1. 北京科技大学能源与环境工程学院，北京 100083； 2. 中国科学院工程热物理研究所，北京 100190
收稿日期:2017-09-12修回日期:2017-10-31出版日期:2018-06-22发布日期:2018-06-06通讯作者:李石琨基金资助:国家重点研发计划资助项目；国家自然科学基金资助项目Dehydrogenation Performance and Reaction Kinetics of Isopropanol in Liquid Film Reactor
Shikun LI1, Min XU2*, Jun CAI2, Xianfang YUE1*, Xiulan HUAI21. School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China;2. Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beijing 100190, China
Received:2017-09-12Revised:2017-10-31Online:2018-06-22Published:2018-06-06摘要/Abstract
摘要： 研究了反应物进料速度、催化剂用量和反应温度对以非晶态合金雷尼镍为催化剂的液膜多相反应模式下异丙醇脱氢反应的影响，考察了反应动力学. 结果表明，温度的影响最显著，与搅拌釜液相脱氢相比，该反应模式有效提升了产氢速率，Langmuir?Hinshelwood反应动力学表达式计算结果与实验结果吻合良好.
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李石琨 许闽 蔡军 岳献芳 淮秀兰. 液膜反应器中异丙醇脱氢性能及反应动力学[J]. 过程工程学报, 2018, 18(3): 652-656.
Shikun LI Min XU Jun CAI Xianfang YUE Xiulan HUAI. Dehydrogenation Performance and Reaction Kinetics of Isopropanol in Liquid Film Reactor[J]. Chin. J. Process Eng., 2018, 18(3): 652-656.
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参考文献
| [1] Ajah A N, Mesbah A, Grievink J, et al. On the robustness, effectiveness and reliability of chemical and mechanical heat pumps for low-temperature heat source district heating: a comparative simulation-based analysis and evaluation[J]. Energy, 2008, 33(6): 908-929. [2] Kitikiatsophon W, Piumsomboon P. Dynamic simulation and control of an isopropanol–acetone–hydrogen chemical heat pump[J]. Science Asia, 2004, 30(1): 135-147. [3] Ajah A N, Mesbah A, Grievink J, et al. On the robustness, effectiveness and reliability of chemical and mechanical heat pumps for low-temperature heat source district heating: a comparative simulation-based analysis and evaluation[J]. Energy, 2008, 33(6): 908-929. [4] Kim T G, Yeo Y K, Song H K. Chemical heat pump based on dehydrogenation and hydrogenation of i‐propanol and acetone[J]. International Journal of Energy Research, 1992, 16(9): 897-916. [5] Briggs R A, Taylor H S. The dehydrogenation of normal heptane and cyclohexane on cerium, vanadium and thorium oxide catalysts[J]. Journal of the American Chemical Society, 1941, 63(9): 2500-2503. [6] Saito Y, Aramaki K, Hodoshima S, et al. Efficient hydrogen generation from organic chemical hydrides by using catalytic reactor on the basis of superheated liquid-film concept[J]. Chemical Engineering Science, 2008, 63(20): 4935-4941. [7] Xin F, Xu M, Li X F, et al. Experimental study of isopropanol dehydrogenation over amorphous alloy raney nickel catalysts[J]. Journal of Thermal Science, 2013, 22(6): 613-618. [8] Zhang L, Xu G, An Y, et al. Dehydrogenation of methyl-cyclohexane under multiphase reaction conditions[J]. International Journal of Hydrogen Energy, 2006, 31(15):2250-2255. [9] Kariya N, Fukuoka A, Ichikawa M. Efficient evolution of hydrogen from liquid cycloalkanes over Pt-containing catalysts supported on active carbons under “wet–dry multiphase conditions”[J]. Applied Catalysis A: General, 2002, 233(1): 91-102. [10] Sakurai M, Honda H, Kameyama H. Fundamental study of a non-steady operation for 2-propanol de-hydrogenation[J]. International journal of hydrogen energy, 2007, 32(9): 1303-1308. [11] Shukla A A, Gosavi P V, Pande J V, et al. Efficient hydrogen supply through catalytic dehydrogenation of methylcyclohexane over Pt/metal oxide catalysts[J]. international journal of hydrogen energy, 2010, 35(9): 4020-4026. [12] Ping H, Xu G, Wu S. System optimization of cyclohexane dehydrogenation under multiphase reaction conditions using the uniform design method[J]. international journal of hydrogen energy, 2015, 40(46): 15923-15932. [13] Zhang L, Xu G, An Y, et al. Dehydrogenation of methyl-cyclohexane under multiphase reaction conditions[J]. International journal of hydrogen energy, 2006, 31(15): 2250-2255. [14] Kou Z, Zhi Z, Xu G, et al. Investigation of the performance and deactivation behavior of Raney-Ni catalyst in continuous dehydrogenation of cyclohexane under multiphase reaction conditions[J]. Applied Catalysis A: General, 2013, 467(10): 196-201. [15] Hao L, Zhen S, Tan D, et al. Preparation of novel Raney-Ni catalysts and characterization by XRD, SEM and XPS[J]. Applied Catalysis A General, 2001, 214(1):69-76. [16] Mooksuwan W, Kumar S. Study on 2-propanol/acetone/hydrogen chemical heat pump: endothermic dehydrogenation of 2-propanol[J]. International journal of energy research, 2000, 24(12): 1109-1122. [17] Xu M, Xin F, Li X, et al. Equilibrium model and performances of an isopropanol–acetone–hydrogen chemical heat pump with a reactive distillation column[J]. Industrial & Engineering Chemistry Research, 2013, 52(11): 4040-4048. [18] Sakurai M, Honda H, Kameyama H. Fundamental study of a non-steady operation for 2-propanol de-hydrogenation[J]. International journal of hydrogen energy, 2007, 32(9): 1303-1308. [19] Kariya N, Fukuoka A, Ichikawa M. Efficient evolution of hydrogen from liquid cycloalkanes over Pt-containing catalysts supported on active carbons under “wet–dry multiphase conditions”[J]. Applied Catalysis A: General, 2002, 233(1): 91-102. [20] Kariya N, Fukuoka A, Utagawa T, et al. Efficient hydrogen production using cyclohexane and decalin by pulse-spray mode reactor with Pt catalysts[J]. Applied Catalysis A: General, 2003, 247(2): 247-259. |
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