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Hierarchical Zn-Doped CoO Nanoflowers for Electrocatalytic Oxygen Evolution Reaction

本站小编 Free考研/2020-04-17

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Hierarchical Zn-Doped CoO Nanoflowers for Electrocatalytic Oxygen Evolution Reaction
文献类型:期刊
通讯作者:Zheng, HQ; Cao, R (reprint author), Shaanxi Normal Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710119, Shaanxi, Peoples R China.; Cao, R (reprint author), Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China.
期刊名称:CHEMCATCHEM影响因子和分区
年:2019
卷:11
期:5
页码:1480-1486
ISSN:1867-3880
关键词:Hierarchical structure; Zn doping; CoO; Electrocatalysts; Oxygen evolution
所属部门:化学系
摘要:Hierarchical Zn-doped CoO nanoflowers have been prepared using their hydroxides as precursors. The nanoflowers are assembled by dozens of 2D nanoplates. Each nanoplate is formed by numerous Zn-doped CoO nanoparticles. Zn-doped CoO catalyst is highly efficient for electrocatalytic water oxidation with a low overpotential (eta=293 mV at j=10 mA cm(-2)) and long-term stability, which is comparable to the commercial RuO2 catalysts in alkaline media. The 3D hierarchical structure provides abundant su ...More
Hierarchical Zn-doped CoO nanoflowers have been prepared using their hydroxides as precursors. The nanoflowers are assembled by dozens of 2D nanoplates. Each nanoplate is formed by numerous Zn-doped CoO nanoparticles. Zn-doped CoO catalyst is highly efficient for electrocatalytic water oxidation with a low overpotential (eta=293 mV at j=10 mA cm(-2)) and long-term stability, which is comparable to the commercial RuO2 catalysts in alkaline media. The 3D hierarchical structure provides abundant surface catalytic sites, while the density functional theory (DFT) calculations show that the Zn doping is also beneficial for the enhanced oxygen evolution reaction (OER) activities. This series of novel hierarchical porous nanoflowers is a promising anode material for water oxidation. ...Hide

DOI:10.1002/cctc.201801908
百度学术:Hierarchical Zn-Doped CoO Nanoflowers for Electrocatalytic Oxygen Evolution Reaction
语言:外文
被引频次:
3
人气指数:3
浏览次数:3
基金:National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21601118, 21101170, 21573139, 21773146]; "Thousand Talents Program" of China; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [GK201903033]; Starting Research Funds of Shaanxi Normal University
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