孟祥太简介

姓名
孟祥太
性别
男
出生年月
1979.04
学历学位
博士


职称
教授
系别
应用化学系
导师类型
硕导

电话
**
Email
xtmeng@tjut.edu.cn

办公/
科研室
19号楼411室
硕导所属学科
081704 应用化学100701 药物化学

研究
方向
1. 有机小分子催化的串联反应研究
2. 鸟嘌呤核苷衍生物的合成以及自组装性质研究
3. 过渡金属催化的C-H键活化反应的研究

讲授
课程
有机化学， 绿色化学与生活

主要科研项目及代表性成果(包括鉴定项目、论文、专著、获奖、专利等)：

项目:
1. 鸟嘌呤核苷G-四链体调控π共轭分子的自组装及光物理性能研究（编号：**）， 国家自然科学基金 （2015.1-2017.12）， 25万， 主持人
2.苝二酰亚胺取代鸟苷的合成及自组装性质研究 （编号： 13JCYBJC38700）， 天津市自然科学基金一般项目 (2013.10-2016.9)， 10万， 主持人
3.：基于C-H键活化的C8取代鸟嘌呤新合成方法研究 (编号：**)，天津市高等学校科技发展基金计划项目(2012.11-2014.10)，4万元，主持人。
论文:
(1) Wenhuan Ding, Youquan Zhang, Aimin Yu, Lei Zhang, and Xiangtai Meng* Substrate-Controlled Domino Reactions of Crotonate-Derived Sulfur Ylides: Synthesis of Benzothiophene Derivatives J. Org. Chem. 2018, 83, 13821-13833.
(2) Jinhui Shen, Yang Yang, Xiaoli Hou, Wenlei Zeng, Aimin Yu, Xiaowei Zhao and Xiangtai Meng* Darzens reaction of thioisatins and sulfonium salts: approach to the synthesis of thiochromenone derivatives with anticancer potency Org. Biomol. Chem. 2018, 16, 3487-3494.
(3) Shanshan Ma, Aimin Yu* and Xiangtai Meng* Phosphine-catalyzed [4 + 2] annulation of γ-benzyl allenoates: facile synthesis of benzothieno[3,2-b]pyran derivatives Org. Biomol. Chem. 2018, 16, 2885-2892.
(4) Shanshan Ma, Aimin Yu, Lei Zhang, and Xiangtai Meng* Phosphine-Catalyzed Domino Reaction of Thioaurones and Allenoate: Synthesis of Benzothiophene-Fused Dioxabicyclo[3.3.1]nonane Derivatives J. Org. Chem. 2018, 83, 5410-5419.
(5) Ke Li, Aimin Yu, and Xiangtai Meng* Synthesis of Dibenzothiophene and 1,4-Dihydrodibenzothiophene Derivatives via Allylic Phosphonium Salt Initiated Domino Reactions Org. Lett. 2018, 20, 1106-1109.
(6) Jiru Jia, Aimin Yu,* Shanshan Ma, Youquan Zhang, Ke Li, and Xiangtai Meng* Solvent-Controlled Switchable Domino Reactions of MBH Carbonate: Synthesis of Benzothiophene Fused α-Pyran, 2,3-Dihydrooxepine, and Oxatricyclodecene Derivatives Org. Lett. 2017, 19, 6084-6087.
(7) Youquan Zhang, Aimin Yu, Jiru Jia, Shanshan Ma, Ke Li, Yin Wei* and Xiangtai Meng* NaH promoted [4 + 3] annulation of crotonate-derived sulfur ylides with thioaurones: synthesis of 2,5-dihydrobenzo[4,5]thieno[3,2-b]oxepines Chem. Commun. 2017, 53, 10672-10675.
(8) Yanlong Du, Aimin Yu,* Jiru Jia, Youquan Zhang and Xiangtai Meng* Direct N-H/α,α,β,β-C(sp³)-H functionalization of piperidine via an azomethine ylide route: synthesis of spirooxindoles bearing 3-substituted oxindoles Chem. Commun. 2017, 53, 1684-1687.
(9) Yanlong Du, Aimin Yu, Youquan Zhang, Jiru Jia, Prof. Xiangtai Meng* Cs₂CO₃-Promoted Michael Addition-[2,3]-Sigmatropic Rearrangement Domino Reaction: Facile Synthesis of a 3-Substituted Indoles Bearing a Homoallyl Sulfide Moiety Asian J. Org. Chem. 2016, 5, 1309-1313.
(10) Yufen Liu, Yanlong Du, Aimin Yu,* Haifeng Mu and Xiangtai Meng* DABCO-catalyzed unusual [4 + 2] cycloaddition reaction: non-substituted allenoate acts as a four-carbon synthon and facile synthesis of spirooxindoles Org. Biomol. Chem. 2016, 14, 1226-1230.
(11) Yufen Liu, Yanlong Du, Aimin Yu,* Dabin Qin, Xiangtai Meng* Diverse synthesis of pyrano[2,3-b]indol and dihydropyrano[2,3-b]indol via tunable Lewis bases catalyzed domino reactions Tetrahedron, 2015, 71, 7706-7716.
(12) Yanlong Du, Yufen Liu, Aimin Yu, Dabin Qin, Kui Zhang and Xiangtai Meng* A Catalyst-Free Approach to Construct 3-(Cyclopentenone)oxindoles Through a Phosphine-Ylide-Initiated Triple Domino Sequence Asian J. Org. Chem. 2015, 4, 630-637.
(13) Yufen Liu, Qi Zhang, Yanlong Du, Aimin Yu,* Kui Zhang and Xiangtai Meng* Convenient synthesis of substituted tetrahydrofuran via Lewis base catalyzed [3 + 2] domino reactions RSC. Adv. 2014, 4, 52629-52632.
(14) Qing Xiao, Dr. Xiangtai Meng, Prof.?Dr. Motomu Kanai and Prof.?Dr. Yoichiro Kuninobu Palladium-Catalyzed C-H Fluorosilylation of 2-Phenylpyridines: Synthesis of Silafluorene Equivalents Angew. Chem. Int.Ed. 2014, 53, 3168-3172.
(15) Xiangtai Meng,Toshiyuki Moriuchi,* Masatoshi Kawahata, Kentaro Yamaguchi and Toshikazu Hirao* A G-octamer scaffold via self-assembly of a guanosine-based Au(I) isonitrile complex for Au(I)-Au(I) interaction Chem. Commun. 2011, 47, 4682-4684.
(16) Xiangtai Meng, Toshiyuki Moriuchi,* Norimitsu Tohnai, Mikiji Miyata, Masatoshi Kawahata, Kentaro Yamaguchic and Toshikazu Hirao* Synthesis and assembling properties of bioorganometallic cyclometalated Au(III) alkynyls bearing guanosine moieties Org. Biomol. Chem. 2011, 9, 5633-5636.
(17) Xiangtai Meng, Toshiyuki Moriuchi,* Yuki Sakamoto, Masatoshi Kawahata, Kentaro Yamaguchi and Toshikazu Hirao* La(OTf)₃-mediated self-organization of guanosine with an alkynyl-Au(I)PPh₃ moiety to induce Au(I)-Au(I) interactions Rsc. Adv., 2012, 2, 4359-4363.
(18) Xiangtai Meng, Peizhong Xie, You Huang* and Ruyu Chen Organocatalytic domino reaction of salicyl N-thiophosphoryl imines and methyl vinyl ketone initiated by an aza-MBH reaction with bifunctional phosphine catalysts Rsc. Adv., 2012, 2, 8104-8109.
(19) Xiang-Tai Meng,* Rong-Hua Xu, Qing-Shan Li,* Feng-Bo Xu* Gold(I) and silver(I) complexes of a diphosphine analog of a half-calix[4]arene moiety Polyhedron, 2013, 50,502-506.
(20) Peizhong Xie, You Huang,* Wenqing Lai, Xiangtai Meng and Ruyu Chen Bifunctional phosphine-catalyzed cross-Rauhut-Currier/Michael/aldol condensation triple domino reaction: synthesis of functionalized cyclohexenes Org. Biomol. Chem. 2011, 9, 6707-6714.
(21) Naokazu Kano,* Masaki Yamamura, Xiangtai Meng, Takaharu Yasuzuka and Takayuki Kawashima Different coordination modes of 2-(diphenylphosphino)azobenzenes in complexation with hard and soft metals Dalton Trans. 2012, 41, 11491-11496.
(22) Naokazu Kano,* Kazuhide Yanaizumi, Xiangtai Meng and Takayuki Kawashima Control of reactivity of phosphine imides by intramolecular coordination with an organoboryl group Heteroat. Chem. 2012, 23, 429-434.
(23) Xiangtai Meng, You Huang, Hongxia Zhao, Peizhong Xie, Jianze Ma and Ruyu Chen PPh₃-Catalyzed Domino Reaction: A Facile Method for the Synthesis of Chroman Derivatives Org.Lett. 2009, 11, 991-994.
(24) Xiangtai Meng, You Huang and Ruyu Chen Bifunctional Phosphine-Catalyzed Domino Reaction: Highly Stereoselective Synthesis of cis-2,3-Dihydrobenzofurans from Salicyl N-Thiophosphinyl Imines and Allenes Org. Lett, 2009, 11, 137-140.
(25) Xiangtai Meng, You Huang and Ruyu Chen A Novel Selective Aza-Morita–Baylis–Hillman (aza-MBH) Domino Reaction and Aza-MBH Reaction of N-Sulfonated Imines with Acrolein Catalyzed by a Bifunctional Phosphine Organocatalyst Chem. Eur. J. 2008, 14, 6852-6856.
(26) Xiang-Tai Meng, Qing-Shan Li, Feng-Bo Xu, Hai-Bin Song, Christopher E. Anson, and Zheng-Zhi Zhang Extended Calix[4]arene Analogues by Two P-CuI-P Bridges and Anion Encapsulation Inorg. Chem. 2006, 45, 7986-7987.