杨婷^1,3,
李丹丹²,
单玄龙¹,
王学中³,
张玮琦³,
张玉洁³,
毕方³,
柴发合³,
张浩^3,4,
赵妤希³,
孟令硕⁵,
李雷⁶,
李红^3,7
1. 吉林大学地球科学学院, 长春 130061;
2. 北京城市学院, 北京 100083;
3. 中国环境科学研究院, 环境基准与风险评估国家重点实验室, 北京 100012;
4. 山东大学环境研究院, 济南 250100;
5 法国滨海大学大气物理化学实验室, 敦克尔顿 59140;
6. 南京白云化工环境监测有限公司, 南京 210047;
7. 大气环境与装备技术协同创新中心, 南京 210044

作者简介: 杨婷(1991-),女,硕士研究生,研究方向为大气环境化学,E-mail:yangt152191@163.com.

基金项目: 国家科技支撑计划课题(2014BAC23B01) ；国家环境保护公益性行业科研专项项目(201409005)；中国科学院战略性先导科技专项(B类)(XDB05010200)；国家科技支撑计划课题(2014BAC06B01)


中图分类号: X171.5

Pollution Characterization, Source Apportionment and Health Risk Assessment of Benzene Homologues in the Ambient Air of a Typical Urban Area in Beijing, China

Yang Ting^1,3,
Li Dandan²,
Shan Xuanlong¹,
Wang Xuezhong³,
Zhang Weiqi³,
Zhang Yujie³,
Bi Fang³,
Chai Fahe³,
Zhang Hao^3,4,
Zhao Yuxi³,
Meng Lingshuo⁵,
Li Lei⁶,
Li Hong^3,7
1. College of Earth Sciences, Jilin University, Changchun 130061, China;
2. Beijing City University, Beijing 100083, China;
3. State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Academy of Environmental Sciences, Beijing 100012, China;
4. Environmental Research Institute, Shandong University, Jinan 250100, China;
5 Laboratory of Atmospheric Physicochemistry, University of Opal Coast, Dunkerque 59140, France;
6. Nanjing Baiyun Chemical Environmental Monitoring Co., Ltd., Nanjing 210047, China;
7. Collaborative Innovation Center on Atmospheric Environment and Equipment Technology, Nanjing 210044, China

CLC number: X171.5

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摘要:自2013年6月以来，利用Airmo VOC在线分析仪在北京市典型城区开展了环境空气中挥发性有机物(VOCs)的连续观测，选取2014年4个季节中各1个月的苯系物在线数据，分析了其浓度水平、变化特征、光化学反应活性，利用美国环保署(US EPA)提出的健康风险评价方法开展了有毒有害苯系物物种的健康风险评价，结合来源分析结果，明确北京市应重点控制的苯系物污染来源。研究区观测期间环境空气中16种苯系物的质量浓度为(22.64±16.83) μg·m^-3，且具有秋季 > 冬季 > 春季 > 夏季的特点，其中BTEX(苯、甲苯、乙苯和二甲苯)的质量浓度为(19.27±14.46) μg·m^-3，占苯系物浓度水平的41.09%~95.16%。研究区观测期间苯系物质量浓度夜间高于日间，日变化呈V字形，在13:00—15:00时质量浓度低。16种苯系物的臭氧生成潜势(OFP)的范围为66.62~170.67 μg·m^-3，其中间+对二甲苯、甲苯和邻二甲苯的OFP值相对较大；二次有机气溶胶生成潜势(SOAFP)的范围为0.71~1.86 μg·m^-3，其中甲苯、间+对二甲苯和乙苯的SOAFP值相对较大。研究区观测期间6种苯系物(BTEX和苯乙烯)的危害指数在8.19E-03~5.01E-02之间，在4个季节中对暴露人群尚不存在非致癌性风险；而Ⅰ类致癌物质苯的风险值处于7.13E-08~8.13E-06之间，在夏、秋和冬季对研究区暴露人群的人体健康均存在潜在的致癌性风险。来源分析结果表明，研究区春、秋季苯系物主要来源于机动车尾气的排放，其中春季还受到溶剂等挥发的影响，夏、冬季苯系物则主要来自于燃煤源。
关键词: 大气苯系物/
污染水平/
人体健康风险/
来源识别/
北京市

Abstract:The continuous observation of volatile organic compounds (VOCs) in the ambient air has been carried out in a typical urban area of Beijing by using an Airmo VOC online monitor since June 2013. The data sets in one month for each of the four seasons in 2014 was selected to study the ambient levels, variation characteristics, photochemical reactivities of 16 benzene homologues, health risk assessments of the toxic benzene homologues were made by adopting US. EPA's method, and the key emission sources for control management of benzene homologues were determined based on the source analytical results. The mass concentrations of 16 benzene homologues in the ambient air were (22.64±16.83) μg·m^-3 in the study area during the observation period, which had the seasonal variation characteristics of autumn > winter > spring > summer. The total mass concentrations of BTEX (benzene, toluene, ethylbenzene and xylene) were (19.27±14.46) μg·m^-3, accounting for 41.09%-95.16% of the mass concentrations of benzene homologues. The mass concentrations of benzene homologues were relatively higher at night than that in the daytime, and the diurnal variation was “V-shaped” with the lowest value being occurred at 13:00-15:00. The ozone formation potential (OFP) of the 16 benzene homologues were in the range of 66.62-170.67 μg·m^-3, and the values of OFP for m/p-xylene, toluene and o-xylene were relatively higher; whereas, the secondary organic aerosol formation potential (SOAFP) of the 16 benzene homologues were in the range of 0.71-1.86 μg·m^-3, and the values of SOAFP for toluene, m/p-xylene and ethylbenzene were relatively higher. Hazard index (HI) of BTEX and styrene changed from 8.19E-03 to 5.01E-02, which suggested that there was no non-cancer risk from such toxic compounds to the exposed population in the study area in four seasons. On the other hand, carcinogenic risk (Risk) of benzene ranged from 7.13E-08 to 8.13E-06, indicating that there was a potential cancer risk from benzene to the exposed population in the three seasons of summer, autumn and winter. Source analytical results showed that benzene homologues were mainly from vehicle emission source in spring and autumn, and they were also affected by solvent usage in spring; while the main source of benzene homologues was coal combustion in summer and winter.
Key words:benzene homologues in the ambient air/
pollution level/
human health risk/
source apportionment/
Beijing.