曹睿，教授，男，1981年3月出生，湖南省益阳市人。2003年从北京大学化学与分子工程学院获得学士学位，2008年从美国埃默里大学(EmoryUniversity)化学系获得博士学位。分别于2008－2009年在埃默里大学化学系，2009－2011年在麻省理工学院(MassachusettsInstituteofTechnology)化学系StephenJ.Lippard课题组进行博士后研究工作。2011年加入中国人民大学化学系，担任教授，博士生导师。2011年入选中组部第一批青年****。Email:ruicao@ruc.edu.cn;ruicao@chem.ruc.edu.cn电话：010-62519133教授课程：目前讲授本科生普通化学实验课程。主要研究领域：通过使用有机金属簇主体，从结构和功能上模拟生物界中含三个或三个以上金属中心的蛋白酶，比如多铜氧化酶，许多参与磷酸生物代谢的酶，等。有利于我们（1）进一步了解生物体系中多个金属中心的协同作用，以及生物体系中小分子活化的机制；（2）设计开发高效的人工合成的酶，从而实现如下过程：i.氧气的活化，二氧化碳和氮气的固定ii.磷酸及其衍生物的水解，水的催化氧化除了以上与生物和能源相关的课题外，离子的识别和控制等于环境相关的问题也是我们主要的研究方向。科研项目：中组部青年****；国家自然科学基金青年基金；中国人民大学启动基金。近五年来发表的代表性论文：1.Cao,R.;McCarthy,B.D.;Lippard,S.J.“Immobilization,Trapping,andAnionExchangeofPerrhenateIonUsingCopper-BasedTripodalComplexes”Inorg.Chem.2011,ASAP,DOI:10.1021/ic201172r.2.Li,Y.;Cao,R.;Lippard,S.J.“DesignandSynthesisofaNovelTriptycene-BasedLigandforModelingCarboxylate-BridgedDiironEnzymeActiveSites”Org.Lett.2011,ASAP,DOI:10.1021/ol201882v.3.Cao,R.;Müller,P.;Lippard,S.J.“TripodalTris-tacnandTris-dpaPlatformsforAssemblingPhosphate-TemplatedTrimetallicCenters”J.Am.Chem.Soc.2010,132,17366-17369.4.Cao,R.;O’Halloran,K.P.;Hillesheim,D.A.;Lense,S.;Hardcastle,K.I.;Hill,C.L.“ControlledSynthesisofaFunctionalizedPolytungstateLigandanda{MaMbMc(PW9)2}SandwichComplex”CrystEngComm2011,13,738-740.5.Cao,R.;O’Halloran,K.P.;Hillesheim,D.A.;Hardcastle,K.I.;Hill,C.L.“Mono-substitutedKeggin,Wells-Dawsonand{P2W21}-TypePolyoxometalateswithoutPositionalDisorder”CrystEngComm2010,12,1518-1525.6.Boone,M.A.;Tong,R.B.;McDonald,F.E.;Lense,S.;Cao,R.;Hardcastle,K.I.“BiomimeticSynthesesfromSqualene-LikePrecursors:Synthesisofent-AbudinolBandReassessmentoftheStructureofMuzitone”J.Am.Chem.Soc.2010,132,5300-5308.7.Fang,X.K.;Speldrich,M.;Schilder,H.;Cao,R.;O'Halloran,K.P.;Hill,C.L.;Kogerler,P.“SwitchingslowrelaxationinaMnIII3MnIVcluster:anexampleofgraftingsingle-moleculemagnetsontopolyoxometalates”Chem.Comm.2010,46,2760-2765.8.Geletii,Y.V.;Besson,C.;Hou,Y.;Yin,Q.S.;Musaev,D.G.;Quinonero,D.;Cao,R.;Hardcastle,K.I.;Proust,A.;Kogerler,P.;Hill,C.L.“Structural,Physicochemical,andReactivityPropertiesofanAll-inorganic,HighlyActiveTetrarutheniumHomogeneousCatalystforWaterOxidation”J.Am.Chem.Soc.2009,131,17360-17370.9.Luo,Z.;Kögerler,P.;Cao,R.;Hill,C.L.“Synthesis,Structure,andMagnetismofaPolyoxometalatewithCoordinativelyUnsaturatedd-Electron-TransitionMetalCenters”Inorg.Chem.2009,48,7812-7817.10.Besson,C.;Musaev,D.G.;Lahootun,V.;Cao,R.;Chamoreau,L.M.;Villanneau,R.;Villain,F.;Thouvenot,R.;Geletii,Y.V.;Hill,C.L.;Proust,A.“VicinalDinitridoruthenium-SubstitutedPolyoxometalatesg-[XW10O38{RuN}2]6-(X=SiorGe)”Chem.Eur.J.2009,15,10233-10243.11.Cao,R.;Ma,H.;Geletii,Y.V.;Hardcastle,K.I.;Hill,C.L.“StructurallyCharacterizedIridium(III)-ContainingPolytungstateandCatalyticWaterOxidationActivity”Inorg.Chem.2009,48,5596-5598.12.Boone,M.A.;McDonald,F.E.;Lichter,J.;Lutz,S.;Cao,R.;HardcastleK.I.“1,5-a-D-Mannoseptanosides,Ring-sizeIsomersThatAreImpervioustoa-Mannosidase-catalyzedHydrolysis”Org.Lett.2009,11,851-854.13.Luo,Z.;Kögerler,P.;Cao,R.;Hill,C.L.“Synthesis,StructureandMagnetismofAOne-DimensionalSilicotungstateArray:K3H4Cu0.5{Cu[Cu7.5Si2W16O60-(H2O)4(OH)4]2}·9H2O”Polyhedron2009,28,215-220.14.Cao,R.;Anderson,T.M.;Hillesheim,D.A.;Kögerler,P.;Hardcastle,K.I.;Hill,C.L.“Platinum-containingPolyoxometalates”Angew.Chem.Int.Ed.2008,47,9380-9382.15.Cao,R.;Han,J.W.;Anderson,T.M.;Hillesheim,D.A.;Hardcastle,K.I.;Slonkina,E.;Hedman,B.;Hodgson,K.O.;Kirk,M.L.;Musaev,D.G.;Morokuma,K.;Geletii,Y.V.;Hill,C.L.“LateTransitionMetalOxoCompoundsandOpenFrameworkMaterialsThatCatalyzeAerobicOxidations”Adv.Inorg.Chem.2008,60,245-272.16.Li,C.;Cao,R.;O’Halloran,K.P.;Ma,H.;Wu,L.“Preparation,characterizationandbifunctionalelectrocatalysisofaninorganic–organiccomplexwithavanadium-substitutedpolyoxometalate”ElectrochimicaActa2008,54,484-489.17.Luo,Z.;Kögerler,P.;Cao,R.;Hakim,I.;Hill,C.L.“Synthesis,StructureandMagnetismofANewDimericSilicotungstate:K9Na2Cu0.5[g-Cu2(H2O)SiW8O31]2·38H2O”DaltonTrans.2008,54-58.18.Cao,R.;Anderson,T.M.;Piccoli,P.M.B.;Schultz,A.J.;Koetzle,T.F.;Geletii,Y.V.;Slonkina,E.;Hedman,B.;Hodgson,K.O.;Hardcastle,K.I.;Fang,X.;Kirk,M.L.;Knottenbelt,S.;Kögerler,P.;Musaev,D.G.;Morokuma,K.;Takahashi,M.;Hill,C.L.“TerminalGold-OxoComplexes”J.Am.Chem.Soc.2007,129,11118-11133.19.Hill,C.L.;Delannoy,L.;Duncan,D.C.;Weinstock,I.A.;Renneke,R.F.;Reiner,R.S.;Atalla,R.H.;Han,J.W.;Hillesheim,D.A.;Cao,R.;Anderson,T.M.;Okun,N.M.;Musaev,D.G.;Geletii,Y.V.“ComplexCatalystsfromSelf-repairingEnsemblestoHighlyReactiveAir-basedOxidationSystems”C.R.Chimie2007,10,305-312.20.Tong,R.;Valentine,J.C.;McDonald,F.E.;Cao,R.;Fang,X.;Hardcastle,K.I.“TotalSynthesesofDurgamone,Nakorone,andAbudinolBviaBiomimeticOxa-andCarbacyclizations”J.Am.Chem.Soc.2007,129,1050-1051.21.Hill,C.L.;Anderson,T.M.;Han,J.W.;Hillesheim,D.A;Geletii,Y.V.;Okun,N.M.;Cao,R.;Botar,B.;Musaev,D.G.;Morokuma,K.“NewComplexesandMaterialsforO2-basedOxidations”J.Mol.Catal.A:Chem.2006,251,234-238.
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