陈健(John Jian Chen)
单位：中科院合肥物质科学研究院固体物理研究所
地址：安徽省合肥市蜀山湖路350号
邮编：230031
电话：86-
个人主页： http://people.ucas.ac.cn/~jchen
实验室介绍：


个人简历 Personal resume


陈健(John Jian Chen)，博士、研究员，博士导师，加拿大籍专家，九三学社中央促创工委委员，中国非金属矿工业协会石英及石英材料专委会常务理事，河南省自然资源科技创新中心主任委员。1989年获中南大学学士学位，1992年获中国科学院金属研究所硕士学位，1995年获中国科学院金属研究所博士学位。其后在在国内外多家科研机构和公司一直从事科研工作。 1995-1996，韩国机械研究院，客座研究员 1996-1998，中南大学粉末冶金研究所，副研究员 1998-2002，美国Kentucky大学, 博士后 2002-2005，加拿大Dalhousie大学, 博士后 2005-2007，加拿大Defense Research & Development Canada(国防研发部材料研究室), 研究科学家 2007-2011，加拿大6N Silicon Inc.公司/美国Calisolar公司，研发科学家 2011-现在, 中国科学院合肥物质科学研究院, 研究员 长期从事新材料的制备理论和应用技术研究，如纳米材料，3D打印粉末，薄膜材料，形状记忆合金，储能材料，高纯硅基材料，光电转换材料，钙钛矿材料，矿物材料等；材料加工技术如冶炼，铸造，凝固，提纯，微波处理等；材料微观结构分析表征，性能测试分析与模拟计算等。成功地研发出了多项技术和产品。 在硅料提纯的理论研究中，提出了Al-Si合金法凝固偏析提纯的表观偏析系数的概念和计算方法并用于提纯动力学的研究，证明了动力学因素是控制提纯效率的一个关键参数，在该理论的指导下，通过研究提纯时的温度场，熔体流场，电磁场以及杂质元素的耦合交互作用，进一步发现了几种新的提纯机制，关键杂质元素B和P的提纯效率得到显著提高，均大幅度打破了行业的提纯效率记录并突破了Al-Si-X三元体系热力学提纯效率理论极限，为太阳能级硅料生产核心技术的创新与突破打下了坚实基础。2007年，在加拿大参与创立6N Silicon Inc.公司并担任研发科学家，发明了Al-Si合金法提纯硅料时初晶硅高效分离及废酸综合利用技术，使生产成本大幅度降低，在世界上首次实现Al-Si合金法提纯硅料技术的产业化生产，该技术在加拿大获得多个奖项和北美主流媒体的广泛关注和报导，还发明了高纯硅材料的快速低成本检测技术，5年累计检测10万个硅材料样品，远超同行的其它实验室。 近来，在石英砂的提纯研究中，发现了一个新型低成本绿色捕收剂聚醚胺(PEA)，该捕收剂对环境友好，而且可以在零度到室温均呈现为液态，能够方便地溶于水，克服了传统的捕收剂难溶于水，对浮选温度敏感的问题，它还可以在pH 2 - pH10的范围内，特别是自然pH条件下对石英砂进行有效捕收；在此基础上，提出了利用PEA捕收剂的吸附量与石英砂的杂质含量有关的现象，采用浮选方法来将石英砂进行纯度分级的原理，成功地将天然石英砂分级成为不同纯度的几组，其中的高纯组的纯度要显著高于原矿的纯度，为石英砂纯度的提高找到了一个新的途径，在工业上具有良好的应用前景；并且还将PEA成功地用于太阳电池硅片切割废硅粉中高纯硅粉和碳化硅粉的浮选分离回收；还将其用于协助硅粉表面进行有机物碳包覆，提高了碳包覆的均匀性，大幅度提高了纳米Si/C复合负极材料的电化学性能。还提出利用微波处理和混合酸酸浸方法提纯石英砂，Fe的去除率一次处理可以达到99.94%，这是目前已知最高的Fe去除率。 还利用我们提出的新型石英砂提纯理论，在国内首次从国产花岗岩中成功地分离出了具有与美国尤尼明石英砂相似的微观结构，纯度达到4N7，羟基含量低的高纯石英砂，为突破我国高纯石英砂领域“卡脖子”技术难题带来了曙光。 研究的Al-Si合金法制备多层级微纳结构硅碳负极材料用于锂电池也使其容量获得了大幅度的提升，同时材料的循环寿命也显著的改善，在840 mA g-1的电流密度下循环200圈，依然保留1226 mAhg-1的可逆比容量，而且具有大规模低成本生产的良好前景。 发表SCI论文100篇以上，并申请专利10余项。


研究方向 Research direction


1、石英砂和硅基材料提纯深加工，功能材料
2、锂离子电池，动力电池材料/纳米，微纳结构材料，电化学性能
3、太阳能电池材料/高纯硅材料，铸锭，切割，制绒，太阳电池制备



招生信息 Enrollment information


招收材料，物理，冶金，化学等专业的毕业生攻读博士和硕士学位，与加拿大多伦多大学等多家国内外高校，研究机构和企业单位有合作关系并联合培养研究生，本团队研究方向兼具理论意义和实用性，学生毕业后的就业前景良好，依托合肥综合性国家科学中心，科研条件优越，合肥长期位列全国最具幸福感城市之一，科研实力居全国第三，欢迎有志科研的同学申请加入团队。博士研究生招生采用申请-审核制录取。硕士研究生招生采用夏令营申报，学校推免或者参加全国统考的方式录取。联系方式：电子邮件: jchen@ipp.ac.cn


论文专著 The monograph


1)Carbon nanotubes-enhanced lithium storage capacity of recovered silicon/carbon anodes produced from solar-grade silicon kerf scrap - Electrochimica Acta - 202104 - 381 (2021) 138269
2)A surface-engineering-assisted method to synthesize recycled silicon-based anodes with a uniform carbon shell-protective layer for lithium-ion batteries - Journal of Colloid and Interface Science - 2021 - 588 (2021) 737-748
3)Mechanism of boron removal of primary Si phases and morphology evolution of impurity phases during slow cooling solidification refining of Al-30wt.%Si alloy with Zr additions - Journal of Alloys and Compounds - 2021 - 860 (2021) 158517
4)Progress in recovery and recycling of kerf losssilicon waste in photovoltaic industry - Separation and Purification Technology - 2021 - 254, (2021), 117581
5)Purification mechanism of quartz sand by combination of microwave heating and ultrasound assisted acid leaching treatment - Silicon - 2021 - 13 (2021) 531-541
6)Recycled silicon-based anodes with three-dimensional hierarchical porous carbon framework synthesized by a self-assembly CaCO3 template method for lithium ion battery - Journal of Alloys and Compounds - 2021 - 858, (2021), 157703
7)Influence of Interactions between Alumina Crucible and Si-Ca-Fe Melt on B and P Removal from Silicon - Separation and Purification Technology - 2021 - 254, (2021), 117743
8)Effect of mechanical stirring on silicon purification during Al-Si solvent refining - Journal of Crystal Growth - 2021 - 553, (2021), 125943
9)Effect of impurity content difference between quartz particles on flotation behavior and its mechanism - Powder Technology - 2020 - 375, (2020), 504-512
10)Recovery of high purity Si from kerf -loss Si slurry waste by flotation method using PEA collector - Waste Management - 2020 - 115 (2020) 1–7
11)A simple method to fabricate size and porosity tunable Si by Al–Si alloy as lithium ion battery anode material - Electrochimica Acta, - 2020 - (2020), 136242
12)Investigating Boron and Phosphorus Removal from Silicon by Si-Ti and Si-Ti-Fe Alloying Systems - Separation and Purification Technology - 2020 - 250, (2020), 117227
13)Porous Si/C anode materials by Al–Si dealloying method with PEA surfactant assisted cross-linked carbon coating for lithium-ion battery applications - Electrochimica Acta - 2019 - 327, (2019), 134995
14)Separation and Recovery of Refined Si from Al–Si Melt by Modified Czochralski Method - Materials - 2020 - 13(4), (2020), 996
15)Effect of calcium addition on the silicon purification in the presence of low concentration of iron - Journal of Alloys and Compounds - 2020 - (2020), 154112
16)Boron and Phosphorus Removal During High Purity Hypereutectic Al–Si Solidification - Metals and Materials International - 2020 - 26, (2020), 526-531
17)Nano-encapsulated phase change materials prepared by one-step interfacial polymerization for thermal energy storage - Materials Chemistry and Physics - 2019 - 231 (2019) 244–251
18)Regulating the mesogenic properties of imidazolium salts by modifying N3-substituents - Science China Chemistry - 2015 - Vol.58 No.12: 18
19)Flotation Behavior, Collector Adsorption Mechanism of Quartz and Feldspar-Quartz Systems Using PEA as a Novel Green Collector - Silicon - 2020 - 12, (2020), 327-338
20)Effect of interaction between impurity elements on silicon purification during Al–Si solvent refining - Mater. Res. Express - 2019 - 6, (2019) 1065d7
21)Synthesis and performance evaluation of paraffin microcapsules with calcium carbonate shell modulated by different anionic surfactants for thermal energy storage - Colloids and Surfaces A: Physicochemical and Engin - 2019 - 571 (2019), 36-43
22)Segregation Behavior of Metal Impurities During Al-Si Melt Directional Solidification with an Open Ended Crucible - Silicon - 2018 - 10(2018), 1283-1290
23)Solidification refining of MG-Si by Al-Si alloy under rotating electromagnetic field with varying frequencies - Separation and Purification Technology - 2018 - 202 (2018) 266–274
24)Distribution Behavior of B and P during Al-Si Melt Directional Solidification with Open-Ended Crucible - High Temperature Materials and Processes - 2018 - 37 (2018), 201–208
25)Anthracene-arylamine hole transporting materials for perovskite solar cells - CHEMICAL COMMUNICATIONS - - 1359-7345
26)Improving the performance of arylamine-based hole transporting materials in perovskite solar cells: Extending π-conjugation length or increasing the number of side groups? - Journal of Energy Chemistry - - 2095-4956
27)Tetraphenylmethane-arylamine hole transporting materials for perovskite solar cells - ChemSusChem - - 1864-5631
28)Thiophene-arylamine hole transporting materials in perovskite solar cells: Substitution position effect - Energy Technology - - 2194-4288
29)Impurity Distribution after Solidification of Hypereutectic Al-Si Melts and Eutectic Al-Si Melt - High Temperature Materials and Processes - 2019 - 38, (2019), 389-395
30)Diketopyrrolopyrrole or benzodithiophene-arylamine small-molecular hole transporting materials for stable perovskite solar cells - RSC Advances - - 2046-2069
31)Study of the Boron Distribution and Microstructure of Solidified Al-Si Alloy During the Process of Silicon Purification - High Temperature Materials and Processes, - 2018 - 37(2018), 69-73
32)Influence of π-linker on triphenylamine-based hole transporting materials in perovskite solar cells - DYES AND PIGMENTS - - 0143-7208
33)Effect of Ti Addition on B Removal during Silicon Refining in Al-30%Si Alloy Directional Solidification - Separation and Purification Technology - 2017 - 174 (2017) 345–351
34)Effect of Sn doping on improvement of minority carrier lifetime of Fe contaminated p-type multi-crystalline Si ingot - Journal of Crystal Growth - 2017 - 458 (2017) 66–71
35)Improving the performance of arylamine-based hole transporting materials in perovskite solar cells: Extending π-conjugation length or increasing the number of side groups? - Journal of Energy Chemistry - 2018 - 27, (2018) 1409-1414
36)Removal of impurities from metallurgical grade silicon during Ga-Si solvent refining - Silicon - 2017 - 9 (2017): 77-83
37)Effect of kinetics on P removal by Al-Si solvent refining at low solidification temperature - Journal of Alloys and Compounds - 2016 - Volume 685, P604-609
38)Mechanism of boron removal from Si-Al melt by Ar-H2 gas mixtures - Transactions of Nonferrous Metals Society of China - 2016 - 2016. 26(11): 3046~3051
39)Mechanism of B removal by solvent refining of silicon in Al–Si melt with Ti addition - Journal of Alloys and Compounds - 2016 - Volume 672, 2016, P489–496
40)Molecular engineering of simple benzene-arylamine hole transporting materials for perovskite solar cells - ACS Applied Materials & Interfaces - - 1944-8244
41)Effect of iron addition (up to 10000 ppmw) on silicon purification during Al-Si solvent refining - Journal of Crystal Growth - 2016 - 453 (2016): 49-53
42)Diketopyrrolopyrrole or benzodithiophene-arylamine small-molecule hole transporting materials for stable perovskite solar cells - RSC Adv. - 2016 - 6 (2016) 87454-87460
43)Refining of metallurgical grade Si by solidification of Al–Si melt under electromagnetic stirring - Journal of Materials Processing Technology - 2015 - 222 (2015) 142–147
44)Effect of cooling rate on phosphorus removal during Al-Si solvent refining - Metallurgical And Materials Transactions B - 2015 - VOLUME 46B, 2015，542-544
45)Effect of cooling rate on boron removal and solidification behavior of Al-Si alloy - High Temperature Materials and Processes - 2015 - 34: 43-49
46)The Mechanism of P Removal by Solvent Refiningin Al-Si-P System - Metallurgical and Materials Transactions B - 2015 - VOLUME 46B, 2430-2437
47)Effect of Ga addition on morphology and recovery of primary Si during Al-Si alloy solidification refining - High Temperature Materials and Processes - 2015 - 34(8): 833-838
48)Distribution of Al in Al–Si Alloys during electromagnetic continuous casting with cylindrical open ended crucible - International Journal of Cast Metals Research - 2015 - V28 (2015), 269-275