone derivatives. Chem. Commun. 2016,52(68), 10396-10399. (SCI 一区, IF 5.996)
15. Hua, H.-L.; Zhang, B.-S.; He, Y.-T.; Qiu, Y.-F.; Wu, X.-X.; Xu, P.-F.; Liang, Y.-M., Silver-Catalyzed Oxidative Cyclization of Propargylamide-Substituted Indoles: Synthesis of Phosphorated Indoloazepinones Derivatives. Org. Lett. 2016,18(2), 216-219. (SCI 一区, IF 6.091)
16. Liu, C.; Liang, Y.; Zheng, N.; Zhang, B.-S.; Feng, Y.; Bi, S.; Liang, Y.-M., Synthesis of indolines via a palladium/norbornene-catalyzed reaction of aziridines with aryl iodides. Chem. Commun. 2018,54(27), 3407-3410. (SCI 一区, IF 5.996) (Hightlighted by X-Mol.)
17. Wang, X.-G.; Li, Y.; Zhang, L.-L.; Zhang, B.-S.; Wang, Q.; Ma, J.-W.; Liang, Y.-M., Ruthenium(ii)-catalyzed selective C–H difluoroalkylation of aniline derivatives with pyrimidyl auxiliaries. Chem. Commun. 2018,54(68), 9541-9544. (SCI 一区, IF 5.996)
18. Wang, Q.; Jin, J.-N.; Chen, X.; Wang, X.-G.; Zhang, B.-S.; Ma, J.-W.; Liang, Y.-M., Synthesis of Difluoroalkyl Unsaturated β-Amino Acid Derivatives Exclusively through Alkyne Difunctionalization. J. Org. Chem. 2018,83(23), 14626-14636. (SCI 二区,IF4.335)
19. Gou, X.-Y.; Li, Y.; Wang, X.-G.; Liu, H.-C.; Zhang, B.-S.; Zhao, J.-H.; Zhou, Z.-Z.; Liang, Y.-M., Ruthenium-catalyzed ortho-selective CAr–H amination of heteroaryl arenes with di-tert-butyldiaziridinone. Chem. Commun. 2019,55(38), 5487-5490. (SCI 一区, IF 5.996)
20. Xia, Y.; Bao, Q.-F.; Li, Y.; Wang, L.-J.; Zhang, B.-S.; Liu, H.-C.; Liang, Y.-M., Ligand-controlled regiodivergent π-allyl palladium catalysis enables a switch between [3+2] and [3+3] cycloadditions. Chem. Commun. 2019,55(32), 4675-4678. (SCI 一区, IF 5.996)
专利
1. 梁永民; 张博生, 一种4-氨基吲哚的合成方法,China Patent No. 1.9.





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