基本信息



黄辉 男 博导 材料科学与光电技术学院
课题组网站
电子邮件：huihuang@ucas.ac.cn
通信地址：北京市石景山区玉泉路19号
邮政编码：100049





部门/实验室：材料科学与光电技术学院
研究领域


详见课题组网站
1. Novel synthetic methodologies for organic/polymeric semiconducting materials
a.Develop new catalysts for C-C bond formation
b. Discover new routes for C-C bond formation

2. Low dimension materials (organic conjugated materials, inorganictwo dimensional materials etc) forenergy,biology, and environmentalapplication
a.Develop novel low dimension materialsfor energy, biology, and environmental application
b. Understand fundamental theories in solid state materials and devices








招生信息招收化学、材料类，博士后，博士与硕士生；欢迎报名

教育背景 2003-08--2008-08 美国达特茅斯学院 博士
2000-09--2003-07 中国科学院化学研究所 硕士
1996-09--2000-07 北京师范大学 学士


工作经历2010年10月-2013年10月，研究科学家，康菲石油公司（菲利普斯66石油公司）全球研发中心，Bartlesville, OK, USA
2008年10月-2010年9月，博士后（合作导师：Tobin J. Marks)，美国西北大学，Evanston, IL, UAS


教授课程有机半导体材料
有机半导体材料及器件的最新进展
中丹太阳能主题周系列讲座


专利与奖励


专利
1. Marks, T. J.; Facchetti, A.; Huang, H.; Chen, Z.; Alkoxylethane Semiconducting Compounds and Device Incorporating Same, US **.
2. Wang, S.; Shi, C.; Chen, R.; Zhang, J.; Wang, W.; Wu, Y.; Huang, H.; Palkar, A.; He, T. Synthesis Photovoltaic Conjugated Polymers, US 61/599419.
3. Huang, H. Process of Novel Donor Building Blocks for Organic Solar Cells, US **.
4. Huang, H. Structure of Novel Donor Building Blocks for Organic Solar Cells, US **.
5. Wang, W.: Shi, C.; Chen, R.; Yang, J.; Wu, Y.; Huang, H.; Woody, K.; Bullock, J.; Palkar, A.; He, T. Furan and Selenophene Derivatized Benzo[1,2-b:4,5-b’] Dithiophene-thienothiophene Based Conjugated Polymers For High-efficiency Organic Solar Cells, P66-00003, filed.
6. Woody, K.; Bullock, J.; Huang, H.; Palkar, A.; He, T.; Shi, C.; Chen, R.; Yang, J.; Daeffler, C.; Hawkins, J.; Wu, Y.; Wang, W. Anthracene Dithiophene Based Semiconducting Polymer for Photovoltaic Application. P66-00065, filed.
7. Shi, C.; Chen, R.; Yang, J.; Daeffler, C.; Hawkins, J.; Wu, Y.; Wang, W.; Woody, K.; Bullock, J.; Huang, H.; Palkar, A.; He, T.; Difluorothienothiophene Based Conjugated Polymer and Their Applications as Organic Semiconductors in Photovoltaic Cells, P66-00113
8. Huang, H.; Woody, K.; He, T.; et al, Compsitionand Synthesis of Benzo[1,2-b:4,5-b]Dithiophene-thienothiophene Randomly Substituted Conjugated PolymersFor Organic Solar Cells, P66-00121
9. Woody, K.; Huang, H.; He, T.; et al, Application of Benzo[1,2-b:4,5-b]Dithiophene-thienothiophene Randomly Substituted Conjugated Polymers For Organic Solar Cells, P66-00121
奖励
中科院前沿研究-青年拔尖人才， 2017
Emergying Investigator, JMCA, 2017
康菲石油公司Leadership Award

相关研究成果被美国主流媒体CNBC，Yahoo和学术媒体Phys.Org等和中国中央人民政府网和科教网等媒体广泛报道。
















出版信息







代表作：
一、合成方法学领域

1.Zhu, T.;Jiang, L.; Li, Y.; Xie, Z.; Li, Z.; Lv, L.; Chen, H.; Zhao, Z.; Jiang, L.; Tang, B.; Huang H.* Converting Thioether Waste into Organic Semiconductors by Carbon--Sulfur Bond Activation, Angewandte Chemie International Edition, 2019, 58, 5044-5048.
2. Jiang, X.; Huang, H.;*Chai, Y.; Lohr, T.;Yu, S.-Y.;*Lai, W.*; Pan, Y.;* Delferro, M.;* Marks, T. J.* Hydrolytic Cleavage of Both CS2 Carbon-Sulfur Bonds by Multinuclear Pd(II) Complexes at Room Temperature, Nature Chemistry, 2017, 9, 188-193.


二、有机/高分子半导体
1.Wu, J.; Xu, Y.; Yang, Z.; Chen, Y.; Sui, X.; Yang, L.; Ye, P.; Zhu, T.; Wu, X.; Liu, X.; Cao, H.; Peng, A.; Huang, H.* Simultaneous Enhancement of Three Parameters of P3HT-based Organic Solar Cells with One Oxygen Atom, Advanced Energy Materials, 2019, 9, **.
2. Yang, L.; Gu, W.;Lv, L.;Chen, Y.;Ye, P.;Wu, J.;Hong, L.;Peng, A.;Huang, H.* Triplet Tellurophene-based Acceptors for Organic Solar Cells, Angewandte Chemie International Edition, 2018, 57, 1096-1102.
3. Dong, T.;Wen, K.;Chen, J.;Xie, J.;Fan, W.;Ma, H.;Yang, L.;Wu, X.;Xu, F.;Peng, A.; Huang, H.* Significant Enhancement of Photothermal and Photoacoustic Efficencies for Conjugated Polymer Nanoparticles through Simply Molecular Engineering, Advanced Functional Materials, 2018, 28, **.
4. Huang, H.*; Yang, L.; Facchetti, A.*; Marks, T. J.* Organic and Polymeric Semiconductors with Noncovalent Conformational Locks, Chemical Reviews,2017, 117, 10291–10318.
5. Dong, T.;Lv, L.; Feng, L.; Deng, W.; Ye, P.; Yang, B.; Facchetti, A.;* Dong, H.*; Huang, H.* Noncovalent Se^…O Conformational Locks for Constructing High Performing Opto-electronic Conjugated Polymers, Advanced Materials, 2017, 29, **.

6. Chen, Y.; Ye, P.; Zhu, Z.; Wang, X.; Yang, L.; Xu, X.; Wu, X.; Dong, T.; Zhang, H.; Hou, J.; Liu, F.;* Huang, H.* Achieving High-Performance Ternary Organic Solar Cells Through Tuning Acceptor Alloy, Advanced Materials,2017, .
7. Wang, X.; Lv, L.; Li, L.; Chen, Y.; Zhang, K.; Chen, H.; Shen, G.;*Huang, J.;* Yang, Z.;* Huang, H.* High-PerformanceAll PolymerPhotoresponse DevicesBased on Novel A-A ConjugatedPolymers, Advanced Functional Materials, 2016, 26, 6306-6315.


Before UCAS
1.Zhou, N.; Lin, H.; Lou, S.; Yu, X.; Guo, P. Loser, S.; Hartnett, P.; Huang, H.; Wasielewski, M. R.; Chen, L. X.; Chang, R. P. H.; Facchetti, A.; Marks, T. J. Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells, Advanced Energy Materials, 2014, 4, **/1-**/8.
2. Youn, J.; Kewalramani, S.; Emery, J.; Shi, Y.; Zhang, S.; Chang, H.-C.; Liang, Y.-j.; Yeh, C.-M.; Feng, C.-Y.; Huang, H.; Stern, C.; Chen, L.-H.; Chen, M.-C.; Bedzyk, M.; Facchetti, A.*; Marks, T. J.*. Fused Thiophene Semiconductors: Crystal Structure-Film Microstructure-Transistor Performance Correlations, Advanced Functional Materials, 2013, 23, 3850-3865.
3. Youn, J.; Dholakia, G.R.; Huang, H.; Facchetti, A.*; Marks, T. J.* Influence of Thiol Treatment on Bottom Contact Field Effect Transistor based on n-Type Organic Semiconductor, Advanced Functional Materials, 2012, 1, 1856-1869.
4. Huang, H.; Chen, Z.; Ponce Ortiz, R.; Youn, J.; Newman, C.; Facchetti, A.*; Marks, T. J.* A Thienyl-vinylene Building Block with Intramolecular Locks for High Mobility and Ambient Stable Polymeric Semiconductors. Journal of the American Chemical Society, 2012, 134, 10966-10973.
5. Usta, H.; Kim C.; Wang, Z.; Lu, S.; Huang, H.; Facchetti A.*; Marks, T. J.* Anthracenedicarboximide-based semiconductors for air-stable, n-channel organic thin-film transistors: materials design, synthesis, and structural characterization. J. Mate. Chem. 2012, 22, 4459-4472.
6. Youn, J., Huang, P.-Y.; Huang, Y.-W.; Chen, M.-C.; Lin, Y.-J.; Huang, H.; Ponce Ortiz, R.; Stern, C.; Chung, M.-C.; Feng, C.-Y.; Chen, L.-H.; Facchetti, A.*; Marks, T.J.* Versatile α,ω-Disubstituted Tetrathienoacene Semiconductors for High Performance Organic Thin-Film Transistors, Advanced Functional Materials, 2012, 1, 48-60.
7. Huang, H.; Youn, J.; Ponce Ortiz, R.; Zheng, Y.; Facchetti, A.*; Marks, T. J.* Very Large Silacylic Substituent Effects on Response in Silole-Based Polymer Transistors. Chemistry of Materials, 2011, 23, 2185-2200.
8. Huang, H.; Hughes, R. P.*; Rheingold, A. L. Synthesis and Structural Characterization of Group 6 Transition Metal Complexes with Terminal Fluoromethylidyne (CF) Ligands; a DFT/NBO/NRT Comparison of Bonding Characteristics of Terminal NO, CF and CH Ligands. Dalton Transaction, 2010, 40, 47-55.
9. Youn, J.; Chen, M.*; Liang, Y.; Huang, H.; Ponce Ortiz, R.; Kim, C.; Stern, C.; Hu, T.; Chen, L.; Yan, J.; Facchetti, A.*; Marks, T.* Novel Semiconductors Based on Functionalized Benzo[d,d′]thieno[3,2-b;4,5-b′]dithiophenes (BTDTs) and the Effects of Thin Film Growth Conditions on Organic Field Effect Transistor Performance, Chemistry of Materials, 2010, 22, 5031-5041.
10. Huang, H.; Rheingold, A. L.; Hughes, R. P.* Synthesis and X-ray Structure of a Diamagnetic Oxo-Bridged Trifluoromethyl-Chromium(V) Complex: Structural and Computational Comparisons between CF3 and CH3 Ligands in Two Different Oxidation States of Chromium. Organometallics, 2010, 29, 3672-3675.
11. Ponce Ortiz, R.; Blanco, R.; Herrera, H.; Huang, H.; Facchetti, A.*; Marks, T. J.*; Zheng, Y.; Segura, J. L.* Organic n-Channel Field Effect Transistors Based on Arylenedimide-thiophene Derivatives, Journal of the American Chemical Society, 2010, 132, 8440–8452.
12. Huang, H.; Hughes, R. P.*; Rheingold, A. L. Synthesis and Structural Characterization of New Perfluoroacyl and Perfluoroalkyl Group 6 Transition Metal Compounds. Organometallics, 2010, 29, 1948-1955.
13. Kim, C.; Chen, M.-C.*; Chiang, Y.-J.; Guo, Y.-J.; Youn, J.; Huang, H.; Liang, Y.-J.; Lin, Y.-J.; Huang, Y.-W.; b, Hub, T.-S.; Lee, G-H.; Facchetti, A.*; Marks, T. J.* Functionalized Dithieno[2,3-b:30,20-d]thiophenes (DTTs) for Organic Thin-film Transistors, Organic Electronics, 2010, 11, 801-813.
14. Bagnis, D.; Beverina, L.; Huang, H.; Silvestri, F.; Zheng, Y.; Pagani, G.A.; Marks, T.J.*; Facchetti, A.* Alkenyl vs. Alkyl Substituent Effects in Squaraine-Based Bulk Heterojunction Solar Cells, Journal of the American Chemical Society, 2010, 132, 4074-4075.
15. Usta, H.; Risko, C.; Wang, Z.; Huang, H.; Deliomeroglu, M. K.; Zhukhovitskiy, A.; Facchetti, A.*; Marks, T. J.* Design, Synthesis, and Characterization of Ladder-Type Molecules and Polymers. Air-Stable, Solution-Processable n-Channel Semiconductors for Thin-Film Transistors via Experiment and Theory. Journal of the American Chemical Society, 2009, 131, 5586-5608.
16. Huang, H.; Hughes, R. P.*; Rheingold, A. L. Serendipitous Discovery of a Simple Compound with an Unsupported Ir-Ir Bond. Organometallics, 2009, 28, 1575-1578.
17. Huang, H.; Hughes, R. P.*; Rheingold, A. L. Octahedral Perfluoroalkyl Complexes of Ir(III) Formed by Oxidative Addition of Perfluoroalkyl Iodides to Ir(acac)(CO)2. Canadian Journal of Chemistry, 2009, 87, 151-160.
18. Huang, H.; Hughes, R. P.*; Rheingold, A. L. Synthesis and Structural Characterization of a Coordinatively Unsaturated Ruthenium Complex, Cp*Ru(Ph2nacnac), and its CO Adduct. Polyhedron, 2008, 27, 734-738.
19. Bourgeois, C. J.; Huang, H. (Prime Author); Laritchev, R.; Zakharov, L. N.; Rheingold, A. L. Hughes, R. P.* Variable-Temperature NMR Determination of the Barriers to Rotation about the Ir-C σ-Bond in a Series of Primary Perfluoroalkyl Iridium Complexes [IrCp*{(CF2)nCF3}(PMe3)2]+X- [n = 1, 2, 3, 5, 7, 9, 11; X = I, OTf]. Organometallics, 2007, 26, 264-271.
20. Huang, H.; Hughes, R. P.*; Landis, C. R.; Rheingold, A. L. The Simplest Binary Fluorocarbon as a Ligand. Synthetic, Spectroscopic, Crystallographic, and Computational Studies of a Molybdenum Complex of Terminally Ligated Carbon Monofluoride (Fluoromethylidyne). Journal of the American Chemical Society, 2006, 128, 7454-7455.
21. Yu, S.-Y.*; Li, S.-Y.; Huang, H.-P.; Zhang, Z.-X.; Jiao, Q.; Huang, H. Molecular Self-Assembly with Modularization and Directionality: Vector-Manipulation at Metal Centers, Current Organic Chemistry, 2005, 9, 555-563.
22. Li, S.-H.; Huang, H.-P.; Yu, S.-Y.*; Li, Y.; Huang, H.; Sei Y.; Yamaguchi, K. Self-assembly of Coordination Molecular Baskets as Inorganic Analogues of Cyclotriveratrylenes (CTV). Dalton Transactions, 2005, 2346-2348.
23. Huang, H.; Yu, S.-Y.*; Liu, H.-B.; Shi, M. Neutral Coordination Frameworks with Host-guest Properties Constructed by Dicopper(II) Units and 4,7- Phenanthroline. Polyhedron, 2004, 23, 55-58.
24. Yu, S.-Y.*; Huang, H.-P; Li S.-H.; Zhang Z.-X.; Meng, T.; Jiao, Q.; Li, H.; Huang, H. Molecular Nanotechnology and Organometallic Molecular Nanosystems, Polymer Bulletin (China), 2004, 2, 6-22.
25. Zhang, Z.-X.; Huang, H.; Yu, S.-Y.* Synthesis and Structure of a Dipyrazol-bridged Macrocyclic Palladium (II) Complex Wuji Huaxue Xuebao, 2004, 7, 849-852.
26. Yu, S.-Y.*; Huang, H.(prime author); Liu, H.-B.; Chen, Z.-N.; Zhang, R.-B.; Fujita, M. Modular Cavity-tunable Self-assembly of Molecular Bowls and Crowns as Structural Analogues of Calix[3]arenes. Angewandte Chemie International Edition, 2003, 42, 686-690.
27. Liu, H.-B.; Yu, S.-Y.* Huang, H.; Zhang, Z-X. Enclathrating benzene in a neutral dicopper(II) coordination framework, Australian Journal of Chemistry, 2003, 56, 671-674.
28. Huang, H.; Jin, Q.-H.; Yu, S.-Y.*; Ma, H.-W.; Li, S.-H.; Huang, H.-P.; Yu, K.-B. Crystal Structure of Catena-poly{[tetra[m-(benzoato-O,O’)]dicopper(II)]-m-2-N,N’-(4,4’’-bi-3,5-dimethylpyrazolate)} hydrate, [Cu2(O2CC6H5)4(C10N4H14)]F9?H2O, Zeitschrift fuer Kristallographie - New Crystal Structures, 2003, 218, 443-444.
29. Huang, H.; Yu, S.-Y.* Synthesis and Crystal Struture of [Cis-1, 10-phenanthroline-palladium (II)(THF)2]dinitrate (THF = tetrahydrofuran), Chinese Journal of Structural Chemistry, 2003, 22, 547-549.









































































































































































































































































































































































































































































































































科研活动学术活动：
1. 入选中科院****2. 担任InfoMater(Wiley)期刊编委
3. 担任美国MRS会议太阳能电池分会主席
4. 国际著名期刊特邀审稿人（Adv. Mater., Adv. Sci., Chem. Mater., Macromolecules等）

科研经费：
1. 引进人才启动经费，主持，（2014-2017）
2. 国家自然科学基金青年基金，主持，（2014-2016）
3. 国家自然科学基金面上基金，主持，（2016-2017）
4. 北京市自然科学基金面上基金，主持，（2016-2018）
5. 航天科技创新基金，共同主持，（2016-2017）
6. 军委装备部国防知识产权基金，主持，2017
7. 国家自然科学基金面上基金，主持，（2018-2021）
8. 中国科学院国际合作重点项目，主持，（2018-2020)
9. 中国科学院前沿研究重点项目，主持，（2017-2021）
10. 中国科学院先导培育项目，参与，2018

会议报告：
1. The 11th International Symposium on Polymer Physics (June, 2014), Nanjing, China, Oral Talk
2. The 6th International Symposium of Polymer Chemistry (June, 2014), Shanghai, China, Invited Talk
3. 第十四届国际光伏大会，北京，中国；2014年11月，分会报告
4. 北京工业大学工程大师论坛，2014年，邀请报告
5. 第三届化学与材料金砖论坛，2014年12月，邀请报告







合作情况
项目协作单位Northwestern University, Texas A&M University, University of Nebraska Lincoln, Institute of Chemistry, CAS.