党延峰博士
副研究员，博士生导师
天津大学“北洋青年****”
专业：物理有机化学、有机化学
联系方式:yanfeng.dang@tju.edu.cn
学习与工作经历：
2018.07–至今天津大学-化学系-副研究员（博导）
2015.11–2018.06 天津大学-化学系-副研究员（硕导）
2010.09–2015.07中国科学院大学-化学学院（博士）
2006.09–2010.07河南大学-化学化工学院 （学士）
研究领域：
（1）有机反应和金属有机均相催化反应的机理研究 （Comput. and Exptl.）
（2）新型过渡金属催化剂的理性优化设计及合成研究 （Comput. and Exptl.）
（3）新型有机金属化合物的设计、合成、结构及性质研究（Comput. and Exptl.）
承担科研项目：
（1）国家自然科学基金面上项目：**，项目名称：钌催化的炔烃水合还原反应的机理研究及新催化体系的优化设计，经费:65.00万元，执行期：2017.1-2020.12;
（2）天津大学北洋****项目：过渡金属催化的C-H活化/C-C偶联反应的机理研究，经费：40万元，执行期：2017.01-2020.12;
（3）天津市自然科学基金青年基金：钯-氨基酸/胺协同催化的C(sp³)-H活化/C-C偶联反应的机理研究，经费：6万元，执行期：2017.04-2019.03.
所获荣誉：
2016年 获天津大学“北洋青年****”
2016年 获中国科学院“优秀博士学位论文”
2015年 获中国科学院“院长特别奖”
2015年 获北京市“优秀毕业生”
2015年 获中国科学院“优秀毕业生”
2014年 获教育部“博士研究生国家奖学金”
2014年 获中国科学院“朱李月华优秀博士生奖”
2014年 获中国科学院“钱志道化学奖学金”
2012年 获教育部“硕士研究生国家奖学金”
代表性论文：
在J. Am.Chem. Soc.、ACS Catal.、J. Org. Chem.等国际知名杂志上发表论文30余篇：
(1). Ni, Z.; Wang, H.; Dong, H.; Dang, Y.; Zhao, Q.; Zhang, X.; Hu, W., Mesopolymer Synthesis by Ligand-modulated Direct Arylation Polycondensation towards n-Type and Ambipolar Conjugated Systems. Nat.Chem., 2019, 11, 271-277. (SCI/一区，IF: 26.201)
(2).Liu, W.;Zheng, J.; Liu, Z.; S, Hu, W.; Wang, X.; Dang, Y., How Does Palladium-Amino Acid Cooperative Catalysis EnableRegio- and Stereoselective C(sp³)-H Functionalization in Aldehydesand Ketones? A DFT Mechanistic Study. ACS Catal.,2018, 8, 7698-7709. (SCI/一区，IF: 11.384)
(3).Dang, Y.;Deng, X.; Guo, J.; Song, C.; Hu, W.; Wang, Z.-X., Unveiling Secrets ofOvercoming the “Heteroatom Problem” in Palladium-Catalyzed Aerobic C-HFunctionalization of Heterocycles: A DFT Mechanistic Study.J. Am. Chem.Soc., 2016,138, 2712-2723. (SCI/一区，IF: 14.357)
(4).Dang, Y.;Qu, S.; Tao, Y.; Deng, X.; Wang, Z.-X., Mechanistic Insight into Ketoneα-Alkylation with Unactivated Olefins via C-HActivation Promoted by Metal-Organic Cooperative Catalysis (MOCC): Enriching the MOCC Chemistry.J. Am. Chem. Soc., 2015,137, 6279-6291. (SCI/一区，IF: 14.357)
(5).Dang, Y.; Qu, S.; Nelson, J. W.; Pham, H. D.; Wang, Z.-X.; Wang, X., The Mechanism of a Ligand-Promoted C(sp³)-H Activation and Arylation Reaction via Palladium Catalysis: Theoretical Demonstration of a Pd(II)/Pd(IV) Redox Manifold.J. Am. Chem. Soc., 2015,137,2006-2014. (SCI/一区，IF: 14.357)
(6).Dang, Y.; Qu, S.; Wang, Z.-X.; Wang, X., A Computational Mechanistic Study of an Unprecedented Heck-Type Relay Reaction: Insight into the Origins of Regio- and Enantioselectivities.J. Am. Chem. Soc., 2014,136, 986-998. (SCI/一区，IF: 14.357)
(7).Qu, S.;Dang, Y.; Song, C.; Wen, M.; Huang, K.-W.; Wang, Z.-X., Catalytic Mechanisms of Direct Pyrrole Synthesis via Dehydrogenative Coupling Mediated by PNP-Ir or PNN-Ru Pincer Complexes: Crucial Role of Proton-Transfer Shuttles in the PNP-Ir System.J. Am. Chem. Soc.,2014,136, 4974-4991. (SCI/一区，IF: 14.357)
(8). Zhu, R.; Liu, Z.; Chen, J, Bai, J.; Dang, Y.; Huang, J. et al. Preparation of Thioanisole Biscarbanion and C-H Lithiation/Annulation Reactions for the Access of Five-Membered Heterocycles. Org. Lett.,2018, 20, 3161-3165. (SCI/一区，IF: 6.601)
(9). Guo, J.; Deng, X.; Song, C.; Lu, Y.; Qu, S.; Dang, Y., Wang, Z.-X., Differences between the Elimination of Early and Late Transition Metals: DFT Mechanistic Insights into the Titanium-Catalyzed Synthesis of Pyrroles from Alkynes and Diazenes.Chem. Sci., 2017, 8, 2413-2425. (SCI/一区，IF: 9.063)
(10). Lu,Y.;Gao, Z.;Chen,X.; Guo, J.;Liu,Z.;Dang,Y.;Ye, S.; Wang, Z.-X., Formylation or Methylation: What Determines the Chemoselectivity of the Reaction of Amine, CO₂, and Hydrosilane Catalyzed by 1,3,2-Diazaphospholene?Chem. Sci.,2017,8, 7637-7650. (SCI/一区，IF: 9.063)
(11).Qu, S.;Dang, Y.; Song, C.; Wang, Z.-X., Depolymerization of Oxidized Lignin Catalyzed by Formic Acid Exploits an Unconventional Elimination Mechanism Involving 3c-4e Bonding: A DFT Mechanistic Study.ACS Catal., 2015,5, 6386-6396. (SCI/一区，IF: 11.384)
(12).Qu, S.; Dai, H.;Dang, Y.; Song, C.; Wang, Z.-X.; Guan, H.,Computational Mechanistic Study of Fe-Catalyzed Hydrogenation of Esters to Alcohols: Improving Catalysis by Accelerating Pre-catalyst Activation with a Lewis Base,ACS Catal., 2014,4, 4377-4388. (SCI/一区，IF: 11.384)
(13). Song, C.; Qu, S.; Tao, Y.;Dang, Y.; Wang, Z.-X., DFT Mechanistic Study of Ru^II-Catalyzed Amide Synthesis from Alcohol and Nitrile Unveils a Different Mechanism for Borrowing Hydrogen.ACS Catal., 2014,4, 2854-2865. (SCI/一区，IF: 11.384)
(14).Dang, Y.; Qu, S.; Tao, Y.; Song, C.; Wang, Z.-X., Mechanistic Origins of Chemo- and Regioselectivity of Ru(II)-Catalyzed Reactions Involvingortho-Alkenylarylacetylene, Alkyne, and Methanol: The Crucial Role of a Chameleon-like Intermediate.J. Org. Chem., 2014,79, 9046-9064. (SCI/二区，IF: 4.785)
(15).Dang, Y.; Qu, S.; Wang, Z.-X.; Wang, X.,Mechanism and Origins of Z Selectivity of the Catalytic Hydroalkoxylation of Alkynes via Rhodium Vinylidene Complexes to Produce Enol Ethers.Organometallics, 2013,32, 2804-2813.(SCI/二区，IF: 4.186)
(16).Dang, Y.; Wang, Z.-X.; Wang, X., Does the Ruthenium Nitrato Catalyst Work Differently in Z-Selective Olefin Metathesis? A DFT Study.Organometallics, 2012,31, 8654-8657. (SCI/二区，IF: 4.186)
(17).Dang, Y.; Wang, Z.-X.; Wang, X.,A Thorough DFT Study of the Mechanism of Homodimerization of Terminal Olefins through Metathesis with a Chelated Ruthenium Catalyst: from Initiation toZ-Selectivity to Regeneration.Organometallics, 2012,31, 7222-7234.(SCI/二区，IF: 4.186)
(18).Deng X.;Dang, Y.; Wang, Z.-X.; Wang, X.,How Does an Earth-Abundant Copper-Based Catalyst Achieve Anti-Markovnikov Hydrobromination of Alkynes? A DFT MechanisticStudy.Organometallics, 2016,35,1923-1930.(SCI/二区，IF: 4.186)
(19).Song, C.;Dang, Y.; Tao, Y.; Wang, Z.-X., DFT Mechanistic Study of Functionalizations of ω-Ene-Cyclopropanes and Alkylidenecyclopropanes via Allylic C-H and C-C Bond Cleavage Facilitated by a Zirconocene Complex.Organometallics, 2015,34, 5233-5244. (SCI/二区，IF: 4.186)
(20).Qu, S.;Dang, Y.; Wen, M.; Wang, Z.-X., Mechanism of the Methyltrioxorhenium-Catalyzed Deoxydehydration of Polyols: A New Pathway Revealed.Chem.-Eur. J., 2013,19, 3827-3832. (SCI/二区，IF：5.731)