李亚辉


性别：
男
单位：
资源与环境学院
专业名称：
农药学

研究方向：
新型农药研发，手性农药合成，羰基化在农药合成中应用

技术职务：
特任教授

E-mail：
Yahui.Liahau.edu.cn

实验室主页：


通讯地址：
合肥市长江西路130号

邮政编码：
230036

李亚辉，皖江****（青年），博士生导师，博士
博士毕业于德国莱布尼茨催化研究所LIKAT，2018年8月作为海外高层次引进人才受聘于安徽农业大学资源与环境学院，安徽省农产品质量安全重点实验室，花日茂教授团队。
真诚欢迎各位同学报考本课题组研究生、博士生，补助及福利待遇除按学校有关规定执行外，将根据研究进展和贡献给予相应补贴。同时，对努力，优秀的学生，可推荐到国内外高校继续深造。
同时欢迎对科研感兴趣的本科生加入到本课题组，对于努力，上进的学生，同样十分乐意帮助推荐到国内外高校继续深造。

　实验条件：

课题组配有专业从事有机合成实验室，岛津GC-MS 2010 气相色谱质谱联用仪，岛津GC-2010 Pro气相色谱仪等设备。
安徽省农产品质量安全重点实验室另配有先进测试设备 如Waters XevoTQ MS 液-质-质联用仪(2台)、Agilent 7000C 三重四极杆气-质-质联用仪、Agilent 6890 GC、岛津气相色谱仪、Aglient 1200 HPLC、岛津LC-20AT 液相色谱仪等。

　主要研究领域：

1）新型靶向农药的研发 2）新型手性农药的合成 3）小分子气体在农药合成中的应用 4）有机合成

　科研情况：

目前主持承担的项目：（1） 安徽自然科学基金面上项目

　获奖情况：

2019年 安徽省皖江****（青年）

　论文论著：

在化学权威期刊发表SCI论文20余篇，其中以通讯作者或第一作者发表文章16篇，期刊包括 Chem. Soc. Rev., Angew. Chem, Comm. Chem., Acs Cata., Chem. Sci., Green Chem., ChemSusChem, Chem. Comm, Organ. Lett., 等，影响因子总和超过140。
部分论文如下：
工作以来发表文章（通讯作者或第一作者）
2020年
1. Y. Li*, et.al Palladium-catalyzed intermolecular transthioetherification of aryl halides with thioethers and thioesters，Chem Sci. 2020, 11, 2187
2. Y. Li, et.al Direct C−H Bond Borylation of (Hetero)Arenes: Evolution from Noble Metal to Metal Free，Angew. Chem. Int. Ed. 2020, 59, 1770
博士期间工作
Y. Li, X-F. Wu, Copper/Iron-Cocatalyzed Alkoxycarbonylation of Unactivated Alkyl Bromides, Communication Chemistry. DOI:10.1038/s42004-018-0039-6
Y. Li, YY. H, X.-F. Wu, Non-noble metal-catalysedcarbonylative transformations，Chem. Soc. Rev. 2018, 47, 172-194. IF > 40.1
Y. Li, Z.Wang, X.-F. Wu, Palladium-Catalyzed Carbonylative Direct Transformation of Benzyl Amines under Additive-Free Conditions, ACS Catal., 2018, 738–741. IF>11.3
Y. Li, K. Dong, F. Zhu, Z. Wang, X.-F. Wu，Copper-Catalyzed Carbonylative Coupling of Cycloalkanes and Amides，Angew. Chem. Int. Ed.,2016, 55, 7227-7230. (VIP Paper, Hightlighton Chemistryviews.org)，IF>12.1
Y. Li, F. Zhu, Z. Wang, X.-F. Wu, Copper-Catalyzed Carbonylative Synthesis of Aliphatic Amides from Alkanes and Primary Amines via C(sp3)−H Bond Activation, ACS Catal., 2016, 5561-5564. IF>11.3
Y. Li, Z. Wang, X.-F. Wu, A Sustainable Procedure toward Alkyl Arylacetates: Palladium- Catalysed Direct Carbonylation of Benzyl Alcohols in Organic Carbonates, Green Chem.,2018, 20, 969-972. IF>8.5
Y. Li, F. Zhu, Z. Wang, X.-F. Wu, Copper-Catalyzed Carbonylative Four Components Reaction of Ethene and Aliphatic Olefins, Chem. Commun., 2018, 54, 1984-1987. IF>6.3
Y. Li, C. Wang, F. Zhu, Z. Wang, P. H. Dixneuf, X.-F. Wu, Copper-Catalyzed Alkoxycarbonylation of Alkanes with Alcohols，ChemSusChem.，2017, 10, 1341-1345. (Back cover, VIP Paper), IF>7.4
Y. Li, C. Wang, F. Zhu, Z. Wang, J. Francois Soule, P. H. Dixneuf, X.-F. Wu, An unexpected copper-catalyzed carbonylative acetylation of amines，Chem. Commun., 2017, 53, 142-144. IF>6.3
Y Li, W. Liu, C. Kuang, Direct arylation of pyridines without the use of a transition metal catalyst, Chem. Comm., 2014, 50, 7124-7127. IF>6.3
Y. Li, F. Zhu, Z. Wang, J. Rabeah, A. Brückner, X.-F. Wu, Practical and General Manganese-Catalyzed Carbonylative Coupling of Alkyl Iodides with Amides. ChemCatChem., 2017, 9, 915-919. IF>4.8
Y. Li, F. Zhu, Z. Wang, X.-F. Wu, Synthesis of Thioethers and Thioesters with Alkyl Arylsulfinates as the Sulfenylation Agent under Metal-Free Conditions. Chem. Asian J., 2016, 11,3503 –3507. IF>4.6
F. Zhu, Y. Li, Z. Wang, X. F. Wu, Iridium-Catalyzed Carbonylative Synthesis of Chromenones from Simple Phenols and Internal Alkynes at Atmospheric Pressure. Angew. Chem. Int. Ed. 2016, 55, 14151-14154. IF>11.9
Z. Wang, Y. Li, F. Zhu, X. F. Wu, Palladium-Catalyzed Oxidative Carbonylation of Aromatic C−H Bonds with Alcohols using Molybdenum Hexacarbonyl as the Carbon Monoxide Source. Adv. Synth. Catal. 2016, 358, 2855-2859，（IF>6.4）
F. Zhu, Y. Li, Z. Wang, X. F. Wu, Iridium-Catalyzed Carbonylative Synthesis of Halogen-Containing Quinolin-2(1H)-ones from Internal Alkynes and Simple Anilines, Adv. Synth. Catal. ,2016, 358, 3350-3354, （IF>6.4）
W. Liu, Y. Li, Y. Wang, C. Kuang. Pd-Catalyzed Oxidative CH/CH Direct Coupling of Heterocyclic N-Oxides, Org. Lett. , 2013, 18, 4682-4685, IF>6.5
W. Liu, Y. Li, B. Xu, C. Kuang. Palladium-Catalyzed Olefination and Arylation of 2-Substituted 1,2,3-Triazole N-Oxides, Org. Lett.2013, 10, 2342 -2345. IF>6.5
F. Zhu, Y. Li, Z. Wang, R. V. Orru, B. U. Maes, X. F. Wu, Palladium-Catalyzed Construction of Amidines from Arylboronic Acids under Oxidative Conditions, Chem. Eur. J. 2016, 22, 7743-7746(Hot Paper). （IF>5.7）
F. Zhu, Y. Li, Z. Wang, X.-F. Wu, Highly efficient synthesis of flavones via Pd/C-catalyzed cyclocarbonylation of 2-iodophenol with terminal acetylenes, Catal. Sci. Technol, 2016, 6, 2905-2909. （IF>5.7）
F. Zhu, Y. Li, Z. Wang, X. F. Wu, An Efficient Rhodium-Catalyzed Carbonylative Annulation of Internal Alkynes and Anilines To Produce Maleimides, ChemCatChem, 2016, 8, 3710-3713. （IF>4.8）