多稳态功能材料课题组
陶 军，教授、杰青、博士生导师地址：北京市房山区良乡东路8号
北京理工大学良乡校区 化学与化工学院邮箱：taojun@bit.edu.cn
课题组网站：www.tao-lab.cn
团队招聘：欢迎优秀博士毕业生加盟本团队从事博士后研究，同时招聘国家高层次青年人才、准聘教授、特立学者、预聘副教授、预聘助理教授等高层次人才！具有配位化学、结构化学、分子磁学、催化化学背景的优先考虑。
个人简历：
安徽大学学士 (1991)、中山大学硕士 (1997)、中山大学博士 (2001)
日本神奈川科学技術アカデミー和九州大学JSPS博士后 (2004-2006)
教育部新世纪优秀人才 (2008)
福建省杰出青年基金获得者 (2009)
国家自然科学基金委杰出青年基金获得者 (2013)
福建省高校领军人才 (2014)
福建省科技创新领军人才 (2014)
厦门大学特聘教授 (2014)
北京理工大学特聘教授 (2016)
研究兴趣：
多稳态分子材料的设计合成与性能调控
多稳态分子材料的功能耦合
柔性分子基晶体功能材料的设计与开发
配位聚合物的可控组装与性质研究
代表论文：
Homochiral versus racemic polymorphs of spin-crossover iron(II) complexes with reversible LIESST effect, Ting-Ting Ma, Xiao-Peng Sun, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. Front. 2020, 7(5), 1196-1204.
Bistable molecular materials with dynamic structures (Feature Article), Zi-Shuo Yao,* Zheng Tang, Jun Tao,* Chem. Commun. 2020, 56(14), 2071-2086.
Switchable on–off spin-crossover properties of iron(II) compounds by trimming intermolecular hydrogen bonds, Na Li, Jin-Peng Xue, Jing-Lin Liu, Yao-Yao Wang, Zi-Shuo Yao,* Jun Tao,* Dalton Trans. 2020, 49(4), 998-1001.
A homochiral 3D framework of mechanically interlocked 1D loops with solvent-dependent spin- state switching behaviors, Xiao-Peng Sun, Zheng Tang, Zi-Shuo Yao,* Jun Tao,* Chem. Commun. 2020, 56(1), 133-136.
A two-dimensional spin-crossover coordination polymer exhibiting interlayer multiple C?Hδ+···Hδ??B dihydrogen bonds, Jin-Peng Xue, Wen-Jie Wu, Quan-Song Li, Zi-Shuo Yao,* Jun Tao,* Inorg. Chem. 2019, 58(23), 15705-15709.
Giant anisotropic thermal expansion actuated by thermodynamically assisted reorientation of imidazoliums in a single crystal, Zi-Shuo Yao,* Han-Xi Guan, Yoshihito Shiota, Chun-Ting He, Xiao-Lei Wang, Shu-Qi Wu, Xiao-Yan Zheng, Sheng-Qun Su, Kazunari Yoshizawa, Xue-Qian Kong, Osamu Sato,* Jun Tao,* Nat. Comm. 2019, 10, 4805.
Facile synthesis of homochiral compounds integrating circularly polarized luminescence and two- photon excited fluorescence, Wen-Ting Deng, Hang Qu, Zhe-Yu Huang, Lin Shi, Zhi-Yong Tang, Xiao-Yu Cao,* Jun Tao,* Chem. Commun. 2019, 55(15), 2210-2213.
Spin crossover and photomagnetic behaviors in one-dimensional looped coordination polymers, Xiao-Peng Sun, Tao Liu, Zi-Shuo Yao,* Jun Tao,* Dalton Trans. 2019, 48(25), 9243-9249.
Ligand substituent effects on the spin-crossover behaviors of dinuclear iron(II) compounds, Chun- Feng Wang, Zi-Shuo Yao,* Guo-Yu Yang, Jun Tao,* Inorg. Chem. 2019, 58(2), 1309-1316.
Solvent effects on the structural packing and spin-crossover properties of a mononuclear iron(II) complex, Xiao-Peng Sun, Rong-Jia Wei,* Zi-Shuo Yao,* Jun Tao,* Cryst. Growth Des. 2018, 18(11), 6853-6862.
Monitoring the spin states of ferrous ions by fluorescence spectroscopy in spin-crossover-fluorescent hybrid materials, Chun-Feng Wang, Guo-Yu Yang, Zi-Shuo Yao,* Jun Tao,* Chem.?Eur. J. 2018, 24(13), 3218-3224.
Ring-opening polymeric single-crystal-to-single-crystal transformation in a cobalt(II) compound, Weng-Ting Deng, Ze-Bin Shen, Li-Jie Su, Yu-Hui Hua, Zhi-Xin Chen, Jun Tao,* Cryst. Growth Des. 2018, 18(2), 587-591.
Reversible three equal-step spin crossover in an iron(II) Hofmann-type metal-organic framework, Fu-Ling Liu, Dong Li, Li-Jie Su, Jun Tao,* Dalton Trans. 2018, 47(5), 1407-1411.
Iodide-centered cuprous octatomic ring: a luminescent molecular thermometer exhibiting dual- emission character, Cheng-Yang Yue, Fu-Ling Liu, Wen-Ting Deng, Jun Tao,* Mao-Chun Hong,* Cryst. Growth Des. 2018, 18(1), 22-26.
Hysteretic two-step spin-crossover behavior in two two-dimensional Hofmann-type coordination polymers, Fu-Ling Liu, Jun Tao,* Chem.?Eur. J. 2017, 23(72), 18252-18257.
A homochiral {CoII16CoIII4} supertetrahedral T4 cluster from a racemic ligand with ferromagnetic behavior and high photocatalytic activity, Wei Du, Yue-Ling Bai,* Xiu-Ping Yin, Jian-Hui Fang, Shou-Rong Zhu, Jun Tao,* Chem.?Eur. J. 2017, 23(33), 8025-8031.
Multiple correlations between spin crossover and fluorescence in a dinuclear compound, Chun-Feng Wang, Ming-Jun Sun, Qi-Jie Guo, Ze-Xing Cao,* Lan-Sun Zheng, Jun Tao,* Chem. Commun. 2016, 52(99), 14322-14325.
Spin transition and structural transformation in a mononuclear cobalt(II) complex, Ying Guo, Xiu-
Long Yang, Rong-Jia Wei, Lan-Sun Zheng, Jun Tao,* Inorg. Chem. 2015, 54(16), 7670-7672.
Coligand and solvent effects on the architectures and spin-crossover properties of (4,4)-connected iron(II) coordination polymers, Xue-Ru Wu, Hai-Yan Shi, Rong-Jia Wei,* Jia Li, Lan-Sun Zheng, Jun Tao,* Inorg. Chem. 2015, 54(8), 3773-3780.
Anionic metal–organic framework for adsorption and separation of light hydrocarbons, Jia Li, Hong- Ru Fu, Jian Zhang, Lan-Sun Zheng, Jun Tao,* Inorg. Chem. 2015, 54(7), 3093-3095.
Synergetic spin crossover and fluorescence in one-dimensional hybrid complexes, Chun-Feng Wang, Ren-Fu Li, Xue-Yuan Chen, Rong-Jia Wei, Lan-Sun Zheng, Jun Tao,* Angew. Chem., Int. Ed. 2015, 54(5), 1574-1577.
Valence tautomeric transitions of three one-dimensional cobalt complexes, Xiang-Yi Chen, Rong- Jia Wei, Lan-Sun Zheng, Jun Tao,* Inorg. Chem. 2014, 53(24), 13212-13219.
Solvent-mediated isomerization of FeII complexes from a 3D 65·8 framework to a 2D 4 4 rhombus- grid network, Xue-Ru Wu, Xu? Yang, Rong-Jia Wei,* Jia Li, Lan-Sun Zheng, Jun Tao,* Cryst. Growth Des. 2014, 14(10), 4891-4894.
A spin canted NiII4-based metal-organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons, Jia Li, Ying Guo, Hong-Ru Fu, Jian Zhang, Rong-Bin Huang, Lan- Sun Zheng, Jun Tao,* Chem. Commun. 2014, 50(65), 9161-9164.
Co-ligand and solvent effects on the spin-crossover behaviors of PtS-type porous coordination polymers, Xiang-Yi Chen, Rong-Bin Huang, Lan-Sun Zheng, Jun Tao,* Inorg. Chem. 2014, 53(10), 5246-5252.
Temperature, light and solvent-induced spin transition in a 3D 2-fold interpenetrated PtS-type porous coordination polymer, Xiang-Yi Chen, Hai-Yan Shi, Rong-Bin Huang, Lan-Sun Zheng, Jun Tao,* Chem. Commun. 2013, 49(93), 10977-10979.
A boracite metal–organic framework displaying selective gas sorption and guest-dependent spin- crossover behaviour, Feng Shao, Jia Li, Jia-Ping Tong, Jian Zhang, Ming-Guang Chen, Zhiping Zheng,* Rong-Bin Huang, Lan-Sun Zheng, Jun Tao,* Chem. Commun. 2013, 49(91), 10730-10732.
Four coordination polymers based on identical eight-connected heptanuclear clusters: spin canting, spin glass, antiferromagnetism, and gas adsorption, Jia Li, Bao Li, Peng Huang, Hai-Yan Shi,* Rong- Bin Huang, Lan-Sun Zheng, Jun Tao,* Inorg. Chem. 2013, 52(19), 11573-11579.
Metal-organic frameworks displaying single crystal-to-single crystal transformation through postsynthetic uptake of metal clusters, Jia Li, Peng Huang, Xue-Ru Wu, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Chem. Sci. 2013, 4(8), 3232-3238.
Unidirectional charge transfer in di-cobalt valence tautomeric compound finely tuned by ancillary ligand, Bao Li, Li-Qin Chen, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Inorg. Chem. 2013, 52, 4136-4138.
Ligand field effect tuned magnetic behaviors of two chain compounds based on MnIII3O units: from slow magnetic relaxation to metamagnetism, Yue-Ling Bai,* Xiao-Li Bao, Shou-Rong Zhu, Jian- Hui Fang, Jun Tao,* Dalton Trans. 2013, 42(4), 1033-1038.
Magnetic nanosized {MII24}-wheel-based (M = Co, Ni) coordination polymers, Jia Li, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Inorg. Chem. 2012, 51(11), 5988-5990.
Thermal and photoinduced valence tautomerism of a chain compound, Li-Qin Chen, Rong-Jia Wei, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Sci. China Chem. 2012, 55(6), 1037-1041.
Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato)dysprosium(III) double-decker SMMs, Hai-Long Wang, Kang Wang, Jun Tao,* Jian-Zhuang Jiang,* Chem. Commun. 2012, 48(24), 2973-2975.
Polymorphism in spin-crossover systems, Jun Tao,* Rong-Jia Wei, Rong-Bin Huang, Lan-Sun Zheng,
Chem. Soc. Rev. 2012, 41(2), 703-737.
Spin-crossover FeII4 squares: two-step complete spin transition and reversible single-crystal-to- single-crystal transformation, Rong-Jia Wei, Qian Huo, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Angew. Chem. Int. Ed. 2011, 50(38), 8940-8943.
Reversible and irreversible vapor-induced guest molecule exchange in spin-crossover compounds, Rong-Jia Wei, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Inorg. Chem. 2011, 50(17), 8553-8564.
Microwave-assisted synthesis of a ferrimagnetic dodecanuclear iron(III) complex with a Fe4(OH)4 cubane core, Jia-Ping Tong, Feng Shao, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Inorg. Chem. 2011, 50(6), 2067-2069.
Making spin-crossover crystals by successive polymorphic transformations, Rong-Jia Wei, Bao Li, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Zhiping Zheng,* Inorg. Chem. 2011, 50(4), 1170-1172.
Temperature-dependent in situ ligand cyclization via C=C coupling and formation of a spin- crossover iron(II) coordination polymer, Feng-Lei Yang, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Inorg. Chem. 2011, 50(3), 911-917.
Thermally induced and photoinduced valence tautomerism in a two-dimensional coordination polymer, Bao Li, Li-Qin Chen, Rong-Jia Wei, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Zhiping Zheng,* Inorg. Chem. 2011, 50(2), 424-426.
In situ C-C coupling and formation of a heptanuclear copper(II) cluster, Jia-Ping Tong, Xiao-Jun Sun, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Inorg. Chem. 2010, 49(4), 1289-1291.
Solvent-induced transformation of single crystals of a spin-crossover (SCO) compound to single crystals with two distinct SCO centers, Bao Li, Rong-Jia Wei, Jun Tao,* Rong-Bin Huang, Lan-Sun Zheng, Zhiping Zheng,* J. Am. Chem. Soc. 2010, 132(5), 1558-1566.
Pressure effects on a spin-crossover monomeric compound [Fe(pmea)(SCN)2] (pmea = bis[(2- pyridyl)methyl]-2-(2-pyridyl)ethylamine), Bao Li, Rong-Jia Wei, Jun Tao,* Rong-Bin Huang, Lan- Sun Zheng, Inorg. Chem. 2010, 49(2), 745-751.
An iron(II) incomplete spin-crossover compound: pressure effects and Mossbauer spectroscopy study, Feng-Lei Yang, Bao Li, Taro Hanajima, Yasuaki Einaga,* Rong-Bin Huang, Lan-Sun Zheng, Jun Tao,* Dalton Trans. 2010, 39(9), 2288-2292.
