姓名：陈谦
学科：化学、生物质材料与能源
手机号码: **
邮箱：chenqian@hit.edu.cn
通讯地址：昆明市白龙寺300号 650024
西南林业大学化学工程学院
简历：
2017年12月至今，西南林业大学化学工程学院副教授
2008年4月2017年12月，哈尔滨工业大学基础与交叉科研院、化工与化学学院，副教授
2007年3月2008年4月， 日本理化学研究所金属有机化学研究室，博士后
2002年10月2006年3月，日本京都大学药学院，获药学博士学位
1997年9月2000年7月， 兰州大学化学化工学院，获理学硕士学位
1993年9月1997年7月，云南师范大学化学系，获理学学士学位
长期从事催化与有机合成、生物质化学与能源、生物质材料与环境等相关领域的研究工作，已在国际SCI期刊及国内核心期刊独立或合作发表学术论文40余篇，受到国际同行的好评。已主持完成国家自然科学基金项目1项、国家留学回国人员基金1项、哈工大海外引进人才启动基金1项、水资源国家重点实验室自主课题研究基金2项、哈工大理工医交叉项目1项，参与完成重点研发计划项目1项，现主持国家自然科学基金1项。担任国际期刊Angew.Chem.；Chem.Commun.;?Organic Chemistry Frontiers等杂志审稿人、教育部学位论文评审专家，2019年入选云南省中青年学术带头人后备人才，化学工程学院生物质化学转化与合成利用科技创新团队负责人。独立培养硕士研究生11人，合作培养硕士、博士研究生5人，其中2人获优秀毕业论文奖。
研究领域：
(1) 催化与有机合成：主要包括碳-碳键及碳-杂原子键的构筑，以设计、合成新型配体及催化剂为起点，探索新型催化反应为主要研究内容，以合成有用化合物或降解有机污染物为目标。
(2) 生物质材料与环境：设计、合成具有优良配位(螯合)性能的多功能吸附材料，并深入研究其对有机污染物及Hg2+、Cd2+、Cu2+等重金属离子的吸附行为，探明吸附机理，并将吸附性能优良的分子制备成可重复利用的吸附材料。
(3) 生物质的化学转化与利用：利用催化的方法实现生物质的选择性化学转化；利用生物质来源的化学品合成手性催化剂、高密度燃油或添加剂、精细化学品等。
发表论文：
1.Chen, Q.*; Luo, M.; Guo, F.; Liang, K.；Zhou, F.; Gao, G. An Addition of Terminal Alkynes to Phthalazin-2-ium Bromide catalyzed by Cupper. Adv. Synth. Catal.?2020, xxx, xxxxxxxx.
2.Jin, Q.; Kang, J.; Chen, Q. *; Shen, J.; Guo, F.; Chen, Z.* Efficiently enhanced Fenton-like reaction via Iron complex immobilized on silica particles for catalytic hydrogen peroxide degradation of 2,4-dichlorophenol. Applied Catalysis B: Environmental 2020, xxx, xxxxxx.
3.Jin, Q.; Chen, Q.*; Kang, J.; Shen, J.; Guo, F.; Chen, Z.* Fabrication of iron-dipicolinamide catalyst with Fe–N bonds for enhancing non-radical reactive species under alkaline Fenton process. Chemosphere, 2020, 241, xxx-xxx.
4.Chen, C.; Chen, Q.*; Kang, J.; Shen, J.; Wang, B.; Guo, F.; Chen, Z*. Hydrophilic triazine-based dendron for copper and lead adsorption in aqueous systems: Performance and mechanism. J. Molecular Liquids, 2020, xxx, xxx-xxx.
5.Chen, Q. *; Mao, Z.; Gao, K.; Guo, F.; Sheng, L.; Chen Z. Synthesis of 1, 2-Dihydroquinazolines via Rearrangement of Indazolium Salts. J. Org. Chem. 2018, 83, **.
6.Jin, Q.; Chen, Q. *; Shen, J.; Guo, F.; Chen, Z. *; Tian, J. Development of Fe(II) system based on N, N’-dipicolinamide for the oxidative removal of 4-chlorophenol. J. Hazard. Mater. 2018, 354, 206214.
7.Chen, Q. *; Liu, X.S.; Guo, F.; Chen, Z.L. An unexpected rearrangement of pyrazolium halides based on N-N bond cleavage: synthesis of 1, 2-dihydropyrimidines. Chem.Commun., 2017, 53, **.
8.Gao, G.L.; Chen, Q*. Recent advance in utilities of active iodine reagents as organo-catalyts in organic synthesis. Current Organocatalysis, 2017, 4, 3347.
9.康 晶，沈吉敏，陈忠林，金 悦，南 军，陈谦，赵晟锌. 2－苯基－4，5－二( 2－呋喃基)－1H－咪唑的晶体结构及化学发光性质研究, 黑龙江大学自然科学学报, 2017, 34, 69-76.
10.Chen, Q. *; Mao, Z.Q.; Guo, F.; Liu, X.S. Indazoliums Halide as Efficient Ligands for Pd-catalyzed Suzuki–Miyaura Cross-Coupling of Aryl Bromides with Arylboronic Acids. Tetrahedron Letters. 2016, 57, **.
11.Chen, Q. *; Li, L.; Zhou, G.; Ma, X.; Zhang, L.; Guo, F.; Luo, Y.; Xia, W. Chiral phosphorus–olefin ligands for the Rh(I)-catalyzed asymmetric addition of aryl boronic acids to electron-deficient olefins. Chem. Asian J. 2016, 11, **.
12.Chen, Q. *; Li, L.; Guo, F.; Mao, Z. The first application of C2-symmetric chiral sulfurous diamide as efficient sulfureolefin hybrid ligands for Rh-catalyzed asymmetric 1, 4-addition reactions. Tetrahedron 2016, 72, **.
13.Chen, Q. *; Liu, C.; Guo, F.; Li, L. A Palladium-catalyzed arylation of N-acyl-N,O-acetals with arylboronic reagents: synthesis of diarylmethylamines protected by easily removable acyl group. Tetrahedron 2015, 71, **.
14.Chang, J.; Chen, Z.; Wang, Z.; Kang, J.; Chen, Q.; Yuan, L.; Shen, J. Oxidation of microcystin-LR in water by ozone combined with UV radiation: The removal and degradation pathway. Chem. Eng. J. 2015, 276, 97–105.
15.Wang, Z.; Chen, Z.; Chang, J.; Shen, J.; Kang, J.; Chen, Q; Fabrication of a low-cost cementitious catalytic membrane for p-chloronitrobenzene degradation using a hybrid ozonation-membrane filtration system. Chem. Eng. J. 2015, 262, 904–912
16.Wang, Z.; Chen, Z.; Chang, J.; Shen, J.; Kang, J.; Yang, L.; Chen, Q. A novel cementitious micro?ltration membrane: mechanisms of pore formation and properties for water permeation. RSC Adv., 2015, 5, 99–108
17.Chang, J.; Chen, Z.; Wang , Z.; Shen, J.; Chen, Q.; Kang, J.; Yang, L.; Liu, X.; Nie, C. Ozonation degradation of microcystin-LR in aqueous solution: Intermediates, byproducts and pathways. Water Research 2014, 63, 5261.
18.Chen, Q. *; Chen, C.; Guo F.; Xia, W. Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(I) catalyzed 1,4-addition of aryl boronic acids with cyclic enones. Chem.Commun., 2013, 49, **.
19.Chen, Q.* Recent Advances of Immobilized Catalysts for Enantioselective Processes. Current Organic Chemistry, 2013, 17, **.
20.Han, Y.; Chen, Z.; Tong, L.; Yang, L.; Shen, J.; Wang, B; Liu, Y.; Chen, Q. Reduction of N-nitrosodimethylamine with zero-valent zinc. Water Research 2013, 47, 216224.
21.Chen, H.; Chen, Q*. Synthesis of Chirl N, P-ligands derived from L-proline and their application to 1, 3-dipolar cycloaddition. Chin. J. Org. Chem(有机化学). 2013, 33, 848853.
22.Hao, X.; Chen, Q.; Kuriyama, M.; Yamada, K.; Yamamoto, Y.; Tomioka, K. Rhodium-catalyzed asymmetric phenylation of N-phosphinoylarylimines with triphenylborane. Catal. Sci. Tech., 2011, 1, 6264.
23.Hao, X.; Chen, Q.; Yamada, K.; Yamamoto, Y.; Tomioka, K. Steric influence of N-phosphorus-arylimines on the rhodium-catalyzed asymmetric arylation. Tetrahedron 2011, 67, **.
24.Zhang, X.; Yi, Z.; Zhao, L.; Chen, Q.; Wang, X.; Xu, J.; Xia, W.; Yang, C. pH-dependent assembly of a series of inorganic–organic hybrid molybdenum(V) phosphate Cryst.Eng.Comm, 2010, 12, 595–603.
25.Yi, Z.; Yu,X.; Xia, W.; Zhao, L.; Yang, C.; Chen, Q.; Wang, X.; Xu, X.; Zhang, X. In?uence of the steric hindrance of organic amines on the superamolecular network based on polyoxovanadates. Cryst.Eng.Comm., 2010, 12, 242–249.
26.Hao, X.; Kuriyama, M.; Chen, Q.; Yamamoto, Y.; Yamada, K.; Tomioka, K. Steric Tuning of the Amidomonophosphane-Rhodium(I) Catalyst in Asymmetric Addition of Arylboroxines to N-Phosphinoyl Aldimines. Org. Lett. 2009, 11, **.
27.Zhao, G.; Yang, C.; Chen, Q.; Jin, J.; Zhang, X.; Zhao, L.; Xia, W. Photochemical studies on exo-bicyclo[2.1.1]hexyl and bicyclo[3.1.0]hexylaryl ketones: two approaches for synthesis of enantiomerically enrichedcyclopentene derivatives. Tetrahedron 2009, 65, 9952.
28.Chen, Q.; Kuriyama, M.; Hao, X.; Soeta, T.; Yamamoto, Y.; Yamada, K.; Tomioka, K. Chiral Amidophosphane-Rhodium(I)-Catalyzed Asymmetric Conjugate Arylation of Acyclic Enones with Arylboronic Acids. Chem. Pharm. Bull., 2009, 57, **.
29.Yang, C.; Xia, W.-J.; Chen, Q.; Zhang, X.; Li, B.; Gou, B.-Q. Photochemical Studies on Benzonorbornene Derivatives: Medium Effects and Asymmetric Induction. Lett. Org. Chem. 2009, 6, 4143.
30.Zhang, X.; Yi, Z.; Zhao, L.; Chen, Q.; Gu, X.; Xu, J.; Wang, X.; Yang, C.; Xu, X.; Xia, W. Steric hindrance-dependent rational design and synthesis of three new Keggin-based supramolecular networks. Dalton Trans., 2009, 9198–9206.
31.Chen, Q.; Soeta, T.; Kuriyama, M.; Yamada, K.; Tomioka, K. Efficient Catalytic Asymmetric Synthesis of trans-2-substituted 5-Arylcyclohexanones by Rhodium-Catalyzed Conjugate Arylation of Racemic 6-Substituted Cyclohexenones. Adv. Synth. Catal.?2006, 348, **.
32.Chen, Q.; Kuriyama, M.; Soeta, T.; Hao, X.; Yamada, K.; Tomioka, K. Asymmetric Synthesis of 5-Arylcyclohexenones by Rhodium(I)-Catalyzed Conjugate Arylation of Racemic 5-(Trimethylsilyl)cyclohexenone with Arylboronic Acids. Org. Lett. 2005, 7, **.
33.Kuriyama, M.; Soeta, T.; Hao, X.; Chen, Q.; Tomioka, K. N-Boc-L-Valine-Connected Amidomonophosphane-Rhodium(I) Catalyst for Asymmetric Arylation of N-Tosylarylimines with Arylboroxines. J. Am. Chem. Soc. 2004, 126, **.
34.Lin, X.; Cai, Y. J.; Li, Z.; Chen, Q.; Liu, Z.L.; Wang, R. Structure determination, apoptosis induction, and telomerase inhibition of CFP-2, a novel lichenin from Cladonia furcata. Biochimica et Biophysica Acta 2003, 1622, 99108.
35.Chen, Q.; Chen, X.; Cai, Y.; Wang, F.; Li, Z. X. Isolation, Purification, and Analysis of Polysaccharides from Adenophora potaninii Kosrh. ZhongYao Cai(中药材), 2002, 25, 2526.
36.Chen, Q.; Lin, X.; Cai, Y.; Li, Z. Structural analysis of polysaccharide from Cladonia furcata and its activities. Chem. Res. Chin. Univ. 2001, 17, 226–227.
37.Chen, X.; Wang, F.; Chen, Q.; Qin, X. C.; Li, Z. X. Analysis of Neurotoxin 3-N-Oxalyl-l-2,3-diaminopropionic Acid and Its α-Isomer in Lathyrus sativus by High-Performance Liquid Chromatography with 6-Aminoquinolyl-N-hydroxysuccinimidyl Carbamate (AQC) Derivatization. J. Agric. Food Chem. 2000, 48, **.
38.Wang, F.; Chen, X.; Chen, Q.; Qin, X. C.; Li, Z. X. Determination of neurotoxin 3-N-oxalyl-2, 3-diaminopropionic acid and non-protein amino acids in Lathyrus sativus by precolumn derivatization with 1-fluoro-2,4-dinitrobenzene. J. Chromatogr. A, 2000, 883, 113118.
39.Wang, F.; Chen, X.; Chen, Q.; Qin, X. C.; Li, Z. X. HPLC Determination of Neurotoxin β-N-oxalyl-L-α,β-diaminopropionic acid and Its α -Isomer in Lathyrus sativus by Precolumn Derivatization with 1-Fluoro-2,4-dinitrobenzene. Chin. Chem. Lett. 2000, 11, 435.
40.Wang, F.; Chen, X.; Chen, Q.; Qin, X. C.; Li, Z. X. Determination of Neurotoxin b-ODAP and Non-protein Amino Acids in Lathyrus Sativus by High-Performance Liquid Chromatography with Precolumn Derivatization with 6-Amino quinolyl-N-hydroxysuccinimidyl Carbamate (AQC). Chin. Chem. Lett. 2000, 11, 605.
41.Li, Z.; Huang, C.; Chen Q.; Wang, F.; Chen, Y. Studies on Chemical Constitution and Antitumor Activity of Galacto-glucan from Asparagus cochinchinensis. J. Lanzhou Uni.(兰州大学学报) 2000, 36, 7781
42.Zhao, L.; Chen, X.; Hu, Z.; Li, Q.; Chen, Q.; Li, Z. Analysis of ?-N-oxalyl-L-a,b-diaminopropionic acid and homoarginine in Lathyrus sativus by capillary zone electrophoresis. J. Chromatogr. A, 1999, 857, 295302.
承担科研项目及团队情况：
1. 国家自然科学基金委地区项目（**, 2019.01–2022.12）；
2. 云南省科技厅“三区”人才支持计划科技人员专项计划（2019, 2019.09–2020.08）；
3. 水资源与水环境国家重点实验室自主课题(2017TS01), (2017.01–2019.06）
4. 国家科技重大专项(2014ZX07405-002-04), (2014.1-2016.12)
5. 哈工大理工医交叉 (HIT.IBRSEM.A. 201404),（2014.06–2016.12）；
6. 水资源与水环境国家重点实验室自主课题(2014TS01), (2014.01–2016.06）
7. 水资源与水环境国家重点实验室自主课题(2010QN06), (2010.09-2012.08)
8. 国家自然科学基金委青年项目（**, 2009.01–2012.12）；
9. 教育部留学回国人员科研启动基金（2008.05–2010.04）；