刘柳Google Scholar ResearcherID

助理教授 (副研究员) 化学系 课题组网站
2020年9月加入南方科技大学化学系，任独立课题组长，博士生导师。2011年本科毕业于厦门大学化学系，2016年博士毕业于厦门大学（2011—2013, 2015—2016）和加州大学圣地亚哥分校（2013—2015）联合培养，师从中国科学院院士赵玉芬教授和法国科学院院士Guy Bertrand教授。毕业后在加拿大多伦多大学（2016—2019；合作导师为加拿大皇家科学院院士Douglas W. Stephan教授）和美国劳伦斯伯克利国家实验室与加州大学伯克利分校（2019—2020；合作导师为三位美国科学院院士F. Dean Toste教授、Kenneth N. Raymond教授和Robert G. Bergman教授）从事科研工作。截至2020年12月，在国际知名期刊共发表学术论文60余篇（h-index: 24），授权专利一项。担任《Chem》期刊青年编委（Next-Generation Advisors）（2020—）。研究领域为基于主族元素的有机化学、无机化学和理论计算化学。入选深圳市海外高层次“孔雀计划”B类人才（2021）。
个人简介
个人简介

研究领域主族有机/无机化学

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教学化学原理A

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学术成果 查看更多For full publications, please see: https://www.liuleoliu.com/overview-publications
Representative publications:
1)?L. Liu;?D. A. Ruiz; D. Munz and G. Bertrand,* A Singlet Phosphinidene Stable at Room Temperature,?Chem?2016,?1, 147–153. (Highlighted by Chem. Eng. News entitled “Stable phosphorus carbene analog debuts”; Previewed by Rory Waterman entitled “A ‘Bottle-able’ Phosphinidene” in Chem)
2)?L. L. Liu;?L. L. Cao; Y. Shao; G. Ménard and D. W. Stephan,* A Radical Mechanism for Frustrated Lewis Pair Reactivity,?Chem?2017,?3, 259–267. (Highlighted by front cover; Previewed by Duncan F. Wass entitled “How Important Are Radical Mechanisms in Frustrated Lewis Pair Chemistry?” in Chem)
3)?L. L. Liu;?L. L. Cao; Y. Shao and D. W. Stephan,* Single Electron Delivery to Lewis Pairs: An Avenue to Anions by Small Molecule Activation,?J. Am. Chem. Soc.?2017,?139, 10062–10071.
4)?L. L. Liu;?J. Zhou; L. L. Cao; R. Andrews; R. L. Falconer; C. A. Russell and D. W. Stephan,* A Transient Vinylphosphinidene via a Phosphirene?Phosphinidene Rearrangement,?J. Am. Chem. Soc.?2018,?140, 147–150.
5)?L. L. Liu;?J. Zhou; R. Andrews and D. W. Stephan,* A Room-Temperature-Stable Phosphanorcaradiene,?J. Am. Chem. Soc.?2018,?140, 7466–7470.
6)?L. L. Liu;?J. Zhou; L. L. Cao; Y. Kim and D. W. Stephan,* Reversible Intramolecular Cycloaddition of Phosphaalkene to an Arene Ring,?J. Am. Chem. Soc.?2019,?141, 8083–8087.
7)?L. L. Liu;?J. Zhou; L. L. Cao and D. W. Stephan,* Phosphaaluminirenes: Synthons for Main Group Heterocycles,?J. Am. Chem. Soc.?2019,?141, 16971–16982. (Highlighted by ChemistryViews entitled “Phosphaaluminirenes Synthesized”)
8)?L. L. Liu;?L. L. Cao; J. Zhou and D. W. Stephan,* Facile Cleavage of the P=P Double Bond in Vinyl-Substituted Diphosphenes,?Angew. Chem. Int. Ed.?2019,?58, 273–277.
9) J. Tang;+?L. L. Liu;+?S. Yang;+ X. Cong; M. Luo and X. Zeng,* Chemoselective Cross-Coupling between Two Different and Unactivated C(aryl)–O Bonds Enabled by Chromium Catalysis,?J. Am. Chem. Soc.?2020,?142, 7715–7720. (+ = equal contribution)
10)?X. Chen;+?L. L. Liu;+?S. Liu; H. Grützmacher and Z. Li,*?A Room-Temperature Stable Distonic Radical Cation,?Angew. Chem. Int. Ed.?2020,?59, 23830-23835. (+ = equal contribution)
11)?L. L. Liu;?D. A. Ruiz; F. Dahcheh; G. Bertrand;* R. Suter; A. M. Tondreau and H. Grützmacher,* Isolation of Au-, Co-η1 PCO and Cu-η2 PCO Complexes, Conversion of an Ir-η1 PCO Complex into a Dimetalladiphosphene, and an Interaction-free PCO Anion,?Chem. Sci.?2016,?7, 2335–2341.
12)?L. L. Liu,*?The Dynamic Nature of Phosphorus,?Chem?2017,?3, 195–197. (Invited “Potential Energy” article)
13)?L. L. Liu?and D. W. Stephan,* Radicals Derived from Lewis Acid/Base Pairs,?Chem. Soc. Rev.?2019,?48, 3454–3463.
14)?L. L. Liu;?J. Zhu* and Y. Zhao,* The Phosphaethynolate Anion Reacts with Unsaturated Bonds: DFT Investigations on [2+2], [3+2] and [4+2] Cycloadditions,?Chem. Comm.?2014,?50, 11347–11349.
15)?L. L. Liu;?D. A. Ruiz; F. Dahcheh and G. Bertrand,* Isolation of a Lewis Base Stabilized Parent Phosphenium (PH2+) and Related Species,?Chem. Comm.?2015,?51, 12732–12735.
16)?L. L.?Liu?and D. W. Stephan,* An Imine-Gallium Lewis Pair Stabilized Oxophosphinidene via an Unexpected Phosphirene Rearrangement,?Chem. Comm.?2018,?54, 1041–1044. (Highlighted by front cover)
17)?L. L.?Liu;?L. L. Cao; D. Zhu; J. Zhou and D. W. Stephan,* Homolytic Cleavage of Peroxide Bonds via a Single Electron Transfer of Frustrated Lewis Pair,?Chem. Comm.?2018,?54, 7431–7434. (Highlighted by front cover)
18) Y. Wu;* C. Shan; Y. Sun; P. Chen; J. Ying; J. Zhu;?L. L. Liu*?and Y. Zhao,* Main Group Metal Ligand Cooperation of N-Heterocyclic Germylene: An Efficient Catalyst for the Hydroboration of Carbonyl Compounds,?Chem. Comm.?2016,?52, 13799–13802.
19)?Y. Wu;?L. L. Liu;*?J. Su; J. Zhu; Z. Ji and Y. Zhao,*?Isolation of a Heavier Cyclobutadiene Analogue: 2,4-Digerma-1,3-diphosphacyclobutadiene,?Organometallics,?2016,?35, 1593–1596.
20) J. Zhou;?L. L. Liu;?L. L. Cao and D. W. Stephan,* The η5-Pentamethylcyclopentadienyl Phosphorus Dication [(η5-Cp*)P]2+: A Phosphorus Lewis Super Acid,?Chem?2018,?4, 2699–2708. (Highlighted by Chemistryworld entitled “Rare phosphorus dication synthesised”)
21) Z. Li;* X. Chen;?L. L. Liu;?M. T. Scharnh?lz and H. Grützmacher,* N-Heterocyclic Carbene Stabilized Dicarbondiphosphide: A Strong Neutral Four-membered Heterocyclic 6π-electron Donor,?Angew. Chem. Int. Ed.?2020,?59, 4288–4293.
22) J. Zhou;?L. L. Liu;?L. L. Cao and D. W. Stephan,* Base-Stabilized [PO]+/[PO2]+ Cations,?Angew. Chem. Int. Ed.?2019,?58, 18276–18280.
23) J. Zhou;?L. L. Liu;?L. L. Cao and D. W. Stephan,* The Arene-Stabilized η5-Pentamethylcyclopentadienyl Arsenic Dication [(η5-Cp*)As(toluene)]2+,?Angew. Chem. Int. Ed.?2019,?58, 5407–5412.
24) J. Zhou;?L. L. Liu;?L. L. Cao and D. W. Stephan,* Nitrogen-Based Lewis Acids: Synthesis and Reactivity of a Cyclic (Alkyl)(Amino)Nitrenium Cation,?Angew. Chem. Int. Ed.?2018,?57, 3322–3326.
25) C. Pranckevicius;?L. L. Liu;?G. Bertrand and D. W. Stephan,* Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene Based Solely on Carbon,?Angew. Chem. Int. Ed.?2016,?55, 5536–5540.
26) Z. Li; X. Chen; Z. Benk?;?L. L. Liu;?D. Ruiz; J. Peltier; G. Bertrand;* C. Su* and H. Grützmacher,* N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism,?Angew. Chem. Int. Ed.?2016,?55, 6018–6022.
27) B. Rao; H. Tang; X. Zeng*;?L. L. Liu;?M. Melaimi and G. Bertrand,* Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals,?Angew. Chem. Int. Ed.?2015,?54, 14915–14919.
28) C. Weinstein; C. Martin;?L. L. Liu?and G. Bertrand,* Cross-Coupling Reactions between Stable Carbenes,?Angew. Chem. Int. Ed.?2014,?53, 6550–6553.
29)?M. M. Hansmann; D. A. Ruiz;?L. L. Liu;?R. Jazzar and G. Bertrand,* (Phosphanyl)phosphaketenes as Building Blocks for Novel Phosphorus Heterocycles,?Chem. Sci.?2017,?8, 3720-3725.



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