文献详情
Nitration-Peroxidation of Alkenes: A Selective Approach to beta-Peroxyl Nitroalkanes
文献类型：期刊
通讯作者：Li, ZP (reprint author), Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China.
期刊名称：ORGANIC LETTERS影响因子和分区
年：2019
卷：21
期：5
页码：1480-1483
ISSN：1523-7060
所属部门：化学系
摘要：Nitration-peroxidation of alkenes for the synthesis of beta-peroxyl nitroalkanes has been developed by using tert-butyl nitrite and tert-butyl hydroperoxide. The method presents a new and selective difunctionalization of alkenes to introduce a nitro group and a peroxyl group across the double bonds of alkenes under mild conditions. A radical reaction pathway is proposed by experimental and theoretical studies.
DOI：10.1021/acs.orglett.9b00266
百度学术：Nitration-Peroxidation of Alkenes: A Selective Approach to beta-Peroxyl Nitroalkanes
语言：外文
被引频次：9
人气指数：3
浏览次数：3
基金：National Natural Science Foundation of ChinaNational Natural Science Foundation of China [21672259]
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