中文关键词改性生物炭吸附氨氮磷 英文关键词modificationbiocharadsorptionammonia nitrogenphosphorus

作者	单位	E-mail
郅蒙蒙	西安建筑科技大学环境与市政工程学院, 西安 710055 中国环境科学研究院湖泊环境研究所, 北京 100012 湖泊水污染治理与生态修复技术国家工程实验室, 北京 100012	1841976614@qq.com
王鹏飞	中国环境科学研究院湖泊环境研究所, 北京 100012 湖泊水污染治理与生态修复技术国家工程实验室, 北京 100012
侯泽英	中国环境科学研究院湖泊环境研究所, 北京 100012 湖泊水污染治理与生态修复技术国家工程实验室, 北京 100012
曹晶	中国环境科学研究院湖泊环境研究所, 北京 100012 湖泊水污染治理与生态修复技术国家工程实验室, 北京 100012
储昭升	中国环境科学研究院湖泊环境研究所, 北京 100012 湖泊水污染治理与生态修复技术国家工程实验室, 北京 100012	chuzs@craes.org.cn
杨永哲	西安建筑科技大学环境与市政工程学院, 西安 710055

中文摘要 为提高人工湿地收割植物利用率并探讨水体中氨氮对镁改性生物炭（magnesium modified biochar，MBC）除磷效果的影响，本文以人工湿地植物芦苇为原料，引入金属镁离子对其改性，制备MBC，并以未改性生物炭（biochar，BC）为对照，通过批量摇床实验，研究了不同氮磷摩尔比（0、5、10）和初始磷浓度（100~500mg·L^-1）条件下，MBC、BC、BC与金属镁离子（BC+Mg²⁺）、Mg²⁺这4种处理方式对磷酸盐的去除效果.结果表明，4种处理方式对磷的去除量排序为MBC>>BC+Mg²⁺≈Mg²⁺>BC，溶液中NH₄⁺的存在促进MBC吸附除磷，氮磷摩尔比越大，初始磷浓度越高，MBC的磷吸附能力越强.XRD图谱分析结果表明，在MBC、BC+Mg²⁺、Mg²⁺这3种处理方式中，当氮磷摩尔比为5、10时，NH₄⁺与溶液中的Mg²⁺和PO₄^3-发生沉淀反应，生成鸟粪石（MgNH₄PO₄·6H₂O），促进磷的去除.本研究利用人工湿地废弃生物质对富含氨氮和磷酸盐的溶液进行处理，确定了氨氮对水体中磷酸盐去除的促进作用，达到了回收利用、以废治废的目的，为水体富营养化治理提供了新的理论依据和数据支持. 英文摘要 The effect of ammonia-nitrogen in water on phosphorus removal by magnesium modified biochar (MBC) was developed to increase the utilization of wetland plants. The crystal structures were measured by X-ray powder diffraction (XRD). MBC was prepared using reed as the biomass feedstock, which was modified with magnesium chloride. The raw biochar (BC) was prepared as a control. The removal of phosphate from solution using four different methods, i.e. MBC, BC, BC, and MgCl₂ solutions (BC+Mg²⁺) and MgCl₂ solutions (Mg²⁺), under different nitrogen to phosphorus molar ratios and initial phosphorus concentrations was investigated in batch experiments. The results demonstrated that the phosphorus removal efficiency of the four treatment methods, which followed the order of MBC>>BC+Mg²⁺≈Mg²⁺>BC. NH₄⁺ in the solution, promoted phosphorus removal by MBC. In addition, the larger the ratio of nitrogen to phosphorus and the higher the initial phosphorus concentration, the stronger the phosphorus removal capacity of MBC was. In the three treatments with MBC, BC+Mg²⁺, and Mg²⁺, the XRD analysis showed that NH₄⁺ reacted with Mg²⁺ and PO₄^3- in the solution to form MgNH₄PO₄·6H₂O at N:P=5 or 10, promoting the removal of phosphorus. For recycling purposes, waste biomass from constructed wetlands could be used to produce MBC and treat polluted water rich in ammonium and phosphate. Moreover, the ammonium-nitrogen promotes the phosphate removal by MBC. The results from this study provide a new theoretical basis and data support for the treatment of water eutrophication.

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