刘东方1,
杨丹1,
魏孝承1,
黄文力1
1.南开大学环境科学与工程学院,天津 300350
基金项目: 国家重点研发项目(2016YFD0801002-01)
天津市科技支撑计划项目(201601190)
天津市滨海新区科技计划项目
Extraction of heavy metal from pig manure using ultrasound and inorganic acid
DU Liqiong1,,LIU Dongfang1,
YANG Dan1,
WEI Xiaocheng1,
HUANG Wenli1
1.School of Environmental Science and Engineering, Nankai University, Tianjin 300350,China
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摘要:对比研究了无机酸及超声对猪粪中重金属Cu、Zn和Mn的去除效果,并对处理前后猪粪中重金属形态变化进行分析。结果表明:无机酸浸提优化条件下Cu、Zn和Mn的浸出率分别为43.24%、76.28%和78.91%;超声协同无机酸浸提优化条件下Cu、Zn和Mn的浸出率分别为39.6%、76.3%和79.9%;2种浸提方式均能显著降低猪粪中重金属有机结合态含量。
关键词: 无机酸/
超声/
重金属/
猪粪/
形态/
养分
Abstract:This paper studied the removal effects of the inorganic acid and ultrasound on heavy metals Cu, Zn and Mn from pig manure, and changes in fractions of these heavy metals in pig manure before and after the extraction. In general, for the inorganic acid, the removal efficiencies of Cu, Zn and Mn reached 43.24%, 76.28%, 78.91% and for the ultrasound-assisted inorganic acid, the removal efficiencies of Cu, Zn and Mn reached 39.6%,76.3%,79.9% under the optimal conditions. Two kinds of extraction methods can significantly reduce organic matter fraction of heavy metals.
Key words:inorganic acid/
ultrasound/
heavy metal/
pig manure/
speciation/
fertility.
[1] | LI Y X, LI W, WU J, et al.Contribution of additives Cu to its accumulation in pig feces: Study in Beijing and Fuxin of China[J].Journal of Environmental Sciences,2007,19(5):610-615 |
[2] | 王森, 焦瑞峰, 马艳华, 等.我国畜禽粪便综合利用途径研究[J].河南科技学院学报(自然科学版),2017,45(1):20-24 |
[3] | 杨慧敏, 常丽春, 阎中, 等.生物沥浸法去除猪粪中重金属的研究[J].环境工程学报,2009,3(6):1103-1108 |
[4] | BONAZZI G, MAESTRI E, MANTOVI P, et al.Accumulation of copper and zinc from liquid manure in agricultural soils and crop plants[J].Plant and Soil,2003,250(2):249-257 |
[5] | ZHOU D M, HAO X Z, WANG Y J, et al.Copper and Zn uptake by radish and pakchoi as affected by application of livestock and poultry manures[J].Chemosphere,2005,59(2):167-175 |
[6] | WONG M H, CHAN K M, LIU W K.Trace metal concentrations in tilapia fed with pig and chicken manure[J].Conservation Recycling,1984,7(2/3/4):351-360 |
[7] | MEEGODA J N, PERERA R.Ultrasound to decontaminate heavy metals in dredged sediments[J].Journal of Hazardous Materials,2001,85(1/2):73-89 |
[8] | 张春雷, 费小通, 李婷, 等.利用超声波辅助去除污染土壤中重金属的研究[J].环境科学与技术,2014,37(S1):121-124 |
[9] | 邱琼瑶, 周航, 邓贵友, 等.污染土壤中重金属的超声波强化EDTA洗脱及形态变化[J].环境科学学报,2014,34(9):2392-2397 |
[10] | WANG X J, CHEN J, YAN X B, et al.Heavy metal chemical extraction from industrial and municipal mixed sludge by ultrasound-assisted citric acid[J].Journal of Industrial and Engineering Chemistry,2015,27:368-372 |
[11] | 杨宁, 杨洋, 彭亮, 等.超声和酸化对猪粪中Cu、Zn去除的影响[J].农业环境科学学报,2014,33(7):1429-1435 |
[12] | 涂剑成, 赵庆良, 杨倩倩.超声辐射协同草酸-HEDTA浸提污泥中重金属[J].中国环境科学,2011,31(8):1280-1284 |
[13] | 杨海琳, 廖柏寒.低分子有机酸去除土壤中重金属条件的研究[J].农业环境科学学报,2010,29(12):2330-2337 |
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超声和无机酸浸提猪粪中的重金属
杜丽琼1,,刘东方1,
杨丹1,
魏孝承1,
黄文力1
1.南开大学环境科学与工程学院,天津 300350
基金项目: 国家重点研发项目(2016YFD0801002-01) 天津市科技支撑计划项目(201601190) 天津市滨海新区科技计划项目
关键词: 无机酸/
超声/
重金属/
猪粪/
形态/
养分
摘要:对比研究了无机酸及超声对猪粪中重金属Cu、Zn和Mn的去除效果,并对处理前后猪粪中重金属形态变化进行分析。结果表明:无机酸浸提优化条件下Cu、Zn和Mn的浸出率分别为43.24%、76.28%和78.91%;超声协同无机酸浸提优化条件下Cu、Zn和Mn的浸出率分别为39.6%、76.3%和79.9%;2种浸提方式均能显著降低猪粪中重金属有机结合态含量。
English Abstract
Extraction of heavy metal from pig manure using ultrasound and inorganic acid
DU Liqiong1,,LIU Dongfang1,
YANG Dan1,
WEI Xiaocheng1,
HUANG Wenli1
1.School of Environmental Science and Engineering, Nankai University, Tianjin 300350,China
Keywords: inorganic acid/
ultrasound/
heavy metal/
pig manure/
speciation/
fertility
Abstract:This paper studied the removal effects of the inorganic acid and ultrasound on heavy metals Cu, Zn and Mn from pig manure, and changes in fractions of these heavy metals in pig manure before and after the extraction. In general, for the inorganic acid, the removal efficiencies of Cu, Zn and Mn reached 43.24%, 76.28%, 78.91% and for the ultrasound-assisted inorganic acid, the removal efficiencies of Cu, Zn and Mn reached 39.6%,76.3%,79.9% under the optimal conditions. Two kinds of extraction methods can significantly reduce organic matter fraction of heavy metals.