基本信息
徐立男博导中国科学院福建物质结构研究所
电子邮件： xli@fjirsm.ac.cn
通信地址： 福州市鼓楼区杨桥西路155号
邮政编码： 350002

研究领域

招生信息
招生专业070301-无机化学
070303-有机化学
070304-物理化学

招生方向团簇的分子与晶体工程
新型有机化合物的设计及其金属功能材料的构筑
Zintl化学


教育背景1990-01--1993-02中科院福建物质结构研究所博士学位

学历
学位

工作经历
工作简历2003-06~现在,中科院福建物质结构研究所,研究员
2002-05~2003-06,加拿大ALBERTA大学,博士后
2000-12~2002-05,美国RICE大学,研究科学家
1998-12~2000-12,美国NOTRE DAME大学,博士后
1997-07~1998-12,日本北海道大学理学院,日本学术振兴会外国人特别研究员
1994-04~1997-07,福建物质结构研究所,副研究员
1993-02~1994-04,中科院福建物质结构研究所,助理研究员
1990-01~1993-02,中科院福建物质结构研究所,博士学位

社会兼职

教授课程

专利与奖励
奖励信息
专利成果

出版信息
发表论文（1）[A3X][Ga3PS8] (A = K, Rb; X = Cl, Br): promising IR non-linear optical materials exhibiting concurrently strong second-harmonic generation and high laser induced damage thresholds,Chemical Science,2106,第11作者
（2）Unprecedented [MoIV3O4]-incorporated Polyoxometalate Concomitant with MoO2 ,ChemCommun,2103,第11作者
（3）Unprecedented 3-D SHG MOF Material of Silver (I) Induced by Chiral Triple R-helices,ChemCommun,2103,第11作者
（4）Unprecedented Nanocage-like and Heterometallic [Mo3O4]-Polyoxomolybdate Hybrid,Dalton Transaction,2018,第11作者
（5）Sb102? and Sb22? found in [K(18-crown-6)]6[Sb10] [Sb4{Mo(CO)3}2]?2en: two missing family members,Dalton Transaction,2017,第11作者
（6）[Ge9{M(CO)5}3]4?: electrophilic addition of M(CO)5 and [E9]4? Zintl anions (M = Cr, Mo, W),Dalton Transaction,2017,第11作者
（7）Counterion-induced Crystallization of Intermetalloid Matryoshka Clusters [Sb@Pd12@Sb20]3-,4-,Dalton Transaction,2017,第11作者
（8）[A3X][Ga3PS8] (A = K, Rb; X = Cl, Br): promising IR non-linear optical materials exhibiting concurrently strong second-harmonic generation and high laser induced damage thresholds,Chemical Science,2016,第11作者
（9）An All-Metal Aromatic Sandwich Complex [Sb3Au3Sb3]3?,J. Am. Chem . Soc,2015,第12作者
（10）Isolated [Cd2Sb5]11- Butterfly Zintl Anion Built of Unprecedented Planar [CdSb3] Triangle,Dalton Transaction,2015,第11作者
（11） [Ge8(Mo(CO)3)2]4？：Unprecedented 20？Electron Empty Ten？vertex Zintl Cluster,ChemCommun,2014,第11作者
（12）Unprecedented Dawson Isomerism Induced by Central [WO5] and Four 45？-rotated Belt ,ChemCommun,2012,第11作者
（13）Countercation-directed chiral resolution of [Mo2O4(H2dtpa)]-, syntheses, crystal structures and CD spectra of (λ)-[NEt4][Mo2O4(H2dtpa)] and (δ)-Na[Mo2O4(H2dtpa)],CrystEngCommun,2012,第11作者
（14）Solvothermal Treatment of Triangular Molybdenum (IV) Oxo Species, A Novel Approach for the Synthesis of New Molybdenum Oxo Clusters,Eur. J. Inorg. Chem,2011,第11作者
（15）Synthesis and Crystal of [K(2,2,2-crypt)]3Sb11 ,Chinese J. Struc. Chem.,2011,第11作者
（16）Synthesis and Crystal Structure of a New mixed-ligands Iron Complex with Cylic Water Hexamers [Fe(HCDTA).H2O].Fe(1,10-phen)3.10H2O.2OH-,Chinese J. Struc. Chem.,2011,第11作者
（17）Bis[(1,10-diaza-4,7,13,16,21,24-hexaoxabicyclo[8.8.8] hexacosane)potassium(+)],Acta. Cryst. Sect C. ,2011,第11作者
（18）Construction of a series of 1D and 2D inorganic-organic hybrid coordination polymers based on 1, 1’-di(propionic acid)-2, 2’-biimidazole,Eur. J. Inorg. Chem ,2010,第11作者
（19）Helix-based Supramolecular Isomerism of Metal-organic Framework,CrystEngComm,2010,第11作者
（20）Reversible formation of Regular Pentagonal Dodecahedral (H2O)20 in a 2D Metal-Organic Framework,CrystEngComm ,2010,第11作者
（21）Lanthanide (III) addition of [Mo2O3S(HNTA)2]2- (Ln = Eu, Dy),J. Solid State Chem.,2009,第11作者
（22）Supramolecular architectures built of triangular molybdenum(IV) heterometallic clusters encapsulating novel water clusters,Inorg. Chim. Acta,2009,第11作者
（23） pH-Dependent Displacement of [Bi(citrate)]- with Cysteine: Synthesis, Spectroscopic and X-ray Crystallographic Characterization of Bi(cysteine)3.,J. Inorg. Biochem.,2008,第11作者
（24）Syntheses and optical property of two novel chlorobithmuthate(III) complexes:[8-hydroxyquinnolinium]4-K2[BiCl6]2 and [8-hydroxyquinnolinium]6-[Bi2Cl10][Bi(H2O)Cl5],J. Mol. Struc.,2008,第11作者
（25）Unprecedented 2-D Hydrated Proton Encapsulated in Supramolecular Framework Built of [Mo3O4(C2O4)(H2O)3]2-,Inorg. Chem. Comm.,2008,第11作者
（26）Two Novel Luminescent Silver(I) Coordination Polymers Containing Octanuclear Silver Cluster Units or Ligand unsupported Ag？？？Ag Interactions Constructed from 5-sulfoisophic acid (H3SIP) and Organic Amine,CrystEngComm. ,2008,第11作者
（27）Unprecedented Helix-based Microporous Metal-Organic Frameworks Constructed from Single Ligand,Chem. Commun.,2008,第11作者
（28）Syntheses, Structures and Photoluminescence of Two 3D- pillared Metal-organic Framework with unique (411？64)(410？65) topology based on two kinds of topologically nonequivalent nodes,Inorg. Chem. Comm.,2008,第11作者
（29）Remarkable Structural Transformation of [Zn(tza)2] During recrystallization, Syntheses and Crystal Structures of [M(tza)2] (M = Zn, Cd, Mn, Co; Htza = Tetrazole-1-acetic Acid ),Crystal Growth and Design,2008,第11作者
（30）Syntheses, crystal structure and properties of two novel coordinationpolymers with the flexible tetrazole-1-acetic acid (Htza),J. Solid. Chem. Chem.,2008,第11作者
（31）Protonated N-Heterocycle-templated Supramolecular Frameworks Built of Triangular Molybdenum(IV) Clusters.,Inorg. Chim. Acta,2008,第11作者
（32）Syntheses,Crystal Structures, and Magnetic Properties of Copper(II) and Manganese(II) Compounds Constructed from 5-Sulfoisophthalic Acid (H3SIP) and 2,2’-Bipydine(bpy) Ligands.,Eur. J. Inorg. Chem.,2008,第11作者
（33）Diversity of Coordination Architecture of Copper(II)-5-Sulfoisophthalic Acid: Synthesis, Crystal Structures and Characterizations.,Cryst Growth and Design,2007,第11作者
（34）Layered Lanthanide Molybdate Pillared by Chiral [l-Mo2O4EDTA]2-,Inorg. Chem.,2006,第11作者
（35） Syntheses, crystal structures and properties of [K(2,2,2-crypt)]3K(HP7)2.en, [K(18-crown-6)]2HP7 and [K(db18-crown-6)]2HP7.toluene,Inorg. Chim. Acta ,2006,第11作者
（36）Counter-anion Induced Formation of cis and trans Singly and Doubly H2biim-bridged Di-, Hexa- and Polymeric Ag-H2biim Complexes.,Eur. J. Inorg. Chem.,2006,第11作者
（37）Syntheses, Crystal Structrues and Photophysical Properties of Two Novel Lead(II)-SIP (NaH2SIP = 5-Sulfoisophthalic Acid Monosodium Salt) Coordination Polymers Containing Tetranuclear Lead(II) Units,Eur. J. Inorg. Chem.,2006,第11作者
（38）Synthesis, Crystal Structures and Photoluminescent Properties of Three Novel Cadmium(II) Compounds Constructed from 5-Sulfoisophthalic Acid (H3SIP),Eur. J. Inorg. Chem.,2006,第11作者
（39）Supramolecular Architecture Built of Biimidazole Complexes and Sulfate or Nitrate Anions,Polyhedron,2006,第11作者
（40）The First Lanthanide(III)-Iminodiacetate Coordination Polymer,Inorg. Chem. Comm.,2006,第11作者
（41）Supramolecular Architectures of Cadmium(II) Built of 2,2-Bimmidazole and Bifunctional Carboxylates: Syntheses, Crystal Structure and Properties,Inorg. Chim. Acta,2006,第11作者
（42）Unprecedented Quadruple-Me2biim Bridged Di- and Tetra-nuclear Complexes, Syntheses, Crystal Structures and Magnetic Properties,Inorg. Chim. Acta,2006,第11作者
（43）Novel Structure Evolution From 1D Chain to 3D Network of Lanthanide-SIP Coordination Polymers as a Consequence of Lanthanide Contraction Effect,Euro. J. Inorg. Chem.,2005,第11作者
（44）A Series of Single, Double, and Triple Me2biim-Bridged Dinuclear, Trinuclear, and Polymeric Complexes: Syntheses, Crystal Structures, and Luminescent Properties,Inorg. Chem.,,2005,第11作者
（45）Synthesis, Crystal Structures and Photophysical Properties of Two Supramolecular Complexes of Cd(II),Inorg. Chem. Comm.,2005,第11作者
（46）(H2O)12-Containing Infinite Chains Encapsulated in Supramolecular Open Framework Structures , CrystEngComm,2005,第11作者
（47）Hybrid Metal Carbonyl-Oxo Clusters, Synthesis and Characterization of,organometallics,2002,第1作者
（48） Stablization of Ozone-like [Bi3]3- in the Heteroatomic closo-Clusters [Bi3Cr2(CO)6]3- and ,J. Am. Chem. Soc.,2001,第1作者
（49）Heteroatomic Deltahedral Clusters of Main Group Elements, Syntheses and Structures of ,Inorg. Chem,2000,第1作者
（50）A Naked Diatomic Molecule of Bismuth, [Bi2]2-, with a Short Bi-Bi Bond: Synthesis and ,J. Am. Chem. Soc.,2000,第1作者
（51）Oxidative Coupling of Deltahedral [Ge9]4- Zintl Ions,J. Am. Chem. Soc.,1999,第1作者

发表著作

科研活动
科研项目（ 1 ） ZINTL团簇的合成，结构与反应性, 主持,国家级,2011-01--2013-12
（ 2 ） 新型半导体团簇的制备及结构性质研究, 主持,国家级,2011-01--2014-12
（ 3 ） 功能导向多孔配合物晶体工程, 参与,国家级,2010-01--2013-12
（ 4 ） Zintl团簇化学：合成，结构与反应性, 主持,国家级,2015-01--2018-12

参与会议

合作情况
项目协作单位

指导学生