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水化学和环境同位素对济南东源饮用水源地地下水演化过程的指示

本站小编 Free考研考试/2021-12-31

中文关键词地下水水化学特征环境同位素水岩作用东源水源地 英文关键词groundwaterhydrogeochemical characteristicenvironmental isotopewater-rock interactionDongyuan groundwater source
作者单位E-mail
张雅中国地质大学环境学院, 武汉 430074nanasazya@163.com
苏春利中国地质大学环境学院, 武汉 430074chl.su@cug.edu.cn
马燕华海南省环境科学研究院, 海口 570026
刘伟江中国地质大学环境学院, 武汉 430074
生态环境部环境规划院长江经济带生态环境联合研究中心, 北京 100012
中文摘要 济南东源水源地属于岩溶裂隙水,是济南市的主要供水水源.以济南市东源水源地为研究区,通过对研究区地下水和地表水的主要离子含量、氢氧同位素比值分析,揭示了东源饮用水源地地下水的补给来源、地表水的影响及水岩作用过程.结果表明,区内地下水水化学类型相似,阳离子以Ca2+为主,阴离子以HCO3-和SO42-离子为主;大气降水是该地区地下水和河水的主要补给来源,且经历了不同程度的蒸发作用.地下水化学组分主要受水-岩作用的控制,方解石和石膏等贫镁矿物的溶解沉淀以及上覆第四系地层硅酸盐矿物的水解是区内地下水水化学组分的主要来源;部分地段河水污染渗漏补给地下水,造成地下水污染,主要超标指标为总硬度、NO3-、NH4+、SO42-、Fe和Mn. 英文摘要 The Dongyuan groundwater source area, which is the main drinking water source of Ji'nan City, is karst fissure water. To identify groundwater recharge sources, the influence of surface water, hydrochemical evolution, hydrochemical and isotopic components (2H and 18O) of groundwater and surface water samples collected from the Dongyuan groundwater source were investigated.The results showed that the hydrochemical characteristics of groundwater were similar, and the main ions were Ca2+, HCO3-, and SO42-. The groundwater, which suffered evaporation to varying degrees, was recharged mainly by precipitation. The hydrochemical composition of regional groundwater is mainly controlled by water-rock interactions, including dissolution/precipitation of carbonate minerals in the limestone aquifers and hydrolysis of silicates minerals in the quaternary aquifers, above the limestone aquifers. In some areas, groundwater was polluted by infiltration of river water. The main indicators of groundwater pollution that exceeded groundwater quality standards were total hardness, NO3-, NH4+, SO42-, Fe, and Mn.

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