石高全 （教授，理学博士）

1981-1985，南京大学化学系，理学学士

1985-1988，南京大学化学系，理学硕士

1988-1990，南京大学化学系，南京大学化学系博士生

1990-1992，日本国东京农工业大学工学部留学（做博士论文）



1992回国，南京大学化学系，理学博士

1992-1993，南京大学化学系讲师

1993-1995，南京大学化学系副教授

1995-2000，南京大学化学系教授

2000-至今，清华大学化学系教授

研究方向

1、 导电高分子材料的合成与微结构控制

2、 导电高分子的光谱研究

3、 导电高分子的微器件研制

4、 高分子纳米材料的自组装

本实验室自1994年以来一直从事导电高分子材料研究。研制了一系列高强度导电高分子材料，特别是电化学合成了强度超过金属铝的聚噻吩膜和力学性能优异的聚苯膜材料。探索了制备各种导电高分子膜材料以及导电高分子/导电纤维复合材料的新方法。利用固体模板和无模板方法制备了高度取向的导电高分子微米/纳米管和导电高分子微容器。研制了数种导电高分子微器件。对微型容器进行线形组装，并研究了其在生物传感器方面的应用。合成了高度取向的聚芘片，培养了其单晶。研究了高分子纳米材料的自组装。在这些方面发表和已接受研究论文110篇 （到2004，3月）。一些论文发表在Science, Adv. Mater., Macromolecules, Chem. Commun., J. Phys. Chem.B 等国际一流刊物上。 研究工作被国内外同行广泛引用。承担并完成了国家自然科学基金面项目两项，教育部项目一项。现承担国家自然科学基金面上项目一项，重点项目一项（参加）。曾获得教育部科技进步一（名次2）、二等奖（名次5）各一项，江苏省科技进步一等奖一项（名次5）。曾入选江苏省333工程第二梯队培养对象，获得过清华大学“清华之友优秀教师”奖等。2002年获得国家自然科学基金杰出青年基金资助。2004年获得中国化学会-巴斯夫“青年知识创新奖”。




Microcups, micronests and microtubules synthesized in my lab.

联系方式

工作地点：清华大学化学馆214室

电话：010-62773743

Email:gshi@tsinghua.edu.cn



Publications




Year 2004 (March on web)



4. Liu C, Zhang JX, Shi GQ, et al.,

Doping Level Change of Polyaniline Film during Its Electrochemical Growth Process

J Appl Polym Sci 2004, 92 (1): 171-177.



3. Liu C, Zhang J X, Shi GQ, et al.

Raman Spectra of Electrosynthesized Polyfuran: A Combined Experimental and Theoretical Study

J Phys Chem B 2004, 108 (7): 2195-2199.



2.Zhang ZP, Shi GQ, Wu X F, et al.

Electropolymerization of 2-Phenylthiophene

Acta Polym Sin 2004, (1): 140-144.



1. Qu LT, Shi GQ, Yuan JY, et al.

Preparation of Polypyrrole Microstructures by Direct Electrochemical Oxidation of Pyrrole in an Aqueous Solution of Camphorsulfonic Acid

J Electroanal Chem 2004, 561 (1-2): 149-156



Year 2003



24. Zhang ZP, Qu LT, Shi GQ,Fabrication of Highly Hydrophobic Surfaces of Conductive Polythiophene, J Mater Chem 2003, 13 (12): 2858-2860



23. Shen Y, Chen FE, Wu PY, et al.A Two-Dimensional Raman Spectroscopic Study on the Structural Changes of A Polythiophene Film during the Cooling Process, J Chem Phys 2003, 119 (21): 11415-11419



22. Liu Z, Shi GQ, Chen FE, et al.

Dodecylamine Supported Layered Tin Iodide as Semiconductor

Chinese J Inorg Chem 2003, 19 (11): 1185-1190





21. Huang ZM, Qu LT, Shi GQ,et al.

Electrochemical Polymerization of Naphthalene in the Electrolyte of Boron Trifluoride Diethyl Etherate Containing Trifluoroacetic Acid and Polyethylene Glycol Oligomer

J Electroanal Chem 2003, 556: 159-165



20. Liu C, Chen FE, Zhang JX, et al.

Raman Spectroscopic Studies on Electrosynthesized Polyaniline Film

Acta Phys-Chim Sin 2003, 19 (9): 810-814





19. Liu C, Zhang JX, Shi GQ, et al.

Proton-Conducting Gel Polyelectrolytes Based on Lewis Acid

J Appl Polym Sci 2003, 90 (5): 1267-1272





18. Cao J, Sun JZ, Shi GQ, et al.

Photovoltaic Properties of Polythiophene Nano-Tubule Films

Mater Chem Phys 2003, 82 (1): 44-48





17. Yuan JY, Qu LT, Shi GQ, et al.

Novel Polypyrrole Microstructures Generated by Direct Electrochemical Oxidation of Pyrrole on P-Type Silicon Substrate

Chinese J Polym Sci 2003, 21 (4): 399-403





16. Chen FG, Zhang JX, Wang F, et al.

Raman Spectroscopic Studies on the Structural Changes of Electrosynthesized Polypyrrole Films during Heating and Cooling Processes

J Appl Polym Sci 2003, 89 (12): 3390-3395





15. Zhang JX, Shi GQ, Liu C, et al.

Electrochemical Fabrication of Polythiophene Film Coated Metallic Nanowire Arrays

J Mater Sci 2003, 38 (11): 2423-2427





14. Qu LT, Sun SQ, Liu C, et al.

Environmental Stability of The Polyene Prepared by Dehydrochlorination of Poly(Vinyl Chloride)

Chinese J Polym Sci 2003, 21 (1): 71-75





13. Ma MM, Shi GQ, Xi CJ

Polymer Precursor to Diamondlike Carbon Prepared by The Polymerization of Alpha, Alpha, Alpha-Trichlorotoluene and Acetonitrile

J Appl Polym Sci 2003, 89 (1): 16-23





12. Chen F, Shi GQ, Zhang JX, et al.

Raman Spectroscopic Studies on the Structural Changes of Electrosynthesized Polythiophene Films during the Heating and Cooling Processes

Thin Solid Films 2003, 424 (2): 283-290





11. Zhang JX, Chen FE, Fu MX, et al.

Aligned Polythiophene Coated Gold Nanowires

Synthetic Met 2003, 135 (1-3): 217-218





10. Qu LT, Shi GQ, Chen FE, et al.

High-quality Polyene Prepared by Liquid/Solid Two-Phase Dehydrochlorination of Poly(Vinyl Chloride)

Synthetic Met 2003, 135 (1-3): 219-220





9. Xu JK, Shi GQ, Qu LT, et al.

Electrosyntheses of High Quality Polypyrrole Films in Isopropyl Alcohol Solution of Boron Trifluoride Diethyl Etherate

Synthetic Met 2003, 135 (1-3): 221-222





8. Huang ZM, Shi GQ, Zhang JX, et al.

Template-free Electrosynthesis of Aligned Poly(p-phenylene) Microtubules

Chinese Sci Bull 2003, 48 (5): 434-436





7. Huang ZM, Shi GQ, Qu LT, et al.

Electrochemical Polymerization of Beta-naphthalene Sulfonic Acid in the Mixed Electrolyte of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid

J Electroanal Chem 2003, 544: 41-46





6. Qu LT, Shi GQ, Chen F, et al.

Electrochemical Growth of Polypyrrole Microcontainers

Macromolecules 2003, 36 (4): 1063-1067





5.Wu XF, Shi GQ, Qu LT, et al.

A Novel Route to Poly(2-methoxy-5-(2 "-ethyl-hexyloxy)-p-phenylene)

Acta Polym Sin 2003, (1): 147-149





4. Chen F, Shi GQ, Fu MX, et al.

Raman Spectroscopic Evidence of Thickness Dependence of the Doping Level of Electrochemically Deposited Polypyrrole Film

Synthetic Met, 2003, 132 (2): 125-132





3.Wu XF, Shi GQ, Qu LT, et al.

Novel Route to Poly (p-phenylene vinylene) polymers

J Polym Sci Pol Chem 2003, 41 (3): 449-455





2. Qu LT, Shi GQ

Electrochemical Synthesis of Novel Polypyrrole Microstructures

Chem Commun 2003, (2): 206-207





1. Xu JK, Shi GQ, Chen FG, et al.

Poly(3-Chlorothiophene) Films Prepared by The Direct Electrochemical Oxidation of 3-Chlorothiophene in Mixed Electrolytes of Boron Trifluoride Diethyl Etherate and Sulfuric Acid

J Appl Polym Sci 2003, 87 (3): 502-509



Year 2002



10. Xu JK, Shi GQ, Zhang JX, et al.

Electrochemical Polymerization of Thianaphthene in Mixed Electrolytes of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid

Macromol Chem Physic 2002, 203 (16): 2385-2390





9. Wang XS, Xut JK, Shi GQ, et al.

Microstructure-Mechanical Properties Relationship in Conducting Polypyrrole Films

J Mater Sci 2002, 37 (24): 5171-5176





8. Chen FG, Zhang JX, Fu MX, et al.

Raman Spectroscopic Studies on The Structural Changes of Poly(3-Methylthiophene) during Heating and Cooling Processes

Chinese Sci Bull 2002, 47 (21): 1791-1793





7. Xu JK, Shi GQ, Chen FE, et al.

Doping Level Increase of Poly(3-Methylthiophene) Film during Electrochemical Polymerization Process

Chinese J Polym Sci 2002, 20 (5): 425-430





6. Fu MX, Chen F, Zhang JX, et al.

Electrochemical Fabrication of Aligned Microtubular Heterojunctions of Poly(p-phenylene) and Polythiophene

J Mater Chem 2002, 12 (8): 2331-2333



5. Fu MX, Shi GQ, Chen FG, et al.

Doping Level Change of Polythiophene Film during Its Electrochemical Growth Process

Phys Chem Chem Phys 2002, 4 (12): 2685-2690





4. Wang F, Shi GQ, Xu ZJ, et al.

Carbonaceous Materials Prepared from Carbon Tetrachloride and Dimethyl Sulfoxide

J Appl Polym Sci 2002, 85 (4): 785-791





3. Wang XS, Zhang JX, Zhu SQ, et al.

Deformation Measurement of Conducting Polythiophene Thin Films by an Electronic Speckle Pattern Interferometric Method

Acta Mech Solida Sin 2002, 15 (1): 30-35





2. Shi GQ, Xu JK, Fu MX

Raman Spectroscopic and Electrochemical Studies on the Doping Level Changes of Polythiophene Films during Their Electrochemical Growth Processes

J Phys Chem B 2002, 106 (2): 288-292





1. Li C, Chen F, Shi GQ, et al.

Electrosynthesis of Free-Standing Poly(Para-Phenylene) Films in Mixed Electrolytes of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid on Stainless Steel Electrode

J Appl Polym Sci 2002, 83 (11): 2462-2466



Year 2001



7. Fu MX, Zhu YF, Tan RQ, et al.

Aligned Polythiophene Micro- and Nanotubules

Adv Mater 2001, 13 (24): 1874-1877





6. Wang F, Shi GQ, Chen F, et al.

Electrochemical Synthesis of Soluble Polythianaphthene

Acta Polym Sin 2001, (6): 807-810





5. Xu JK, Shi GQ, Xu ZJ, et al.

Low Potential Electrochemical Polymerization of 3-Chlorothiophene in Mixed Electrolytes of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid

J Electroanal Chem 2001, 514 (1-2): 16-25





4. Shi GQ, Zhang JX, Chen FE, et al.

Electrochemical Copolymerization of 3-Methylthiophene and 3-Chlorothiophene

Acta Chim Sinica 2001, 59 (10): 1818-1822





3. Wang F, Shi GQ, Chen FG, et al.

Electrochemical Polymerization of Thianaphthene

J Electroanal Chem 2001, 510 (1-2): 29-34





2. Shi GQ, Chen FG, Wu SX, et al.

Polymerization of Chlorofluorocarbon-22 and Acetonitrile

J Appl Polym Sci 2001, 81 (1): 116-120





1. Guo L, Shi GQ, Liang YQ

Poly(Ethylene Glycol)S Catalyzed Homogeneous Dehydrochlorination of Poly(Vinyl Chloride) with Potassium Hydroxide

Polymer 2001, 42 (13): 5581-5587



Year 2000-1999



8. Wu SX, Ming L, Shi GQ, et al.

Liquid/solid Two-phase Carbonization of Low-molecular-weight Chloro-/bromo-hydrocarbons

J Appl Polym Sci 2000, 76 (10): 1510-1515





7. Shi GQ, Ming L, Wu SX, et al.

Carbonization of Trichloroethanes with Anhydrous Potassium Hydroxide

J Appl Polym Sci 2000, 76 (2): 185-189





6. Wang XF, Shi GQ, Liang YQ

Low Potential Electropolymerization of Thiophene at a Copper Oxide Electrode

Electrochem Commun, 1999, 1 (11): 536-539





5.Shi GQ, Li C, Liang YQ

High-Strength Conducting Polymers Prepared by Electrochemical Polymerization in Boron Trifluoride Diethyl Etherate Solution

Adv Mater 1999, 11 (13): 1145-1146





4. Wang XF, Shi GQ, Liang YQ

Synthesis of carbyne-like nano-particles by electrocatalytic dehydrochlorination of 1,1,2-trichloroethane

J Electroanal Chem 1999, 470 (1): 95-97





3. Li C, Shi GQ, Liang YQ

Electrochemical Synthesis of Free-Standing Poly(Para-Phenylene) Films in Composite Electrolytes of Boron Trifluoride Diethyl Etherate and Sulfuric Acid

Synthetic Met 1999, 104 (2): 113-117





2. Guo L, Shi GQ, Liang YQ

High-Quality Polyene Films Prepared by Poly (Ethylene glycol)s Catalyzed Dehydrochlorination of Poly (Vinyl chloride) with Potassium Hydroxide

Eur Polym J 1999, 35 (2): 215-220





1. Guo L, Shi GQ, Liang YQ

Polyene Films Prepared by Poly(Ethylene Glycol)S-Catalyzed Dehydrochlorination of Poly(Vinyl Chloride): Chemical and Electrochemical Properties

Synthetic Met 104 (2): 129-135 JUL 8 1999



Year 1998-1994



17. Shi GQ

Synthesis of carbyne nano-particles by dehydrochlorination of 1,1,1 -trichloroethane

CHEM. COMMUN., 1: 2271-2272, 1998



16. Guo L, Shi GQ, Liang YQ

Electrosynthesis of Soluble Polyaniline in Acetic Acid

Polym Bull 1998, 41 (6): 681-686





15. Lu YQ, Shi GQ, Li C, et al.

Thin Polypyrrole Films Prepared by Chemical Oxidative Polymerization

J Appl Polym Sci 1998, 70 (11): 2169-2172





14. Guo L, Shi GQ, Du XZ, et al.

Poly(Ethylene glycol)s Catalyzed Two-Phase Dehydrochlorination of Poly(Vinyl Chloride) with Potassium Hydroxide

J Appl Polym Sci 1998, 70 (12): 2463-2469





13. Li C, Shi GQ, Liang YQ

Low Potential Electrochemical Polymerization of Benzene in a Composite Electrolyte of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid

J Electroanal Chem 1998, 455 (1-2): 1-4





12. Li C, Shi GQ, Liang YQ, et al.

High-Strength Metallic Plastic Sheet Prepared by Electrochemical Polymerization of Thiophene on Stainless Steel

J Appl Polym Sci 1998, 68 (6): 1027-1029





11. Li C, Shi GQ, Liang YQ, et al.

Crystalline Polythiophene Film Prepared by Electrochemical Polymerization of Thiophene at a Nickel Electrode

Polymer 1997, 38 (26): 6421-6422





10. Li C, Shi GQ, Liang YQ, et al.

High-Quality Poly(P-Phenylene) Film Prepared by Electrochemical Polymerization of Benzene at a Stainless Steel Electrode

Polymer 1997, 38 (20): 5023-5026





9.Li HH, Shi GQ, Ye W, et al.

Polypyrrole Carbon Fiber Composite Film Prepared by Chemical Oxidative Polymerization of Pyrrole

J Appl Polym Sci 1997, 64 (11): 2149-2154





8.Shi GQ, Li C, Yu B, et al.

Deposition of Polythiophene Films onto p-type Silicon

Polymer 1997, 38 (5): 1247-1249





7.Li C, Shi GQ, Xue G, et al.

High-Quality Polythiophene Films Prepared By Electropolymerization of Thiophene in BF3-Ethyl Ether Solution

J Polym Sci Pol Phys 1995, 33 (16): 2199-2203





6. Shi GQ, Jin S, Xue G, et al.

A Conducting Polymer Film Stronger Than Aluminum

Science 1995, 267 (5200): 994-996





5. Shi GQ, Yu B, Xue G, et al.

Electrochemical Fabrication of a P-Type Silicon-Polythiophene P-N-Junction Diode

J Chem Soc Chem Comm 1994, (22): 2549-2550





4. Shi GQ, Xue G, LI C, et al.

Layered Poly(Naphthalene) Films Prepared by Electrochemical Polymerization

Polym Bull 1994, 33 (3): 325-329





3. Shi GQ, Xue G, LI C, et al.

Uniaxial Oriented Poly(P-Phenylene) Fibrils and Films

Macromolecules 1994, 27 (13): 3678-3679 JUN 20





2. Xue G, Lu Y, Shi GQ, et al.

Glass-Transition of Expanded Polystyrene Coils

Polymer 1994, 35 (4): 892-894





1. Xue G, Lu Y, Shi GQ

Sers Studies of Synergetic Effect in Corrosion Inhibition for Cu by a 2-Component Inhibitor System of Polyvinylimidazole and Benzimidazole

Appl Surf Sci 1994, 74 (1): 37-41



Year 1994 Before
16、Hou W, Peng BC, Yan QJ, Fu XC, Shi GQ

The first silica-pillared layered niobate

J. Chem. Soc., Chem. Commun., 253-254, 1993



15． Shi GQ, Xue G, Hou WH, Dong J

Electrochemical behavior of MOR zeolite in poly (ethylene oxide) oligomer

J. Electroanal. Chem., 344:363, 1993



14．Xue G, Lu Y, Shi GQ, Dai QP

Glass transition expaned polystyrene coils

polymer, 35:892, 1993



13． Shi GQ, Xue G, Wang GQ, Hou WH

Electrochemical behavior of NaX and ZSM-5 zeolites in poly(ethylene

glycol) oligomer

Chinese Sci. Bull., 38:1443, 1993



12．石高全,薛奇,王国祥,候文华

Nax, ZSM-5分子筛在乙二醇低聚物中的电化学行为

科学通报, 38:617, 1993



11． 石高全,薛奇, 李村,马万里,金士

萘在三氟化硼乙醚溶液中的电化学聚合

高等学校化学学报, 14:1623-1624, 1993



10. 石高全,薛奇

丝光沸石在乙二醇低聚物中的电化学行为

南京大学学报, 29:259-262,1993



9. Shi GQ

Matrix chain-length dependence of the electrochemitry of electroactive

molecules in amorphous polymeric solvents

J. Phys. Chem. 96:4677, 1992



8. Shi GQ, Xue G, Wu ZB, Shen B

Matrix chain-length dependence of the electrochemistry of electroactive

molecules in melton ionic conductive polymer electrolytes

J. Electroanal. Chem., 338: 353-357, 1992



7. 薛奇, 石高全,顾晓红

在位表面增强拉曼散射研究金属表面化学反应

光散射学报, 4:86,1992



6. 薛奇,石高全,董雪吟

高分子,生物高分子与金属复合物界面结构的表面增强拉曼光谱研究

光散射学报,4:162, 1992



5. Shi GQ, Ohno H

Electrochemical behavior of hemin and PEO-hemin in ionic conductive

polymer matrices

J. Electroanal. Chem., 314: 59-69, 1991



4. Xue G, Shi GQ, Ding JF, Zhang WM, Chen RS

Complex-induced coupling effect: adhesion of some polymers to copper

metal promoted by benzimidazole

J. Adhesion Sci. Tech., 4:723, 1990



3. Shi GQ, Ohno H, Suzuki T, Yamakuci N

Electrochemical behavior of PEO-hemin in solid polymer electrolytes

in B. V. Chaodari et al eds, “Recent advances in fast ion conducting

materials and devices”

World Scientific, Singapore, 273, 1990







2. Xue G, Zhang JF, Shi GQ, Wu PY

Spectroscopic studies on the polymerization of benzimidazole with

metallic copper

J. Chem. Soc., Perkin Trans II, 33-36, 1989



1. Xue G, Zhang JF, Huang XY, Shi GQ

Chemical reaction of metallic copper with imidazole

J. Chem. Soc., Dalton Trans., 1487, 1988























































石高全 （教授，理学博士）

1981-1985，南京大学化学系，理学学士

1985-1988，南京大学化学系，理学硕士

1988-1990，南京大学化学系，南京大学化学系博士生

1990-1992，日本国东京农工业大学工学部留学（做博士论文）



1992回国，南京大学化学系，理学博士

1992-1993，南京大学化学系讲师

1993-1995，南京大学化学系副教授

1995-2000，南京大学化学系教授

2000-至今，清华大学化学系教授

研究方向

1、 导电高分子材料的合成与微结构控制

2、 导电高分子的光谱研究

3、 导电高分子的微器件研制

4、 高分子纳米材料的自组装

本实验室自1994年以来一直从事导电高分子材料研究。研制了一系列高强度导电高分子材料，特别是电化学合成了强度超过金属铝的聚噻吩膜和力学性能优异的聚苯膜材料。探索了制备各种导电高分子膜材料以及导电高分子/导电纤维复合材料的新方法。利用固体模板和无模板方法制备了高度取向的导电高分子微米/纳米管和导电高分子微容器。研制了数种导电高分子微器件。对微型容器进行线形组装，并研究了其在生物传感器方面的应用。合成了高度取向的聚芘片，培养了其单晶。研究了高分子纳米材料的自组装。在这些方面发表和已接受研究论文110篇 （到2004，3月）。一些论文发表在Science, Adv. Mater., Macromolecules, Chem. Commun., J. Phys. Chem.B 等国际一流刊物上。 研究工作被国内外同行广泛引用。承担并完成了国家自然科学基金面项目两项，教育部项目一项。现承担国家自然科学基金面上项目一项，重点项目一项（参加）。曾获得教育部科技进步一（名次2）、二等奖（名次5）各一项，江苏省科技进步一等奖一项（名次5）。曾入选江苏省333工程第二梯队培养对象，获得过清华大学“清华之友优秀教师”奖等。2002年获得国家自然科学基金杰出青年基金资助。2004年获得中国化学会-巴斯夫“青年知识创新奖”。




Microcups, micronests and microtubules synthesized in my lab.

联系方式

工作地点：清华大学化学馆214室

电话：010-62773743

Email:gshi@tsinghua.edu.cn



Publications




Year 2004 (March on web)



4. Liu C, Zhang JX, Shi GQ, et al.,

Doping Level Change of Polyaniline Film during Its Electrochemical Growth Process

J Appl Polym Sci 2004, 92 (1): 171-177.



3. Liu C, Zhang J X, Shi GQ, et al.

Raman Spectra of Electrosynthesized Polyfuran: A Combined Experimental and Theoretical Study

J Phys Chem B 2004, 108 (7): 2195-2199.



2.Zhang ZP, Shi GQ, Wu X F, et al.

Electropolymerization of 2-Phenylthiophene

Acta Polym Sin 2004, (1): 140-144.



1. Qu LT, Shi GQ, Yuan JY, et al.

Preparation of Polypyrrole Microstructures by Direct Electrochemical Oxidation of Pyrrole in an Aqueous Solution of Camphorsulfonic Acid

J Electroanal Chem 2004, 561 (1-2): 149-156



Year 2003



24. Zhang ZP, Qu LT, Shi GQ,Fabrication of Highly Hydrophobic Surfaces of Conductive Polythiophene, J Mater Chem 2003, 13 (12): 2858-2860



23. Shen Y, Chen FE, Wu PY, et al.A Two-Dimensional Raman Spectroscopic Study on the Structural Changes of A Polythiophene Film during the Cooling Process, J Chem Phys 2003, 119 (21): 11415-11419



22. Liu Z, Shi GQ, Chen FE, et al.

Dodecylamine Supported Layered Tin Iodide as Semiconductor

Chinese J Inorg Chem 2003, 19 (11): 1185-1190





21. Huang ZM, Qu LT, Shi GQ,et al.

Electrochemical Polymerization of Naphthalene in the Electrolyte of Boron Trifluoride Diethyl Etherate Containing Trifluoroacetic Acid and Polyethylene Glycol Oligomer

J Electroanal Chem 2003, 556: 159-165



20. Liu C, Chen FE, Zhang JX, et al.

Raman Spectroscopic Studies on Electrosynthesized Polyaniline Film

Acta Phys-Chim Sin 2003, 19 (9): 810-814





19. Liu C, Zhang JX, Shi GQ, et al.

Proton-Conducting Gel Polyelectrolytes Based on Lewis Acid

J Appl Polym Sci 2003, 90 (5): 1267-1272





18. Cao J, Sun JZ, Shi GQ, et al.

Photovoltaic Properties of Polythiophene Nano-Tubule Films

Mater Chem Phys 2003, 82 (1): 44-48





17. Yuan JY, Qu LT, Shi GQ, et al.

Novel Polypyrrole Microstructures Generated by Direct Electrochemical Oxidation of Pyrrole on P-Type Silicon Substrate

Chinese J Polym Sci 2003, 21 (4): 399-403





16. Chen FG, Zhang JX, Wang F, et al.

Raman Spectroscopic Studies on the Structural Changes of Electrosynthesized Polypyrrole Films during Heating and Cooling Processes

J Appl Polym Sci 2003, 89 (12): 3390-3395





15. Zhang JX, Shi GQ, Liu C, et al.

Electrochemical Fabrication of Polythiophene Film Coated Metallic Nanowire Arrays

J Mater Sci 2003, 38 (11): 2423-2427





14. Qu LT, Sun SQ, Liu C, et al.

Environmental Stability of The Polyene Prepared by Dehydrochlorination of Poly(Vinyl Chloride)

Chinese J Polym Sci 2003, 21 (1): 71-75





13. Ma MM, Shi GQ, Xi CJ

Polymer Precursor to Diamondlike Carbon Prepared by The Polymerization of Alpha, Alpha, Alpha-Trichlorotoluene and Acetonitrile

J Appl Polym Sci 2003, 89 (1): 16-23





12. Chen F, Shi GQ, Zhang JX, et al.

Raman Spectroscopic Studies on the Structural Changes of Electrosynthesized Polythiophene Films during the Heating and Cooling Processes

Thin Solid Films 2003, 424 (2): 283-290





11. Zhang JX, Chen FE, Fu MX, et al.

Aligned Polythiophene Coated Gold Nanowires

Synthetic Met 2003, 135 (1-3): 217-218





10. Qu LT, Shi GQ, Chen FE, et al.

High-quality Polyene Prepared by Liquid/Solid Two-Phase Dehydrochlorination of Poly(Vinyl Chloride)

Synthetic Met 2003, 135 (1-3): 219-220





9. Xu JK, Shi GQ, Qu LT, et al.

Electrosyntheses of High Quality Polypyrrole Films in Isopropyl Alcohol Solution of Boron Trifluoride Diethyl Etherate

Synthetic Met 2003, 135 (1-3): 221-222





8. Huang ZM, Shi GQ, Zhang JX, et al.

Template-free Electrosynthesis of Aligned Poly(p-phenylene) Microtubules

Chinese Sci Bull 2003, 48 (5): 434-436





7. Huang ZM, Shi GQ, Qu LT, et al.

Electrochemical Polymerization of Beta-naphthalene Sulfonic Acid in the Mixed Electrolyte of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid

J Electroanal Chem 2003, 544: 41-46





6. Qu LT, Shi GQ, Chen F, et al.

Electrochemical Growth of Polypyrrole Microcontainers

Macromolecules 2003, 36 (4): 1063-1067





5.Wu XF, Shi GQ, Qu LT, et al.

A Novel Route to Poly(2-methoxy-5-(2 "-ethyl-hexyloxy)-p-phenylene)

Acta Polym Sin 2003, (1): 147-149





4. Chen F, Shi GQ, Fu MX, et al.

Raman Spectroscopic Evidence of Thickness Dependence of the Doping Level of Electrochemically Deposited Polypyrrole Film

Synthetic Met, 2003, 132 (2): 125-132





3.Wu XF, Shi GQ, Qu LT, et al.

Novel Route to Poly (p-phenylene vinylene) polymers

J Polym Sci Pol Chem 2003, 41 (3): 449-455





2. Qu LT, Shi GQ

Electrochemical Synthesis of Novel Polypyrrole Microstructures

Chem Commun 2003, (2): 206-207





1. Xu JK, Shi GQ, Chen FG, et al.

Poly(3-Chlorothiophene) Films Prepared by The Direct Electrochemical Oxidation of 3-Chlorothiophene in Mixed Electrolytes of Boron Trifluoride Diethyl Etherate and Sulfuric Acid

J Appl Polym Sci 2003, 87 (3): 502-509



Year 2002



10. Xu JK, Shi GQ, Zhang JX, et al.

Electrochemical Polymerization of Thianaphthene in Mixed Electrolytes of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid

Macromol Chem Physic 2002, 203 (16): 2385-2390





9. Wang XS, Xut JK, Shi GQ, et al.

Microstructure-Mechanical Properties Relationship in Conducting Polypyrrole Films

J Mater Sci 2002, 37 (24): 5171-5176





8. Chen FG, Zhang JX, Fu MX, et al.

Raman Spectroscopic Studies on The Structural Changes of Poly(3-Methylthiophene) during Heating and Cooling Processes

Chinese Sci Bull 2002, 47 (21): 1791-1793





7. Xu JK, Shi GQ, Chen FE, et al.

Doping Level Increase of Poly(3-Methylthiophene) Film during Electrochemical Polymerization Process

Chinese J Polym Sci 2002, 20 (5): 425-430





6. Fu MX, Chen F, Zhang JX, et al.

Electrochemical Fabrication of Aligned Microtubular Heterojunctions of Poly(p-phenylene) and Polythiophene

J Mater Chem 2002, 12 (8): 2331-2333



5. Fu MX, Shi GQ, Chen FG, et al.

Doping Level Change of Polythiophene Film during Its Electrochemical Growth Process

Phys Chem Chem Phys 2002, 4 (12): 2685-2690





4. Wang F, Shi GQ, Xu ZJ, et al.

Carbonaceous Materials Prepared from Carbon Tetrachloride and Dimethyl Sulfoxide

J Appl Polym Sci 2002, 85 (4): 785-791





3. Wang XS, Zhang JX, Zhu SQ, et al.

Deformation Measurement of Conducting Polythiophene Thin Films by an Electronic Speckle Pattern Interferometric Method

Acta Mech Solida Sin 2002, 15 (1): 30-35





2. Shi GQ, Xu JK, Fu MX

Raman Spectroscopic and Electrochemical Studies on the Doping Level Changes of Polythiophene Films during Their Electrochemical Growth Processes

J Phys Chem B 2002, 106 (2): 288-292





1. Li C, Chen F, Shi GQ, et al.

Electrosynthesis of Free-Standing Poly(Para-Phenylene) Films in Mixed Electrolytes of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid on Stainless Steel Electrode

J Appl Polym Sci 2002, 83 (11): 2462-2466



Year 2001



7. Fu MX, Zhu YF, Tan RQ, et al.

Aligned Polythiophene Micro- and Nanotubules

Adv Mater 2001, 13 (24): 1874-1877





6. Wang F, Shi GQ, Chen F, et al.

Electrochemical Synthesis of Soluble Polythianaphthene

Acta Polym Sin 2001, (6): 807-810





5. Xu JK, Shi GQ, Xu ZJ, et al.

Low Potential Electrochemical Polymerization of 3-Chlorothiophene in Mixed Electrolytes of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid

J Electroanal Chem 2001, 514 (1-2): 16-25





4. Shi GQ, Zhang JX, Chen FE, et al.

Electrochemical Copolymerization of 3-Methylthiophene and 3-Chlorothiophene

Acta Chim Sinica 2001, 59 (10): 1818-1822





3. Wang F, Shi GQ, Chen FG, et al.

Electrochemical Polymerization of Thianaphthene

J Electroanal Chem 2001, 510 (1-2): 29-34





2. Shi GQ, Chen FG, Wu SX, et al.

Polymerization of Chlorofluorocarbon-22 and Acetonitrile

J Appl Polym Sci 2001, 81 (1): 116-120





1. Guo L, Shi GQ, Liang YQ

Poly(Ethylene Glycol)S Catalyzed Homogeneous Dehydrochlorination of Poly(Vinyl Chloride) with Potassium Hydroxide

Polymer 2001, 42 (13): 5581-5587



Year 2000-1999



8. Wu SX, Ming L, Shi GQ, et al.

Liquid/solid Two-phase Carbonization of Low-molecular-weight Chloro-/bromo-hydrocarbons

J Appl Polym Sci 2000, 76 (10): 1510-1515





7. Shi GQ, Ming L, Wu SX, et al.

Carbonization of Trichloroethanes with Anhydrous Potassium Hydroxide

J Appl Polym Sci 2000, 76 (2): 185-189





6. Wang XF, Shi GQ, Liang YQ

Low Potential Electropolymerization of Thiophene at a Copper Oxide Electrode

Electrochem Commun, 1999, 1 (11): 536-539





5.Shi GQ, Li C, Liang YQ

High-Strength Conducting Polymers Prepared by Electrochemical Polymerization in Boron Trifluoride Diethyl Etherate Solution

Adv Mater 1999, 11 (13): 1145-1146





4. Wang XF, Shi GQ, Liang YQ

Synthesis of carbyne-like nano-particles by electrocatalytic dehydrochlorination of 1,1,2-trichloroethane

J Electroanal Chem 1999, 470 (1): 95-97





3. Li C, Shi GQ, Liang YQ

Electrochemical Synthesis of Free-Standing Poly(Para-Phenylene) Films in Composite Electrolytes of Boron Trifluoride Diethyl Etherate and Sulfuric Acid

Synthetic Met 1999, 104 (2): 113-117





2. Guo L, Shi GQ, Liang YQ

High-Quality Polyene Films Prepared by Poly (Ethylene glycol)s Catalyzed Dehydrochlorination of Poly (Vinyl chloride) with Potassium Hydroxide

Eur Polym J 1999, 35 (2): 215-220





1. Guo L, Shi GQ, Liang YQ

Polyene Films Prepared by Poly(Ethylene Glycol)S-Catalyzed Dehydrochlorination of Poly(Vinyl Chloride): Chemical and Electrochemical Properties

Synthetic Met 104 (2): 129-135 JUL 8 1999



Year 1998-1994



17. Shi GQ

Synthesis of carbyne nano-particles by dehydrochlorination of 1,1,1 -trichloroethane

CHEM. COMMUN., 1: 2271-2272, 1998



16. Guo L, Shi GQ, Liang YQ

Electrosynthesis of Soluble Polyaniline in Acetic Acid

Polym Bull 1998, 41 (6): 681-686





15. Lu YQ, Shi GQ, Li C, et al.

Thin Polypyrrole Films Prepared by Chemical Oxidative Polymerization

J Appl Polym Sci 1998, 70 (11): 2169-2172





14. Guo L, Shi GQ, Du XZ, et al.

Poly(Ethylene glycol)s Catalyzed Two-Phase Dehydrochlorination of Poly(Vinyl Chloride) with Potassium Hydroxide

J Appl Polym Sci 1998, 70 (12): 2463-2469





13. Li C, Shi GQ, Liang YQ

Low Potential Electrochemical Polymerization of Benzene in a Composite Electrolyte of Boron Trifluoride Diethyl Etherate and Trifluoroacetic Acid

J Electroanal Chem 1998, 455 (1-2): 1-4





12. Li C, Shi GQ, Liang YQ, et al.

High-Strength Metallic Plastic Sheet Prepared by Electrochemical Polymerization of Thiophene on Stainless Steel

J Appl Polym Sci 1998, 68 (6): 1027-1029





11. Li C, Shi GQ, Liang YQ, et al.

Crystalline Polythiophene Film Prepared by Electrochemical Polymerization of Thiophene at a Nickel Electrode

Polymer 1997, 38 (26): 6421-6422





10. Li C, Shi GQ, Liang YQ, et al.

High-Quality Poly(P-Phenylene) Film Prepared by Electrochemical Polymerization of Benzene at a Stainless Steel Electrode

Polymer 1997, 38 (20): 5023-5026





9.Li HH, Shi GQ, Ye W, et al.

Polypyrrole Carbon Fiber Composite Film Prepared by Chemical Oxidative Polymerization of Pyrrole

J Appl Polym Sci 1997, 64 (11): 2149-2154





8.Shi GQ, Li C, Yu B, et al.

Deposition of Polythiophene Films onto p-type Silicon

Polymer 1997, 38 (5): 1247-1249





7.Li C, Shi GQ, Xue G, et al.

High-Quality Polythiophene Films Prepared By Electropolymerization of Thiophene in BF3-Ethyl Ether Solution

J Polym Sci Pol Phys 1995, 33 (16): 2199-2203





6. Shi GQ, Jin S, Xue G, et al.

A Conducting Polymer Film Stronger Than Aluminum

Science 1995, 267 (5200): 994-996





5. Shi GQ, Yu B, Xue G, et al.

Electrochemical Fabrication of a P-Type Silicon-Polythiophene P-N-Junction Diode

J Chem Soc Chem Comm 1994, (22): 2549-2550





4. Shi GQ, Xue G, LI C, et al.

Layered Poly(Naphthalene) Films Prepared by Electrochemical Polymerization

Polym Bull 1994, 33 (3): 325-329





3. Shi GQ, Xue G, LI C, et al.

Uniaxial Oriented Poly(P-Phenylene) Fibrils and Films

Macromolecules 1994, 27 (13): 3678-3679 JUN 20





2. Xue G, Lu Y, Shi GQ, et al.

Glass-Transition of Expanded Polystyrene Coils

Polymer 1994, 35 (4): 892-894





1. Xue G, Lu Y, Shi GQ

Sers Studies of Synergetic Effect in Corrosion Inhibition for Cu by a 2-Component Inhibitor System of Polyvinylimidazole and Benzimidazole

Appl Surf Sci 1994, 74 (1): 37-41



Year 1994 Before
16、Hou W, Peng BC, Yan QJ, Fu XC, Shi GQ

The first silica-pillared layered niobate

J. Chem. Soc., Chem. Commun., 253-254, 1993



15． Shi GQ, Xue G, Hou WH, Dong J

Electrochemical behavior of MOR zeolite in poly (ethylene oxide) oligomer

J. Electroanal. Chem., 344:363, 1993



14．Xue G, Lu Y, Shi GQ, Dai QP

Glass transition expaned polystyrene coils

polymer, 35:892, 1993



13． Shi GQ, Xue G, Wang GQ, Hou WH

Electrochemical behavior of NaX and ZSM-5 zeolites in poly(ethylene

glycol) oligomer

Chinese Sci. Bull., 38:1443, 1993



12．石高全,薛奇,王国祥,候文华

Nax, ZSM-5分子筛在乙二醇低聚物中的电化学行为

科学通报, 38:617, 1993



11． 石高全,薛奇, 李村,马万里,金士

萘在三氟化硼乙醚溶液中的电化学聚合

高等学校化学学报, 14:1623-1624, 1993



10. 石高全,薛奇

丝光沸石在乙二醇低聚物中的电化学行为

南京大学学报, 29:259-262,1993



9. Shi GQ

Matrix chain-length dependence of the electrochemitry of electroactive

molecules in amorphous polymeric solvents

J. Phys. Chem. 96:4677, 1992



8. Shi GQ, Xue G, Wu ZB, Shen B

Matrix chain-length dependence of the electrochemistry of electroactive

molecules in melton ionic conductive polymer electrolytes

J. Electroanal. Chem., 338: 353-357, 1992



7. 薛奇, 石高全,顾晓红

在位表面增强拉曼散射研究金属表面化学反应

光散射学报, 4:86,1992



6. 薛奇,石高全,董雪吟

高分子,生物高分子与金属复合物界面结构的表面增强拉曼光谱研究

光散射学报,4:162, 1992



5. Shi GQ, Ohno H

Electrochemical behavior of hemin and PEO-hemin in ionic conductive

polymer matrices

J. Electroanal. Chem., 314: 59-69, 1991



4. Xue G, Shi GQ, Ding JF, Zhang WM, Chen RS

Complex-induced coupling effect: adhesion of some polymers to copper

metal promoted by benzimidazole

J. Adhesion Sci. Tech., 4:723, 1990



3. Shi GQ, Ohno H, Suzuki T, Yamakuci N

Electrochemical behavior of PEO-hemin in solid polymer electrolytes

in B. V. Chaodari et al eds, “Recent advances in fast ion conducting

materials and devices”

World Scientific, Singapore, 273, 1990







2. Xue G, Zhang JF, Shi GQ, Wu PY

Spectroscopic studies on the polymerization of benzimidazole with

metallic copper

J. Chem. Soc., Perkin Trans II, 33-36, 1989



1. Xue G, Zhang JF, Huang XY, Shi GQ

Chemical reaction of metallic copper with imidazole

J. Chem. Soc., Dalton Trans., 1487, 1988