姓　　名
王佰全 性　　别
男
出生年月
1968-05 籍　　贯
辽宁锦州黑山县
学　　历
硕士 毕业院校
南开大学
职　　称
教授 管理职务
副院长
工作内容
教学科研 系所单位
化学系
特殊人才称号

通讯地址
天津市南开区卫津路94号南开大学化学学院化学楼北楼505
电 话
**
电子邮件
bqwang@nankai.edu.cn
课题组网站
http://skleoc.nankai.edu.cn/cms/item/view?table=team&id=412
研究领域
金属有机化学与均相催化，有机合成方法学
1. C-H键活化的金属有机化学
通过分步和计量反应分离鉴定关键反应中间体，研究过渡金属催化的C-H键活化反应的反应机理
基于对反应机理的理解，设计和发展新型高效的过渡金属催化的C-H键活化及转化反应
2. 过渡金属烯烃聚合催化剂的设计合成及催化烯烃聚合反应
重点研究基于阴离子N-杂环卡宾配体的过渡金属化合物的设计合成，研究它们在烯烃配位聚合和共聚等聚合反应的催化性能，开发具有自主知识产权的高效烯烃聚合催化剂。

教育及科研经历
1986-1990年，南开大学化学系，理学学士学位。
1990-1993年，南开大学化学系，理学硕士学位（有机化学）。
1993-1996年，南开大学化学系，理学博士学位（有机化学）。
1996年，南开大学化学系，任讲师。
1998年，南开大学化学系，教授。
2001年，南开大学化学系，博士生导师。
其中1997年3月至12月到香港中文大学化学系作访问****。
1999年9月至2000年8月到德克萨斯大学奥斯汀分校作博士后研究。
2003年起主讲化学学院本科生必修课《有机化学》，该课程2005年被评为南开大学校级示范精品课程。
主要从事金属有机化学及均相催化研究。科研成果累计发表SCI收录论文150余篇，授权中国发明专利10项。曾多次在国际或双边学术会议上作邀请报告。

相关网页参见：
http://skleoc.nankai.edu.cn/cms/item/view?table=team&id=412

荣誉和奖励
1998年，获教育部科技进步二等奖。
2004年，入选教育部“新世纪优秀人才支持计划”。
2017年，南开大学教学名师

科研成果与代表作
代表性研究成果：
1. 宋礼成，王佰全，《金属有机化学原理及应用》，高等教育出版社，103万字，2012.
2. Wang, B. Ansa-metallocene polymerization catalysts: effects of the bridges on the catalytic activities,
Coord. Chem. Rev. 2006, 250, 242-258.
3. Tan, X.; Liu, B.; Li, X.; Li, B.; Xu, S.; Song, H.; Wang B.* Rhodium-catalyzed cascade oxidative annulation leading to substituted naphtho[1,8-bc]pyrans by sequential cleavage of C(sp2)-H/C(sp3)-H and C(sp2)-H/O-H bonds,
J. Am. Chem. Soc. 2012, 134, 16163-16166.
4. Liu, B.; Zhou, T.; Li, B.; Xu, S.; Song, H.; Wang, B.* Rhodium(III)-catalyzed alkenylation reactions of 8-methylquinolines with alkynes via C(sp3)-H activation,
Angew. Chem., Int. Ed. 2014, 53, 4191-4195.
5. Li, B.; Wu, Z.; Gu, Y.; Sun, C.; Wang, B.*; Shi, Z.* Direct cross-coupling of C-H bonds with Grignard reagents through cobalt catalysis,
Angew. Chem., Int. Ed. 2011, 50, 1109-1113.
6. Zhou, T.; Li, B.; Wang, B.* Rhodium-catalyzed C2 and C4 C–H activation/annulation of 3-(1H-indol-3-yl)-3-oxopropanenitriles with internal alkynes: a facile access to substituted and fused carbazoles,
Chem. Commun. 2017, 53, 6343-6346.
7. Gong, D.; Hu, B.; Shi, J.; Ma, P.; Wang, B. *; Chen, D.* Synthesis of diruthenium complexes derived from pyridyl-substituted indenes,
Organometallics 2017, 36, 1066-1072.
8. Li, B.*; Xu, H.; Wang, H.; Wang, B.* Rhodium-catalyzed annulation of tertiary aniline N-oxides to N-alkylindoles: Regioselective C–H activation, oxygen-atom transfer, and N-dealkylative cyclization,
ACS Catal. 2016, 6, 3856-3862.
9. Ge, Q.; Hu, Y.; Li, B.; Wang, B.* Synthesis of conjugated polycyclic quinoliniums by rhodium (III)-catalyzed multiple C?H activation and annulation of arylpyridiniums with alkynes,
Org. Lett. 2016, 18, 2483-2486.
10. Shen, B.; Li, B.; Wang, B.* Rh(III)-catalyzed oxidative annulation leading to substituted indolizines by cleavage of C(sp2)-H/C(sp3)-H bonds,
Org. Lett. 2016, 18, 2816-2819.
11. Shi, L.; Wang, B.* Tandem Rh(III)-catalyzed C-H amination/annulation reactions: Synthesis of indoloquinoline derivatives in water,
Org. Lett. 2016, 18, 2820-2823.
12. Zhou, T.; Wang, Y.; Li, B.; Wang, B.* Rh(III)-catalyzed carbocyclization of 3-(indolin-1-yl)-3-oxopropanenitriles with alkynes and alkenes through C-H activation,
Org. Lett. 2016, 18, 5066-5069.
13. Zhou, T.; Li, B.; Wang, B.* Rhodium-catalyzed C–H activation of of 3-(indolin-1-yl)-3- oxopropanenitriles with diazo compounds and tandem cyclization leading to hydrogenated azepino[3,2,1-hi]indoles,
Chem. Commun. 2016, 52, 14117-14120.
14. Yu, K.; Liang, Y.; Li, B.; Wang, B.* Rh(III)-catalyzed synthesis of indole derivatives from pyrimidyl-substituted anilines and diazo compounds,
Adv. Synth. Catal. 2016, 358, 661-666.
15. Xie, W.; Li, B.; Wang, B.* Rh(III)-catalyzed C7-thiolation and selenation of indolines,
J. Org. Chem. 2016, 81, 396-403.
16. Yang, D.; Tang, Y.; Song, H.; Wang, B.* Synthesis, structures, and norbornene polymerization behavior of palladium complexes bearing tridentate o-aryloxide-N-heterocyclic carbene ligands,
Organometallics 2016, 35, 1392-1398.
17. Zhou, T.; Li, L.; Li, B.; Song, H.; Wang, B.* Ir(III)-catalyzed oxidative coupling of NH isoquinolones with benzoquinone,
Org. Lett. 2015, 17, 4204-4207.
18. Liu, B.; Li, B.; Wang, B.* Ru(II)-catalyzed amidation reactions of 8-methylquinolines with azides via C(sp3)-H activation,
Chem. Commun. 2015, 51, 16334-16337.
19. Shi, L.; Yu, K.; Wang, B.* Regioselective synthesis of multisubstituted isoquinolones and pyridones via Rh(III)-catalyzed annulation reactions,
Chem. Commun. 2015, 51, 17277-17280.
20. Li, R.; Hu, Y.; Liu, R.; Hu, R.; Li, B.; Wang, B.* Ruthenium(II)-catalyzed oxidative annulation reactions of aryl imidazolium salts via NHC-directed C–H activation,
Adv. Synth. Catal. 2015, 357, 3885-3892.
21. Li, B.*; Yang, J.; Xu, H.; Song, H.; Wang, B.* Rhodium(III)-catalyzed C–H activation and annulation with 1-alkynylphosphine sulfides: A mild and regioselective access for the synthesis of bulky phosphine ligands,
J. Org. Chem. 2015, 80, 12397-12409.
22. Shu, Z.; Li, W.*; Wang, B.* Pd/C-catalyzed synthesis of isoquinolones via C-H activation,
ChemCatChem 2015, 7, 605-608.
23. Li, M.; Song, H.; Wang, B.* Synthesis, structures, and norbornene polymerization behavior of N-heterocyclic carbene-sulfonate ligated palladacycles,
Organometallics 2015, 34, 1969-1977.
24. Yang, D.; Tang, Y.; Song, H.; Wang, B.* o-Aryloxide-N-heterocyclic carbenes: efficient synthesis of the proligands and their p-cymene ruthenium complexes,
Organometallics 2015, 34, 2012-2017.
25. Liang, Y.; Yu, K.; Li, B.; Xu, S.; Song, H.; Wang, B.* Rh(III)-catalyzed synthesis of 1-aminoindole derivatives from 2-acetyl-1-arylhydrazines and diazo compounds in water,
Chem. Commun. 2014, 50, 6130-6133.
26. Wang, N.; Li, R.; Li, L.; Xu, S.; Song, H.; Wang, B.* Rhodium(III)-catalyzed intermolecular amidation with azides via C(sp3)-H functionalization,
J. Org. Chem. 2014, 79, 5379-5385.
27. Xie, W.; Yang, J.; Wang, B.*; Li, B.* Regioselective ortho olefination of aryl sulfonamide via rhodium-catalyzed direct C–H bond activation,
J. Org. Chem. 2014, 79, 8278-8287.
28. Xie, W.; Li, B.; Xu, S.; Song, H.; Wang, B.* Palladium-catalyzed direct dehydrogenative annulation of ferrocenecarboxamides with alkynes in air,
Organometallics 2014, 33, 2138-2141.
29. Ma, C.; Ai, C.; Li, Z.; Li, B.; Song, H.; Xu, S.; Wang, B.* Synthesis and alkyne insertion reactions of NHC-based cyclometalated ruthenium(II) complexes,
Organometallics 2014, 33, 5164-5172.
30. Dang, L.; Song, H.; Wang, B.* Synthesis, structures, and norbornene polymerization behavior of o-aryloxide-substituted NHC-ligated σ, π-cycloalkenyl palladium complexes,
Organometallics 2014, 33, 6812-6818.
31. Dang, L.; Guo, J.; Song, H.; Liu, B.; Wang, B.* Synthesis, structures, and norbornene polymerization behavior of C(sp3), N-chelated palladacycles bearing o-aryloxide-N-heterocyclic carbene ligands,
Dalton Trans. 2014, 43, 17177-17183.
32. Li, B.*; Wang, N.; Liang, Y.; Xu, S.; Wang, B.* Ruthenium-catalyzed pyrrole synthesis via oxidative annulation of enamides and alkynes,
Org. Lett. 2013, 15, 136-139.
33. Wang, N.; Li, B.*; Song, H.; Xu, S.; Wang, B.* Investigation and comparison of the mechanistic steps of the [Cp*MCl2]2 (Cp* = C5Me5, M = Rh, Ir)-catalyzed oxidative annulation of isoquinolones with alkynes, Chem. Eur. J. 2013, 19, 358-364.
34. Li, B.*; Ma, J.; Xie, W.; Song, H.; Xu, S.; Wang, B.* Regioselective C2 oxidative olefination of indoles and pyrroles through cationic rhodium(III)-catalyzed C-H bond activation,
Chem. Eur. J. 2013, 19, 11863-11868.
35. Li, B.*; Ma, J.; Xie, W.; Song, H.; Xu, S.; Wang, B.* Ruthenium-catalyzed regioselective C2 alkenylation of indoles and pyrroles via C?H bond functionalization,
J. Org. Chem. 2013, 78, 9345-9353.
36. Tan, X.; Li, B.; Xu, S.; Song, H.; Wang, B.* Synthesis, reactivities, and catalytic properties of iodo-bridged polymeric iridium complexes with flexible carbon chain-bridged bis(tetramethylcyclopentadienyl) ligands, Organometallics 2013, 32, 3253-3261.
37. Li, B.*; Ma, J.; Wang, N.; Feng, H.; Xu, S.; Wang, B.* Ruthenium-catalyzed oxidative C-H bond olefination of N-methoxybenzamides using an oxidizing directing group,
Org. Lett. 2012, 14, 736-739.
38. Li, B.*; Feng, H.; Wang, N.; Ma, J.; Song, H.; Xu, S.; Wang, B.* Ruthenium-catalyzed oxidative coupling/cyclization of isoquinolones with alkynes through C-H/N-H activation: Mechanism study and synthesis of dibenzo[a,g]quinolizin-8-one derivatives,
Chem. Eur. J. 2012, 18, 12873-12879.
39. Kong, Y.; Xu, S.; Song, H.; Wang, B.* Synthesis, structures, and norbornene ROMP behavior of o-aryloxide-N-heterocyclic carbene p-cymene ruthenium complexes,
Organometallics 2012, 31, 5527-5532.
40. Li, B.*; Feng, H.; Xu, S.; Wang, B.* Ruthenium-catalyzed isoquinolone synthesis through C–H activation using an oxidizing directing group,
Chem. Eur. J. 2011, 17, 12573-12577.
41. Kong, Y.; Wen, L.; Song, H.; Xu, S.; Yang, M.; Liu, B.; Wang, B. Synthesis, structures, and norbornene polymerization behavior of aryloxide-N-heterocyclic carbene ligated palladacycles,
Organometallics 2011, 30, 153-159.
42. Chen, D.; Zhang, C.; Xu, S.; Song, H.; Wang, B. Reactions of trinuclear ruthenium complex derived from 3-(2-pyridyl)indene with diphenylacetylene and phenylacetylene: Insertion of alkynes into the Ru-C bond, Organometallics 2011, 30, 676-683.
43. Kong, Y.; Cheng, M.; Ren, H.; Xu, S.; Song, H.; Yang, M.; Liu, B.; Wang, B. Synthesis, structures, and norbornene polymerization behavior of bis(aryloxide-N-heterocyclic carbene) nickel complexes,
Organometallics 2011, 30, 1677-1681.
44. Tan, X.; Li, B.; Xu, S.; Song, H.; Wang, B. Trinuclear and tetranuclear ruthenium carbonyl clusters derived from indenylphosphines: C-H and C-P bonds cleavage,
Organometallics 2011, 30, 2308-2317.
45. Zhang, C.; Li, B.; Song, H., Xu, S.; Wang, B. Reactions of unsymmetrically substituted N-heterocyclic carbenes with Ru3(CO)12,
Organometallics 2011, 30, 3029-3036.
46. Chen, D.; Zhang, X.; Xu, S.; Song, H.; Wang, B. Pyridyl-substituted indenyl ruthenium complexes: Synthesis, structures, and reactivities, Organometallics 2010, 29, 3418-3430.
47. Li, M.; Song, H.; Xu, S.; Wang, B. Alkyne-functionalized zirconocene complexes: synthesis, structures, and reactivities,
Organometallics 2010, 29, 6092-6096.
48. Kong, Y.; Ren, H.; Xu, S.; Song, H.; Liu, B.; Wang, B.* Synthesis, structures and norbornene polymerization behavior of bis(aryloxide-N-heterocyclic carbene) palladium complexes,
Organometallics 2009, 28, 5934-5940.
49. Luo, S.; Zhao, X.; Mu, B.; Song, H.; Xu, S.; Wang, B.* Diels-Alder reactions of benzyne with indenyl and fluorenyl ruthenium complexes,
Organometallics 2009, 28, 4602-4605.
50. Luo, S.; Shen, B.; Li, B.; Song, H.; Xu, S.; Wang, B.* Synthesis, structures and polymerization catalytic properties of doubly bridged biscyclopentadienyl dinuclear (μ-oxo) titanium complexes, Organometallics 2009, 28, 3109-3112.
51. Xu, K.; Li, B.; Xu, S.; Song, H.; Wang, B.* Reactions of dihydrooctamethyl-s-indacene and 1,2,3,4,7-pentamethylindene with Ru3(CO)12: Intramolecular sp3 C?H activation,
Organometallics 2009, 28, 4438-4442.
52. Zhang, C.; Zhao, Y.; Li, B.; Song, H.; Xu, S.; Wang, B.* The intramolecular sp2 and sp3 C-H bond activation of (p-cymene)ruthenium(II) N-heterocyclic carbene complexes,
Dalton Trans. 2009, 5182-5189.
53. Zhang, C.; Luo, F.; Cheng, B.; Li, B.; Song, H.; Xu, S.; Wang, B.* Reactions of indenyl-functionalized imidazolium salts and N-heterocyclic carbenes with Ru3(CO)12,
Dalton Trans. 2009, 7230-7235.
54. Luo, X.; Zhao, X.; Xu, S.; Wang, B.* The exo-substituted ?4-cyclopentadiene CpCo(I) complexes: A new kind of ATRP catalysts and the actual catalyst for the Cobaltocene-catalyzed ATRP,
Polymer 2009, 50, 796-801.
55. Zhao, X.; Xu, S.; Wang, B.* Controlled/“living” radical polymerization of methyl methacrylate catalyzed by CpCo(I) complexes conveniently generated from cobaltocene in situ, Polymer 2009, 50, 2258-2263.
56. Luo, X.; Zhuang, Y.; Zhao, X.; Zhang, M.; Xu, S.; Wang, B.* Controlled/living radical polymerization of styrene catalyzed by cobaltocene, Polymer 2008, 49, 3457-3461.
57. Chen, D.; Guo, J.; Xu, S.; Song, H.; Wang, B.* Reactions of Si-H-functionalized cyclopentadienes with metal carbonyls,
Organometallics 2007, 26, 4212-4219.
58. Wang, B.; Li, M.; Xu, S.; Song, H.; Wang, B.* A general synthetic route to 6,6-substituted- 6H-dibenzo[b,d]pyrans from dibenzofuran,
J. Org. Chem. 2006, 71, 8291-8293.
59. Li, B.; Wang, B.*; Xu, S.; Zhou, X.; Song, H. Reactions of CpArCHCHArCp with Ru3(CO)12: An unexpected cleavage of bridging C?C bond and coupling of the two cyclopentadienyl rings to fulvalene diruthenium complexes,
Organometallics 2006, 25, 1158-1166.
60. Chen, D.; Li, Y.; Wang, B.*; Xu, S.; Song, H. Reactions of pyridyl side-chain- functionalized cyclopentadienes with metal carbonyl: intramolecular C-H Activation of pyridine,
Organometallics 2006, 25, 307-310.
61. Wang, B.*; Mu, B.; Deng, X.; Cui, H.; Xu, S.; Zhou, X.; Zou, F.; Li, Y.; Yang, L.; Li, Y.; Hu, Y. Synthesis and structures of cycloalkylidene-bridged cyclopentadienyl metallocene catalysts: effects of the bridges of ansa-metallocene complexes on the catalytic activity for ethylene polymerization,
Chem. Eur. J. 2005, 11, 669-679.
62. Wang, B.*; Mu, B.; Chen, D.; Xu, S.; Zhou, X. Diels-Alder reactions of benzyne with indenyl iron complexes,
Organometallics 2004, 23, 6225-6230.
63. Wang, B.*; Zhuang, Y.; Luo, X.; Xu, S.; Zhou, X. Controlled/“living” radical polymerization of MMA catalyzed by cobaltocene,
Macromolecules 2003, 36, 9684-9686.
64. Wang, B.*; Zhu, B.; Zhang, J.; Xu, S.; Zhou, X.; Weng, L. Reactions of doubly bridged biscyclopentadienes with iron pentacarbonyl,
Organometallics 2003, 22, 5543-5555.
65. Wang, B.*; Zhu, B.; Xu, S.; Zhou, X. Reactions of doubly bridged biscyclopentadienes with molybdenum (tungsten) carbonyl,
Organometallics 2003, 22, 4842-4852.
66. Xu, S.; Deng, X.; Wang, B.*; Zhou, X.; Yang, L.; Li, Y.; Hu, Y. Ethylene polymerizations with cycloalkylidene-bridged cyclopentadienyl metallocene catalysts,
Macromol. Rapid Commun. 2001, 22, 708-709.
67. Zhang, Y.; Wang, B.*; Xu, S.; Zhou, X. Unexpected formation of the ruthenium carbonyl cluster with a trigonal-bipyramidal Ge2Ru3 core accompanied by loss of germanium methyl groups,
Organometallics 2001, 20, 3829-3932.

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