中文关键词镧锆改性沸石镧改性沸石锆改性沸石底泥磷释放控制对比 英文关键词lanthanum/zirconium-modified zeolitelanthanum-modified zeolitezirconium-modified zeolitesedimentary phosphorus release controlcomparison

作者	单位	E-mail
刘婷	上海海洋大学海洋生态与环境学院, 上海 201306	1760216900@qq.com
赵钰颖	上海海洋大学海洋生态与环境学院, 上海 201306
林建伟	上海海洋大学海洋生态与环境学院, 上海 201306	jwlin@shou.edu.cn
詹艳慧	上海海洋大学海洋生态与环境学院, 上海 201306	yhzhan@shou.edu.cn
秦琴	中检集团理化检测有限公司, 上海 200436

中文摘要 本研究采用镧和锆作为改性剂制备了3种不同类型的改性沸石，即锆改性沸石（ZrMZ）、镧改性沸石（LaMZ）和镧锆改性沸石（LaZrMZ），对比考察了其对水中磷酸盐的吸附作用，并对比研究了其添加对上覆水、间隙水和底泥中磷的影响.结果发现，3种改性沸石均可有效地吸附水中的磷酸盐，且LaZrMZ对水中磷酸盐的吸附性能明显优于LaMZ和ZrMZ.3种改性沸石添加均可有效地降低上覆水和间隙水中SRP的浓度.LaMZ对底泥中潜在活性磷的钝化效果优于LaZrMZ，而后者又优于ZrMZ.3种改性沸石添加均可以降低底泥中水溶性磷（WSP）、藻类可利用磷（AA-P）和铁氧化物-滤纸提取磷（FeO-P）的含量，WSP和AA-P削减效应的排序为：LaMZ > LaZrMZ > ZrMZ，FeO-P削减效应的排序为：LaZrMZ > ZrMZ > LaMZ.LaZrMZ和LaMZ添加均可以降低底泥中易解吸磷（RDP）的含量，且削减效应的排序为：LaMZ>LaZrMZ.LaZrMZ和ZrMZ添加均可以降低底泥中NaHCO₃提取磷（Olsen-P）的含量，且削减效应的排序为：LaZrMZ>ZrMZ.以上结果显示，镧、锆和镧锆改性沸石均可以有效控制水体内源磷向上覆水的释放；从吸附容量和生物可利性磷钝化效果看，镧锆联合改性沸石是一种非常有希望的用于控制水体内源磷释放的底泥改良材料. 英文摘要 In this study, the adsorption characteristics of phosphate on zirconium-modified zeolite (ZrMZ), lanthanum-modified zeolite (LaMZ) and lanthanum/zirconium-modified zeolite (LaZrMZ) were comparatively investigated, and the effect of ZrMZ, LaMZ, and LaZrMZ addition on the mobilization of phosphorus (P) in sediments was comparatively studied. Results showed that the phosphate adsorption capacity decreased in the order of LaZrMZ > LaMZ > ZrMZ. The addition of LaZrMZ, LaMZ, and ZrMZ in sediments all could effectively reduce the concentrations of soluble reactive P (SRP) in the overlying and pore waters. Furthermore, the addition of LaZrMZ, LaMZ and ZrMZ all could decrease the amount of mobile P in sediments, and the reduction rate decreased in the order of LaMZ > LaZrMZ > ZrMZ. The amendment of sediments with LaZrMZ, LaMZ, and ZrMZ all could lead to a decrease in the amount of water-soluble P (WSP), algal available P (AA-P) and iron oxide-filter paper extractable P (FeO-P) in the sediments. The reduction rate of WSP and AA-P decreased in the order of LaMZ > LaZrMZ > ZrMZ, and the reduction rate of FeO-P decreased in the order of LaZrMZ > ZrMZ > LaMZ. The addition of LaZrMZ and LaMZ both could reduce the content of readily desorbed P (RDP), and the reduction rate decreased in the order of LaMZ>LaZrMZ. The LaZrMZ and ZrMZ amendments both could decrease the concentration of NaHCO₃ extractable P (Olsen-P) in sediments, and the reduction rate decreased in the order of LaZrMZ>ZrMZ. The results of this study demonstrate that the addition of ZrMZ, LaMZ, and LaZrMZ in sediments all could effectively intercept the upward mobilization of sedimentary P to the overlying water, and LaZrMZ is a very promising amendment for the control of the internal P loading from the point of view of both phosphate adsorption ability and bioavailable P immobilization efficiency.

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