中文关键词PM_2.5有机碳(OC)元素碳(EC)生物质燃烧左旋葡聚糖 英文关键词PM_2.5organic carbon(OC)elemental carbon(EC)biomass burninglevoglucosan

作者	单位	E-mail
徐足飞	南京信息工程大学大气环境中心, 南京 210044	20151212192@nuist.edu.cn
曹芳	南京信息工程大学大气环境中心, 南京 210044	caofangle@163.com
高嵩	江苏省电力公司电力科学研究院, 南京 210000
鲍孟盈	南京信息工程大学大气环境中心, 南京 210044
石一凡	南京信息工程大学, 气象灾害预报预警与评估协同创新中心, 江苏省农业气象重点实验室, 南京 210044
章炎麟	南京信息工程大学大气环境中心, 南京 210044
刘晓妍	南京信息工程大学大气环境中心, 南京 210044
范美益	南京信息工程大学大气环境中心, 南京 210044
张雯淇	南京信息工程大学大气环境中心, 南京 210044
卞航	南京信息工程大学大气环境中心, 南京 210044
刘寿东	南京信息工程大学大气环境中心, 南京 210044

中文摘要 本研究于2015年10~11月在南京北郊分昼夜采集PM_2.5样品，采用热光透射法（TOT）和离子色谱法对样品中的有机碳（OC）/元素碳（EC）和左旋葡聚糖（levoglucosan）的质量浓度特征进行分析.观测期间OC和EC的平均浓度分别为（11.3±4.9）μg·m^-3和（1.1±0.9）μg·m^-3，总碳TC占PM_2.5的质量分数为22.9%，OC/EC的平均值为7.4，SOC占OC的质量分数为51.9%.PM_2.5、OC、EC和SOC质量浓度都体现出夜晚>白天的特征，白天OC和EC的相关性好于夜晚（相关性系数分别为0.86和0.7）.通过分析PM_2.5、左旋葡聚糖和SOC质量浓度以及后向轨迹和火点数据可知南京北郊在13~16号受到来自河北等地生物质燃烧远距离输送的影响.采样期间K⁺和左旋葡聚糖与OC、EC和SOC的相关性显著（相关性系数分别为0.78、0.79和0.65），经受体示踪物方法估算采样期间生物质燃烧对OC的贡献为21.9%. 英文摘要 In this study, PM_2.5 samples were collected from October to November of 2015 in the northern suburb of Nanjing. The mass concentrations of organic carbon (OC), elemental carbon (EC), and levoglucosan in the samples were analyzed by thermal optical transmittance (TOT) and ion chromatography. The average concentrations of OC and EC were respectively (11.3±4.9) μg·m^-3 and (1.1±0.9) μg·m^-3. The average total carbon (TC) was 22.9%, and the OC/EC was 7.4. The quality concentrations of PM_2.5, OC, EC, and SOC all reflected daytime features, and the correlation between OC and EC was better during the day than at night (correlation coefficients of 0.86 for day and 0.7 for night). By analyzing the mass concentrations of PM_2.5, levoglucosan, and SOC, as well as the data of backward trajectories and fire point data, it was determined that the northern suburb of Nanjing is affected by the long-distance transportation of biomass from Hebei and other places from October 13-16. The correlations between levoglucosan and OC, EC, or SOC were significant (correlation coefficients of 0.78, 0.79, and 0.65, respectively), and the contribution of biomass combustion during sampling to OC was 21.9%.

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