曹利平
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男
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birth
1111-11-11
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2019-12-30
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618
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chcaoliping@nwu.edu.cn
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中共党员
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化学与材料科学学院,
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汉
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未知
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在职
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超分子化学领域：大环分子的合成与功能化应用。
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2014-06-16
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2034-06-16
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教师网页：https://faculty.nwu.edu.cn/LipingCao/zh_CN/index.htm曹利平，本科（2006年，应用化学）和博士（2011年，有机化学）毕业于华中师范大学化学学院；2011年-2014年在美国马里兰大学从事博士后研究；2014年以人才引进加入西北大学化学与材料科学学院，任教授、博导。获华中师范大学优秀博士论文（2011年），入选西北大学青年学术骨干（2015年）、陕西省青年人才项目（2016年）、Thieme Chemistry Journals Award（2020年）、以及教育部霍英东青年教师基金（2020年）。主持包括国家自然科学基金面上项目和陕西省自然科学基金面上项目等。主要从事大环分子的设计合成与功能化，实现了水相高强度分子识别、基于主客体荧光功能材料、新型水溶性大环分子的合成与功能化应用等方面的研究工作；迄今以第一或通讯作者发表论文30余篇。学习和工作经历：2014年-今：教授，博导，西北大学，化学与材料科学学院。2017年-2018年：国家公派访问****，美国犹他大学，化学系。　2011年-2014年：博士后，美国马里兰大学，化学与生物化学系。2006年-2011年：理学博士，华中师范大学，农药与化学生物学教育部重点实验室。2002年-2006年：学士，华中师范大学，化学学院。 获得的荣誉：2020年：教育部霍英东高校青年教师基金2020年：Thieme Chemistry Journals Award2016年：陕西省青年人才项目2015年：西北大学优秀青年学术骨干计划研究兴趣：1、新颖大环分子的合成及其功能化应用研究；2、基于分子识别的刺激响应超分子组装体系的建立；3、超分子框架材料的构筑与性质研究、功能探索。 代表性科研成果：独立工作： 19. Duan, H.; Li, Y.; Li, Q.; Wang, P.; Liu, X.; Cheng, L.; Yu, Y.; Cao, L.* Host-Guest Recognition and Fluorescence of a Tetraphenylethene-Based Octacationic Cage. Angew. Chem., Int. Ed. 2020, 59, 10101-10110. (SCI, IF = 12.1, 一区) 18. Wang, P.; Miao, X.; Meng, Y.; Wang, Q.; Wang, J.*; Duan, H.; Li, Y.; Li, C.; Liu, J.; Cao, L.* Tetraphenylethene-Based Supramolecular Coordination Frameworks with Aggregation-Induced Emission for Artificial Light-Harvesting System. ACS Appl. Mater. & Interfaces 2020, 12, 22630-22639.. (SCI, IF = 8.5, 一区) 17. Li, Y.; Qin, C.; Li, Q.; Wang, P.; Miao, X.; Jin, H.; Ao, W.; Cao, L.* Supramolecular Organic Frameworks with Controllable Shape and Aggregation-Induced Emission for Tunable Luminescent Materials Through Aqueous Host-Guest Complexation. Adv. Opt. Mater. 2020, **. (SCI, IF = 7.1, 一区) 16. Nian, H.; Li, A.; Li, Y.; Cheng, L.; Wang, L.; Xu, W.; Cao, L.* Tetraphenylethene-Based Tetracationic Dicyclophanes: Synthesis, Mechanochromic Luminescence, and Photochemical Reaction. Chem. Commun.2020, 56, 3195-3198. (SCI, IF = 6.1, 一区)15. Li, C.; Nian, H.; Dong, Y.*; Li, Y,; Zhang, B.; Cao, L.* Tetraphenylethene-Based Platinum(II) Bis-Triangular Dicycles with Tunable Emissions. Inorg. Chem. 2020, 59, 5713-5720. (SCI, IF = 4.8, 一区)14. Li, C.; Zhang, B.; Dong, Y.*; Li, Y.; Wang, P.; Yu, Y.; Cheng, L.; Cao, L.* A Tetraphenylethene-Based Pd2L4Metallacage with Aggregation-Induced Emission and Stimuli-Responsive Behavior. Dalton Trans. 2020, 49, 8051-8055. (SCI, IF = 4.1, 二区) 13. Li, Y.; Dong, Y.; Cheng, L.; Qin, C.; Nian, H.; Zhang, H.; Yu, Y.; Cao, L.* Aggregation-Induced Emission and Light-Harvesting Function of Tetraphenylethene-Based Tetracationic Dicyclophane. J. Am. Chem. Soc. 2019, 141, 8412-8415.(SCI, IF = 14.1, 一区) 12. Cao, L.*; Wang, P.; Miao, X.; Duan, H.; Wang, H.; Dong, Y.; Ma, R.; Zhang, B.; Wu, B.; Li, X.; Stang, P. J. Diamondoid Frameworks via Supramolecular Coordination: Structural Characterization, Metallogel Formation, and Adsorption Study. Inorg. Chem. 2019, 58, 6268-6275. (SCI, IF = 4.8, 一区) 11. Cheng, L.; Zhang, H.; Dong, Y.; Zhao, Y.; Yu, Y.; Cao, L.* Tetraphenylethene-Based Tetracationic Cyclophanes and Their Selective Recognition for Amino Acids and Adenosine Derivatives in Water. Chem. Commun. 2019, 55, 2372 - 2375.(SCI, IF = 6.6, 一区) 10. Zhang, B.; Dong, Y.; Li, J.; Yu, Y.; Li, C.; Cao, L.* Pseudo[n,m]rotaxanes of Cucurbit[7/8]uril and Viologen-Naphthalene Derivative: A Precise Definition of Rotaxane. Chin. J. Chem. 2019, 37, 262-275. (SCI, IF = 2.03, 三区) 9. 李亚雯; 敖宛彤; 金慧琳; 曹利平* 四苯乙烯衍生物与大环主体在主客体相互作用下的聚集诱导发光, 化学进展, 2019, 31,121-133.(国内权威综述期刊，SCI) 8. Cao, L.*; Wang, P.; Miao, X.; Dong, Y.; Wang, H.; Duan, H.; Yu, Y.; Li, X.; Stang, P. J.* Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages. J. Am. Chem. Soc. 2018, 140, 7005-7011. (SCI, IF = 14.4, 一区top) 7. Li, Y.; Dong, Y.; Miao, X.; Ren, Y.; Zhang, B.; Wang, P.; Yu, Y.; Li, B.; Isaacs, L.; Cao, L.* Shape-Controllable and Fluorescent Supramolecular Organic Frameworks through Aqueous Host–Guest Complexation. Angew. Chem., Int. Ed., 2018, 57, 729-733. (SCI, IF = 11.4, 一区top) 6. Yu, Y.; Li, Y.; Wang, X.; Nian, H.; Wang, L.; Zhao, Y.; Li, J.; Yang, X.; Liu, S.*; Cao, L.* Cucurbit[10]uril-based [2]Rotaxane: Preparation and Supramolecular Assembly-Induced Fluorescence Enhancement. J. Org. Chem.2017, 82, 5590-5596. (SCI, IF = 4.7, 二区top) 5. Wang, P.; Wu, Y.; Zhao, Y.; Yu, Y.; Zhang, M.*; Cao, L.* Crystalline Nanotubular Framework Constructed by Cucurbit[8]uril for Selective CO2 Adsorption. Chem. Commun. 2017, 53, 5503-5506. (SCI, IF = 6.5, 一区) 4. Li, J.; Zhao, Y.; Dong, Y.; Yu, Y.; Cao, L.;* Wu, B. Supramolecular Organic Frameworks of Cucurbit[n]uril-Based [2]Pseudorotaxanes in the Crystalline State. CrystEngComm, 2016, 18, 7929-7933.（前封面文章，SCI = 3.8, 二区） 3. Dong, Y.; Cao, L.* Functionalization of Cucurbit[n]uril. Progress in Chemistry,（化学进展） 2016, 28, 1039-1053.(国内权威综述期刊，SCI) 2. Li, J.; Yu, Y.; Luo, L.; Li, Y.; Wang, P.; Cao, L.*; Wu, B. Square [5]Molecular Necklace Formed from Cucurbit[8]uril and Carbazole Derivative. Tetrahedron Lett. 2016, 57, 2306-2310. (SCI, IF = 2.6, 三区) 1. Yu. Y.; Li, J.; Zhang, M.; Cao, L.;* Isaacs, L.* Hydrophobic Monofunctionalized Cucurbit[7]Uril Undergoes Self-Inclusion Complexation and Forms Vesicle-Type Assemblies. Chem. Commun. 2015, 51, 3762-3765. (SCI, IF = 6.7, 一区) 博士后期间工作： 11. Sigwalt, D.; Sekutor, M.; Cao, L.; Zavalij, P. Y.; Hostas, J.; Ajani, H.; Hobza, P.; Mlimaric-Majerski, K.*; Glaser, R.*; Isaacs, L.* Unraveling the Structure-Affinity Relationship between Cucurbit[n]urils (n = 7, 8) and Cationic Diamondoids. J. Am. Chem. Soc. 2017, 139, 3249-3258. (SCI, IF = 13, 一区top) 10. ?kalamera, ?.; Cao, L.; Isaacs, L.*; Glaser, R.;* Mlinari?-Majerskia, K.* Steric Hindrance To The Syntheses and Stabilities of 1,5- and 2,6-Naphthalene N-Permethylated Diammonium Salts. Tetrahedron, 2016, 72,1541-1546. (SCI, IF = 2.6, 三区)9. Cao, L.; Skalamera, D.; Zavalij, P. Y.; Hobza, P.*; Mlinari?-Majerski, K.*; Glaser R.*; Isaacs, L.* Influence of Hydrophobic Residues on the Binding of CB[7] toward Diammonium Ions of Common Ammonium???ammonium Distance. Org. Biomol. Chem. 2015, 13, 6249-6254. (SCI, IF = 3.5) 8. Cao, L.; ?ekutor, M.; Zavalij, P. Y.; Mlinari?-Majerski, K.*; Glaser R.*; Isaacs, L.* Cucurbit[7]uril.Guest Pair with an Attomolar Dissociation Constant. Angew. Chem., Int. Ed. 2014, 53, 988-993. (SCI, IF = 13.4, VIP paper and Poster of the frontispiece, 一区top) 7. Zhang, M.#; Cao, L.# (共同第一作者); Isaacs, L.* Cucurbit[6]Uril-Cucurbit[7]Uril Heterodimer Promotes Controlled Self-Assembly Of Supramolecular Networks And Supramolecular Micelles By Self-Sorting Of Amphiphilic Guests. Chem. Commun. 2014, 50, 14756-14759. (SCI, IF = 6.7, 一区) 6. Cao, L.; Isaacs,L.* Absolute and Relative Binding Affinity of Cucurbit[7]uril Towards A Series of Cationic Guests. Supramol. Chem. 2014, 26, 251-258. (SCI, IF = 2.1)5. ?ekutor, M.; Mol?anov, K.; Cao, L.; Isaacs, L.*; Glaser R.*; Mlinari?-Majerski, K.* Design, Synthesis, and X-ray Structural Analyses of Diamantane Diammonium Salts: Guests for Cucurbit[n]uril (CB[n]) Hosts. Eur. J. Org. Chem. 2014, 12, 2533-2542. (SCI, IF = 3.2)4. Cao, L.; Hettiarachchi, G.; Briken, V.*; Isaacs, L.* Cucurbit[7]uril Containers for Targeted Delivery of Oxaliplatin to Cancer Cells. Angew. Chem., Int. Ed. 2013, 52, 12033-12037. (SCI, IF = 13.4, 一区top) 3. Vinciguerra, B.#; Cao, L.# (共同第一作者); Cannon, J. R.; Zavalij, P. Y.; Fenselau, C.; Isaacs, L.* Synthesis and Self-Assembly Processes of Monofunctionalized Cucurbit[7]uril. J. Am. Chem. Soc. 2012, 134, 13133-12140. (SCI, IF = 11.4, 一区top) (Spotlights on Recent JACS Publications, J. Am. Chem. Soc. 2012, 134, 14265-14266.)2. Cao, L.; Isaacs, L.* Daisy Chain Assembly Formed from a Cucurbit[6]uril Derivative. Org. Lett. 2012, 14, 3072-3075. (SCI, IF = 6.3, 一区)1. Lucas, D.; Minami, T.; Iannuzzi, G.; Cao, L.; Wittenberg, J. B.; Anzenbacher, Jr. P.*; Isaacs, L.* Templated Synthesis of Glycoluril Hexamer and Monofunctionalized Cucurbit[6]uril Derivatives. J. Am. Chem. Soc. 2012, 134, 13133-12140. (SCI, IF = 11.4)博士期间工作： 6. Cao, L.; Wang, J. G.; Ding, J. Y.; Wu, A. X.*; Isaacs,L.* Reassembly Self-Sorting Triggered by Heterodimerization. Chem. Commun. 2011, 47, 8548-8550. (SCI, IF = 6.7, 一区) 5. Cao, L.; Meng, X. G.; Ding, J. Y.; Chen, Y. F.; Gao, M.; Wu, Y. D.; Li, Y. T.; Wu, A. X.*; Isaacs, L.* Nanotubular Non-Covalent Macrocycle Within Non-Covalent Macrocycle Assembly: (MeOH)(12) Encapsulated in Amolecular Clip Cyclododecamer. Chem. Commun. 2010, 46, 4508-4510. (SCI, IF = 6.7) 4. Cao, L.; Ding, J. Y.; Gao, M.; Wang, Z. H.; Li, J.; Wu, A. X.* Novel and Direct Transformation of Methyl Ketones or Carbinols to Primary Amides by Employing Aqueous Ammonia. Org. Lett. 2009, 11, 3810-3813. (SCI, IF = 6.3) (highlighted by Organic Chemistry Portal: http://www.organic-chemistry.org/abstracts/lit2/649.shtm; ChemInform, 2010, 41, DOI:10.1002/chin.) 3. Cao, L.; Ding, J. Y.; Wang, J. G.; Chen, Y.; Gao, M.; Xue, W. J.; Wu, A. X.* Colorimetric Fluoride Sensor Based on a Bisthiourea Functionalized Molecular Clip. Synlett 2010, 2553-2556. (SCI, IF = 2.8) 2. Cao, L.; Ding, J. Y.; Yin, G. D.; Gao, M.; Li, Y. T.; Wu, A. X.* Thioglycoluril as a Novel Organocatalyst: Rapid and Efficient alpha-Monobromination of 1,3-Dicarbonyl Compounds. Synlett. 2009, 1445-1448. (SCI, IF = 2.8) 1. 曹利平; 高蒙; 李义涛; 丁娇阳; 吴彦东; 祝艳平; 佘能芳; 吴安心* 二元组装体集群时的高选择性杂化重组行为. 中国科学B辑: 化学, 2009, 39, 343-349. (国家核心期刊) 参与编写专著 1. Cao, L.; Zhao, J.; Yang, D.; Yang, X.-J.; Wu, B.* Hydrogen Bonding-Driven Anion Recognition in Hydrogen Bonded Supramolecular Structures. Springer-Verlag Berlin Herdelberg, 2015, DOI:10.1007/978-3-662-45756-6_5. *通讯作者（Corresponding author）
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