文献详情
Manganese-Catalyzed Selective Upgrading of Ethanol with Methanol into Isobutanol
文献类型：期刊
期刊名称：ChemSusChem影响因子和分区
年：2019
ISSN：1864-564X
关键词：Guerbet reaction,ethanol,isobutanol,manganese,methanol
所属部门：化学系
摘要：Isobutanol serves as an ideal gasoline additive owing to its good compatibility with current engine technology, high energy density, and high octane number. Herein, an efficient and selective Mn-catalyzed upgrading of ethanol with methanol into isobutanol is reported. This is the first example of deoxygenative coupling of lower alcohols to isobutanol by using a homogeneous non-noble-metal catalyst. This transformation proceeded at very low catalyst loading with a high turnover number (9233) and ...More
Isobutanol serves as an ideal gasoline additive owing to its good compatibility with current engine technology, high energy density, and high octane number. Herein, an efficient and selective Mn-catalyzed upgrading of ethanol with methanol into isobutanol is reported. This is the first example of deoxygenative coupling of lower alcohols to isobutanol by using a homogeneous non-noble-metal catalyst. This transformation proceeded at very low catalyst loading with a high turnover number (9233) and up to 96?% isobutanol selectivity.? 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. ...Hide

DOI：10.1002/cssc.201802689
百度学术：Manganese-Catalyzed Selective Upgrading of Ethanol with Methanol into Isobutanol
语言：外文
人气指数：2
浏览次数：2
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