中文关键词挥发性芳香烃稳定碳同位素环境空气污染源来源分析 英文关键词volatile aromatic compoundsstable carbon isotope ratioambient airpollution sourcesource apportionment

作者	单位	E-mail
李颖慧	华北电力大学环境科学与工程学院, 资源环境系统优化教育部重点实验室, 北京 102206 华北电力大学可再生能源学院, 北京 102206	liyinghui2008@hotmail.com
闫雨龙	华北电力大学环境科学与工程学院, 资源环境系统优化教育部重点实验室, 北京 102206	yanyulong@yeah.net
李志生	中国石油勘探开发研究院天然气地质所, 廊坊 065007
郝爱胜	中国石油勘探开发研究院天然气地质所, 廊坊 065007
李如梅	华北电力大学环境科学与工程学院, 资源环境系统优化教育部重点实验室, 北京 102206
杨帆	华北电力大学环境科学与工程学院, 资源环境系统优化教育部重点实验室, 北京 102206
彭林	华北电力大学环境科学与工程学院, 资源环境系统优化教育部重点实验室, 北京 102206	penglin6611@163.com

中文摘要 利用Tenax TA吸附管采集太原市不同排放源及不同功能区环境空气样品，色谱-质谱、同位素质谱联用技术测定了其挥发性芳香烃化合物的碳同位素组成，并分析了其组成特征.结果表明，柴油挥发源、汽油挥发源、溶剂挥发源、机动车尾气源和民用燃煤源排放的挥发性芳香烃化合物中稳定碳同位素值（δ¹³C）测定范围依次为：（-30.79±0.98）‰~（-29.10±0.14）‰、（-30.96±0.88）‰~（-28.02±1.77）‰、（-32.13±0.59）‰~（-27.67±0.49）‰、（-27.58±0.16）‰~（-25.50±0.75）‰和（-25.14±0.93）‰~（-23.44±1.32）‰，民用燃煤源显著富集¹³C.仅在民用燃煤源排放烟气中检出苯乙烯，δ¹³C值为（-23.44±1.32）‰.太原市4个不同功能区采样分析显示，居民交通混合区环境空气中挥发性芳香烃的δ¹³C值为（-25.61±2.20）‰~（-23.91±0.78）‰，较其他区域富集¹³C；工业区δ¹³C检测值为（-29.15±1.06）‰~（-24.53±1.07）‰，较其他区域贫¹³C.将环境空气中挥发性芳香烃δ¹³C值与排放源δ¹³C值比较可发现，太原市4个环境空气点位的挥发性芳香烃主要来源是机动车尾气源和民用燃煤源，工业区受溶剂挥发影响较大. 英文摘要 This study used Tenax TA absorption tubes to sample volatile aromatic compounds from different emission sources and functional zones in Taiyuan City, Shanxi Province, China. Thermal desorption-gas chromatography-isotope ratio mass spectrometry (TD-GC-IRMS) was subsequently employed to analyze the stable carbon isotope characteristics of the volatile aromatic compounds. The results revealed that the stable carbon isotope ratio (δ¹³C) of the volatile aromatic compounds emitted through diesel, gasoline, and solvent volatilization, vehicle exhaust, and domestic coal combustion ranged from (-30.79±0.98)‰ to (-29.10±0.14)‰, (-30.96±0.88)‰ to (-28.02±1.77)‰, (-32.13±0.59)‰ to (-27.67±0.49)‰, (-27.58±0.16)‰ to (-25.50±0.75)‰, and (-25.14±0.93)‰ to (-23.44±1.32)‰, respectively. The δ¹³C value of styrene was (-23.44±1.32)‰, which was only detected in the fumes emitted through domestic coal combustion. Additionally, the sample analysis based on data collected from four different functional zones of Taiyuan City revealed the following:① the δ¹³C values of the atmospheric volatile aromatic compounds in the mixed residential and traffic zone ranged from (-25.61±2.20)‰ to (-23.91±0.78)‰. Compared with other functional zones, the emissions in this zone were enriched with¹³C; and ② the δ¹³C values measured in the industrial zone ranged from (-29.15±1.06)‰ to (-24.53±1.07)‰; the emissions in this functional zone were relatively low in ¹³C compared with other zones. A comparison of the δ¹³C values of the atmospheric volatile aromatic compounds and emission sources indicated that the main sources of volatile aromatic compounds at the four sampling points in Taiyuan were vehicle exhausts and domestic coal combustion, while the air sampled in the industrial functional zone was heavily affected by the volatilization of solvents.

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