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浙江工业大学化学工程学院导师教师师资介绍简介-沈振陆

本站小编 Free考研考试/2021-04-06

name
沈振陆
education
博士研究生
subject
绿色化学与技术学科
title
教授,博导
talent_level
浙江省高校中青年学科带头人
office_tel
**
email
zhenlushen@zjut.edu.cn
/upload/2019-02-25-10-57-364212.png
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学习经历
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2008.04-2008.10 美国新泽西州立大学(Rutgers University)访问****
2004.06至今 浙江工业大学化学工程学院教师
1999.09-2004.06 浙江大学化学系博士
1991.09-1995.06 浙江师范大学化学系本科

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学术兼职
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中国化学会会员
杭州市钱江特聘专家
《Chinese Chemical Letters》 青年编委
《精细石油化工》 特约编委

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id
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教授课程
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有机定量分析
文献检索



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研究方向
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药物活性化合物的合成方法研究
绿色合成新方法和新工艺的开发
复杂组分的结构解析
天然产物的分离和结构修饰

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科研项目
order
6
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1. “5-羟甲基糠醛选择性催化氧化反应系统的构建及其拓展应用研究”,国家自然科学基金,项目负责人
2. “绿色催化氧化体系DDQ/FePcLn/O2的构建与应用研究”,国家自然科学基金,项目负责人
3. “以分子氧为清洁氧源DDQ参与的催化氧化体系的构建与应用基础研究”,国家自然科学基金,项目负责人
4. “含羟基生物质基平台化合物选择性催化氧化的研究”,浙江省自然科学基金,项目负责人
5. “手性α-羟基酯的绿色催化合成研究”,浙江省自然科学基金,项目负责人
6. “新型有机催化氧化体系的构建及其应用研究”,浙江省自然科学基金,项目负责人
7. “天然维生素E提余废渣中植物甾醇的提取工艺研究”,浙江省科技厅项目,项目负责人
8. “含4-氨基喹唑啉骨架药物的绿色化关键技术研发与应用”,浙江省科技厅项目,项目负责人



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代表论文
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以第一作者或通讯作者发表的主要学术论著
2016-
1. Visible-light-induced aerobic oxidation of benzylic C(sp3)–H of alkylarenes promoted by DDQ/tert-butyl nitrite/AcOH, Synlett, 2019, 30: 218.
2. I2/Fe(NO3)3?9H2O-catalyzed oxidative synthesis of aryl carboxylic acids from aryl alkyl ketones and secondary benzylic alcohols, Tetrahedron Letters, 2018, 59: 4349.
3. Synthesis of 3-sulfenylindoles from indoles and various sulfenylation agents via aerobic oxidative C–S bond coupling, Synlett, 2018, 29: 1914.
4. Oxidative C–C bond cleavage for the synthesis of aryl carboxylic acids from aryl alkyl ketones, Synlett, 2018, 29: 1505.
5. Electrochemical Sulfenylation of Indoles with Disulfides Mediated by Potassium Iodide, Journal of The Electrochemical Society, 2018, 165: G67.
6. Direct synthesis of imines by 9-azabicyclo-[3,3,1]nonan-N-oxyl/KOH- catalyzed aerobic oxidative coupling of alcohols and amines, Chinese Chemical Letters, 2018, 29: 1269.
7. ABNO-Catalyzed Aerobic Oxidative Synthesis of 2-Substituted 4H-3,1-Benzoxazines and Quinazolines, European Journal of Organic Chemistry, 2017: 3335.
8. Ferric nitrate-catalyzed aerobic oxidation of benzylic sp3 C-H bonds of ethers and alkylarenes, Tetrahedron, 2017, 73: 3002.
9. One-Pot Electrochemical Oxidation of Alcohols to Nitriles Mediated by TEMPO, Journal of The Electrochemical Society, 2017, 164: G54.
10. Aerobic oxidation of secondary alcohols in water with ABNO/tert-butyl nitrite/KPF6 catalytic system, Tetrahedron Letters, 2017, 58: 652.
11. A practical iodine-catalyzed oxidative conversion of aldehydes to nitriles, RSC Advances, 2017, 7: 1484.
12. Electrocatalytic synthesis of nitriles from aldehydes with ammonium acetate as the nitrogen source, Electrochimica Acta, 2017, 226: 53.
13. A Mild TEMPO-Catalyzed Aerobic Oxidative Conversion of Aldehydes into Nitriles, Advanced Synthesis &. Catalysis, 2016, 358: 1157.
14. Metal-free, iodine-catalyzed regioselective sulfenylation of indoles with thiols, Tetrahedron Letters, 2016, 57: 1912.
15. 2,3-Dichloro-5,6-dicyano-1,4-benzoquinonecatalyzed aerobic oxidation reactions via multistep electron transfers with iron(II) phthalocyanine as an electron-transfer mediator, RSC Advances, 2016, 6: 51908.
16. An efficient and convenient method for the preparation of disulfides from thiols using oxygen as oxidant catalyzed by tert-butyl nitrite, Chinese Chemical Letters, 2016, 27: 1505.
17. Electrochemical synthesis of nitriles from aldehydes using TEMPO as a mediator,Electrochemisty Communications, 2016, 64: 51.
18. Efficient Electrooxidation of Alcohols Using TEMPO-Modified Polyaniline Electrode Prepared by Electrochemical Polymerization, Journal of The Electrochemical Society, 2016, 163: H321.
2015及以前
1. DDQ/tert-Butyl nitrite-catalyzed aerobic oxidation of diarylmethane sp3 C-H bonds, Tetrahedron, 2015, 71: 6733.
2. Transformation of ethers into aldehydes or ketones: a catalytic aerobic deprotection/oxidation pathway, Tetrahedron Letters, 2015, 56: 2768.
3. Electropolymerization and Electrocatalytic Activity of Poly(4-thienylacetyl-amino- 2,2,6,6-tetramethylpiperidinyl-1-yloxy)/(2,2-bithiophene) Copolymerm, Journal of The Electrochemical Society, 2015, 162: H251.
4. Selective oxidation of benzyl alcohol on poly(4-(3-(pyrrol-1-yl)propionamido)-2,2,6,6- tetramethylpiperidin-1-yloxy) electrode, Journal of Solid State Electrochemistry, 2015 19: 2291.
5. Copper-catalyzed a-aminoxylation of 1,3-dicarbonyl compounds with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) via an aerobic oxidative sp3 C-H bond activation. Tetrahedron, 2014, 70: 8226.
6. Characterization and Electrocatalytic Activity of Poly(4-thienylacetyl-oxy-2,2,6,6- tetramethylpiperidin-1-yloxy) Prepared by Electrochemical Polymerization. ECS Electrochemistry Letters, 2014, 3: H12.
7. Aerobic oxidative deprotection of benzyl-type ethers under atmosphericpressure catalyzed by 2,3-dichloro-5,6-dicyano-1,4-benzoquinone(DDQ)/tert-butyl nitrite. Tetrahedron Letters, 2013, 54: 1579.
8. Hexachlorocyclotriphosphazene (HCCP)-Mediated Direct Formationof Thioethers and Ethers from Quinazolin-4(3H)-ones. Molecules, 2013, 18: 5580.
9. 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)/tert-Butyl Nitrite/Oxygen: AVersatile Catalytic Oxidation System. Advanced Synthesis and Catalysis, 2011, 353: 3031.
10. One-pot synthesis of 4-aminoquinazolines by hexamethyldisilazane-mediated reaction of quinazolin-4(3h)-ones with amines. Synthetic Communications, 2011, 41: 3644.
11. Switching the Chemoselectivity in the Amination of 4-Chloroquinazolines with Aminopyrazoles. Organic Letters, 2010, 12: 552.
12. An Efficient HCCP-Mediated Direct Amination of Quinazolin-4(3H)-ones. Tetrahedron, 2011, 67: 1665.
13. TEMPO-tert-butyl nitrite: An efficient catalytic system for aerobic oxidation of alcohols. Advanced Synthesis and Catalysis, 2009, 351: 89.
14. Catalytic O-methylation of phenols with dimethyl carbonate to aryl methyl ethers using [BMIm]Cl. Green Chemistry, 2005, 7: 97.
15. Acid-catalyzed intramolecular oxa-Michael addition reactions under solvent-free and microwave irradiation conditions. Arkivoc, 2010, (xiv): 146.
16. Oxa-Michael 加成反应的研究新进展. 有机化学, 2009, 29: 1544.
17. Synthesis and characterization of new thiazolidin-4-one derivatives. Phosphorus, Sulfur, and Silicon and the Related Elements. 2009, 184: 523.
18. Study on Selective Dimerization of a-Methylstyrenes Promoted by Ionic Liquids. Catalysis Letters, 2008, 122: 3 59.
19. Asymmetric Glyoxylate-Ene Reactions Catalyzed by Chiral Pd(II) Complexes in the Ionic Liquid [bmim][PF6]. International Journal of Molecular Sciences, 2007, 8: 553.
20. 氯铝酸离子液体中Glyoxylate-Ene反应合成α-羟基酯. 催化学报, 2006, 27(3): 197.

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19254"
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