李天铎教授 泰山****
博士生导师
山东省轻工助剂重点实验室主任
化学与制药工程学院院长
办公室：第一教学楼B座309
电话(O)： (L)：
Email： litianduo@163.com
教育背景
1985 山东大学 学士学位
1988 山东大学 硕士学位
1999 四川大学 博士学位
研究兴趣
1. 胶原蛋白质定量化改性及其功能材料
2. 聚氨酯分子结构调控及其新型材料
3. 超分子组装与高分子功能膜材料
4. 皮革精细化学品研发
主持项目
1. 环氧硅氧烷与胶原多肽界面接枝反应及梯度模的制备研究(**)，国家自然科学基金项目, 2014-2017
2. 低分散度聚氨酯的合成研究(**)，国家自然科学基金项目,2012-2015
3. 氟、硅嵌段共聚物的合成及其功能梯度膜的研究(**)，国家自然科学基金项目（已结题）
4. 二乙基-2, 3-环氧丙基-[3-(甲基二甲氧基)]硅丙基氯化铵的合成(208073)，教育部重点项目（已结题）
5. 高性能汽车内饰革的研发及产业化(2004BA320B02-1)，“十五”国家科技攻关计划项目（已结题）
6. 由制革下脚料研制蛋白涂饰剂(02BS109, 2005BS08003)，山东省博士基金(已结题)
7. 季铵型聚硅氧烷的合成及性能研究(Y2004B04)，山东省自然科学基金(已结题)
发表论文
2017年
4. Tao Sun, Qingfen Niu*, Zongrang Guo, Tianduo Li. A simple highly sensitive and selective turn-onfluorescent chemosensorfor the recognition of Pb²⁺. Tetrahedron Lett., 2017, 58: 252–256.
3. Shanshan Zhang, Qingfen Niu*, Linxin Lan,Tianduo Li*. Novel oligothiophene-phenylamine Based Schiff base as a fluorescentchemosensor for the dual-channel detection of Hg²⁺ and Cu²⁺withhigh sensitivity and selectivity. Sensor. Actuat. B-Ch., 2017, 240: 793–800 .
2. Yu Liu, Haixia Liu*, Qing Zhang and Tianduo Li. Adjusting the proportions of {0001} facets And high-index facets of ZnO hexagonal prisms andtheir photocatalytic activity. RSC Adv., 2017, 7: 3515-3520.
1. Lei Yue, Jing Li, Wei-Yue Zhu, Jing Xu, Tian-Duo Li. Fabrication, and characterization of polydimethylsiloxane/glycidol-grafted gelatin film. J. Coat. Technol. Res, 2017, 14(1): 225-232.
2016年
22.Kai-Rui Fu, Ji-Kang Yao, Qiang Xiao, Hai-Xia Liu, Tian-Duo Li*, Takashi Tatsumiand Jin-Gui Wang*. A low-deactivation-rate Lewis acid zeolite preparedin an alkali metal ion-containing system for alkene Epoxidation. RSC Adv., 2016, 6: 98514-98519.
21. Xingxing Wu, Qingfen Niu*, Tianduo Li, Yuezhi Cui, Shanshan Zhang. A highly sensitive，selective and turn-off fluorescent sensor based on phenylamine-oligothiophene derivative for rapid detection of Hg²⁺. J. Lumin., 2016, 175: 182–186.
20.Ai-Qing Wang, Yue-Zhi Cui*, Fu-Rong Tao, Dong-hao Wang, Tian-Duo Li, Jin-Ku Xu. Preparation of a functionalized glass sensor and its sensing performancesfor nitroaromatics. Thin Solid Films. 2016, 598: 299–304.
19.Qingfen Niu*, XingxingWu, Tianduo Li, Yuezhi Cui, Shanshan Zhang, Xiaoyan Li. Highly selective, sensitive and fast-responsive fluorescent sensor for Hg²⁺. Spectro. Acta. A., 2016, 163: 45–48.
18. Chuanguang Zhang, Xiaodeng Yang, Shijie Wang, Junying Li, Yuezhi Cui, Tianduo Li. Interaction Between GMAC-m-CS and Surfactants: Surface Tension and Conductivity Methods. J. Disper. Sci. Techno., 2016, 37: 1502–1510.
17. Runhui Yu, Yan Li, Furong Tao, Yuezhi Cui*, Weiqiang Song, andTianduo Li. A novel double-layer electrospun nanofibrousmembrane sensor for detecting nitroaromatic Compounds. J. Mater. Sci., 2016, 51: 10350–10360.
16. Dong-Hao Wang, Yue-Zhi Cui?, Fu-Rong Tao, Qing-Fen Niu, Tian-Duo Li, He Xu. A novel film of conjugated polymergrafted onto gelatin for detectingnitroaromatics vapor with excellent inhibiting photobleaching.Sensor. Actuat. B-Ch., 2016, 255: 319–326 .
15. Aiqing Wang, Yuezhi Cui*, Furong Tao, Caihong Gu, Shijie Wang, and Tianduo Li. Fluorescent Film Sensor for Nitroaromatics Prepared via Graftinga Conjugated Polymer on a Glass Slide Surface. Russ. J. Phys.Chem. A+,2016, 90(2): 399–405.
14. Qiuchen Su, Qingfen Niu?, Tao Sun, Tianduo Li. A simple fluorescence turn-on chemosensor based on Schiff-basefor Hg²⁺-selective detection.Tetrahedron Lett., 2016, 57: 4297–4301.
13. Qingfen Niu, Xingxing Wu, Tianduo Li, Yuezhi Cui, Shanshan Zhang, Qiuchen Su. A Phenylamine-Oligothiophene-Based Fluorescent Chemosensorfor Selective Detection of Hg(II). J. Fluoresc., 2016, 26: 1053–1058.
12. Ling Lu, Pengfei Yang, Yongzhi Liu, Junying Li, Zhiliang Zhang and Tianduo Li. Kinetics and thermodynamics of the blocking reaction of several aliphatic isocyanates. J. Macromol. Sci. A., 2016, 53(9)：574–578.
11. 步红红, 焦燕妮, 兰文军, 庄晓丽, 戴肖南, 李天铎*. 盐酸胍/ 玉型胶原分散体系的流变性. 高等学校化学学报，2016，6：1189-1195.
10. 张华勇，成金勇，卢红旺，夏咏梅，李天铎*. 不饱和聚酯树脂在皮革样品制备中的应用研究.中国皮革, 2016, 45(5): 28-35.
9. Xiwen Wu, Libin Liu, Wenyuan Fang, Congde Qiao, Tianduo Li. Effect of hard segment architecture on shape memory propertiesof polycaprolactone-based polyurethane containing azobenzene. J. Mater. Sci., 2016, 51: 2727–2738.
8. Xingxing Wu, Qingfen Niu &Tianduo Li. Novel one-pot synthesis of symmetrically substituted ureas. Synthetic Commun., 2016, 46(16): 1364–1369.
7. Lei Yue, Jing Li, Yunqiao Ding, Jing Xu &Tianduo Li. Heterogeneous Reaction Kinetics Between MonoEpoxy Terminated Polydimethylsiloxane and Gelatin: Effect of Material Ratio and Temperature. International Journal of Polymer Analysis and Characterization. Int. J. Polym. Amal. Ch., 2016, 21(3): 198-206.
6. Jinli Pang, Guowei Zhou?, Ruirui Liu, Tianduo Li. Esterification of oleic acid with methanol by immobilized lipaseon wrinkled silica nanoparticles with highly ordered, radiallyoriented mesochannels. Mat. Sci. Eng. C-Mater., 2016, 59: 35–42.
5. Xiaodeng Yang^?, Congde Qiao, Yan Li, Tianduo Li. Dissolution and resourcfulization of biopolymers in ionic liquids. React. Funct. Polym., 2016, 100: 181–190.
4. Qingfen Niu^*, XingxingWu, Shanshan Zhang, Tianduo Li, Yuezhi Cui, Xiaoyan Li. A highly selective and sensitivefluorescent sensor for the rapid detectionof Hg²⁺based on phenylamine-oligothiophene derivative. Spectro. Acta. A., 2016, 153: 143–146.
3. 王世杰*，黄雯，王磊，崔月芝，李天铎. pH响应性高分子的合成及表征研究进展. 高分子通报，2016，4：61-79.
2. Huali Li , Tianduo Li, Haixia Liu *, Baibiao Huang , Qing Zhang. Hierarchical flower-like nanostructures of anatase TiO₂nanosheets dominated by {001} facets. J. Alloy. Compd., 2016, 657 : 1-7.
1. Xingxing Wu, Qingfen Niu^*, Tianduo Li ^*. A novel urea-based “turn-on” fluorescent sensor for detection of Fe³⁺/F^?ions with high selectivity and sensitivity. Sensor. Actuat. B., 2016 , 222: 714–720.
2015年
13.Yun-qiao Ding^*, Yue-zhi Cui, Tian-duo Li. New Views on the Reaction of Primary Amine and Aldehyde From DFT Study.J. Phys. Chem. A., 2015, 119：4252?4260.
12.Shanshan Zhang,Qingfen Niu, Xingxing Wu, Tianduo Li, Yuezhi Cui, Xiaoyan Li. A Fast-Responsive Fluorescent Sensor for Hg²⁺with High Selectivity and Sensitivity in Aqueous Media. J.Fluoresc., 2015, 25:1543–1548.
11.Ting Li, Yunqiao Ding, Libin Liu,* Jian Liu, Wenyuan Fang, Yu Xiang and Tianduo Li. Facile fabricationof multifunctional perfluoroalkylfunctionalized graphene hydrogel via asynchronous reduction and grafting strategy. J. Mater. Chem. A., 2015, 3, 21744–21753.
10.YunqiaoDing*, Chenglung Chen, Tian-duo Li, JinyongCheng, and Huayong Zhang. Effects of Chromium-olation Length on Crosslinking Effects Investigated by Molecular Dynamics Simulation. Soft Materials, 2015, 13: 24–31.
9.李华丽, 刘海霞, 张庆, 李天铎^?. 溶剂热法制备纳米二氧化钛及光催化活性研究. 稀有金属材料与工程，2015, 44(3): 533-537.
8.Xiaodeng Yang, Chuanguang Zhang, Congde Qiao, Xueli Mu, Tianduo Li^?, Jinku Xua, Lei Shi, Dongju Zhang^?. A simple and convenient method to synthesize N-[(2-hydroxyl)-propyl-3-trimethy
lammonium] chitosan chloride in an ionic liquid. Carbohyd. Polym. 2015, 130: 325–332.
7. Jian Liu, Libin Liu*, Xiwen Wu, Xiaokai Zhang,Tianduo Li*. Environmentally friendly synthesis of graphene-silver composites with surface-enhanced Raman scattering and antibacterial activity via reduction with L-ascorbic acid/water vapor. New J. Chem, 2015, 39(7):5272-5281.
6. Junying Li,Pengfei Yang,Zuoliang Sha*, Tianduo Li,Yaming Liu. Synthesis and Micellization of Organosilicon Gemini Quaternary Ammonium Surfactants. J.Surfact.Deterg., 2015, 18(1): 155-161.
5.Shuxia Liu,Xiaodeng Yang,Shijie Wang,Xiaonan Dai,Tianduo Li*&Yuexia Wang. Interaction Between EPTACModified Gelatin and Surfactants: Surface Tension and Conductivity Methods. J.Disper.Sci.Technol., 2015,36(5):731-739.
4. Huali Li, Haixia Liu, QingZhang, Chengfei Wang, Tianduo Li *. Synthesis and photocatalytic activity of ring-like anatase TiO₂with {001} facts exposed. Ceram. Int., 2015，41: 8717-8722.
3. NaZhang, LeiShi , TingtingYu, TianduoLi*, WeiHua, CongLin. Synthesis and characterization of pure STW-Zeotype germanosilicate, Cu- and Co-substituted STW-zeotype materials.J .Solid. State. Chem., 2015，225: 271–277.
2. Zhangqing, Liuhaixia, Lihuali, Li Tianduo*. Solvthermal Synthesis and photocatalytic properities of NiO ultrathin nanosheets with porous structure. Appl. Surf. Sci., 2015，328: 525-530.
1. Bin Sun , Guowei Zhou , Yan Zhang , Ruirui Liu , Tianduo Li. Photocatalytic properties of exposed crystal surface-controlled rutile TiO₂nanorod assembled microspheres. Chem. Eng. J., 2015，264: 125–133.
2014 年
10. Huayong Zhang,yongmei Xia,Lei Shi and Tianduo Li*. Characterization of Leather Structure via Metallographic Sample Preparation. J . Am.Leather. As., 2014, 109(1): 1-7.
9. Xiaodeng Yang*, Huina Meng, TianduoLi, LeiShi,YanLi, Guiying Xu. CaCO₃crystallization in HPCHS/CTAB mixed solutions. Powder Technol., 2014, 256: 272-278.
8. Xiaodeng Yang*,Huina Meng,Tianduo Li,Congde Qiao,Guiying Xu. Viscometric Properties of Carboxy methylchitosan Solutions. J.Macromol.Sci.B, 2014, 53:1128-1136.
7. Jing Xu, Yongmei Xia, Congde Qiao, Tianduo Li*. Solid-State Structure of Gelatin-PDMS Polymer: Effect of Electrostatic and Hydrophobic Interactions. Colloids Surf.B., 2014, 123:945-950.
6. Minnan Zhao, Guowei Zhou, Lei Zhang, Xiuyan Li, Tianduo Liand Fangfang Liu. Fabrication and photoactivity of a tunable-void SiO₂-TiOcore-shell structure on modified SiO₂nanospheres by grafting an amphiphilic diblock copolymer using ARGET ATRP?. Soft Matter, 2014, 10, 1110-1120.
5. Qiang Shi, Yue-Zhi Cui , Fu-Rong Tao, Yong-Tao Wang, Jun-Ying Li, Tian-Duo Li. Fluorescent film sensor for nitroaromatics via monolayer assembly of arylethenyl-branched s-triazine on glass slide surfaces. Opt. Mater. 2014, 37: 11-17.
4. YuLong Li, CongDe Qiao, Lei Shi, QingWei Jiang,TianDuo Li*. Viscosity of Collagen Solutions: Influence of Concentration, Temperature, Adsorption and Role of Intermolecular Interactions.J. Macromol. Sci B., 2014, 53(5): 893-901.
3. Yinghua Gong, Pengfei Yang, Furong Tao, Datong Zhang, Xiaofei Guo , Tianduo Li*.Int. J. Polym. Anal.Charact., 2014,19(2):107-114.
2. Jing Xu, Zhen Xu, Congde Qiao, Tianduo Li*. Effect of anionic surfactants on grafting density of gelatinmodifiedwith PDMS-E. Colloid Surf. B., 2014, 114, 310-315.
1. QingweiJiang,JingXu,TianduoLi*,CongdeQiaoandYulongLi.
Synthesisandantibacterialactivitiesofquaternaryammoniumsaltofgelatin.J.Macromol.SciB.,2014, 53,133-141.
2013年
12. Yang Sang, Pengfei Yang, Tianduo Li*. Selective derivatization of oxime-blocked tolylene-2,4-diisocyanate.CnineseChem. Lett., 2013, 24(11): 1019-1022
11. Jing Xu, Tianduo Li*, Furong Tao, Yuezhi Cui, Yongmei Xia. Structure Evolution of GelatinParticles Induced bypHand Ionic Strength. Microsc. Res. Tec., 2013, 76, 272-281.
10. Peng Fei Yang, Tian Duo Li, Jun Ying Li. Catalytic kinetics and mechanism transformation of Fe(acac)₃on the urethane reaction of 1,2-propanediol with phenyl isocyanate. Int.J.Chem. Kinet., 2013, 45(10): 623-628.
9. Peng Fei Yang, Tian Duo Li.Urethane reaction kinetics of butanediols catalyzed by Zr(acac)₄. J. Appl . Polym.. Sci., 2013, 129(5): 2399-2403.
8. Peng Fei Yang, Yan Hong Yu, Tian Duo Li, Meng Zhang. Kinetic studies on the urethanereaction of propanediol with isocyanate in nitrogenous solvents. Int. J. Polym. Anal. Charact., 2013, 18(1): 57-63.
7. Yanyan Wang, Linbin Liu, Congde Qiao, Tianduo Li*. Stimuli-
Responsive Films Based on N-Substituted Polyurethane with Different Alkyl Length. Aust. J. Chem., 2013, 66, 1361–1369.
6. Linbin Liu, Xiwen Wu,Tianduo Li. Novel polymer electrolytes based on cationic polyurethane with different alkylchainlength. J. Power Sources, 2014, 249, 397-404.
5. Huayong Zhang, yongmei Xia, Jinyong CHeng, Lei Shi, Tianduo Li*. A Novel Technique forGetting Leather SectionImage Based on Metallographic Sample Preparation. J.Am. Leather Chem.As., 2013; 108 (5): 166.
4. Shunping Wang, Xiaodeng Yang, Qingquan Bai, Tianduo Li*. In Situ FT-IR Studies of the Zirconium (IV) Acetylacetonate Catalyzed Urethane Reaction of Butanediols. Int. J. Polym.Anal. Character., 2013, 18, 119-125.
3.Shunping Wang, Qingquan Bai, Tianduo Li*. In Situ Monitoring of Selective Catalysts onUrethane Formation by FT-IR Spectroscopy. Int. J. Polym. Anal. Charact., 2013, 18, 146–153.
2. Shunping Wang, Qingquan Bai, Tianduo Li*. Ferric Acetylacetonate Catalyst on the Urethane Reaction of PhenylIsocyanate and 1,2-Propyleneglycol: A Study of Kinetics, Thermodynamics, andMechanism with In Situ Ft-IR Spectroscopy. Int. J. Polym. Anal. Charact., 2013, 18, 163–171.
1. Jing Xu, Tianduo Li*, Qiangwei Jiang, Congde Qiao, Jinyong Chen. Microstructure transformation of PDMS- grafted gelatinpolymers induced by SDS and SDBS. Colloid Surf. B., 2013, 103, 375-380.
2012年
12. Peng Fei Yang, Yong De Han, Tian Duo Li*, Jun Ying Li. J. Appl. Polym. Sci., 2012, 123(1): 580-584.
11.L. B. Liu, T. D. Li, M. Lee, Chem. Phys. Chem., 2012, 13, 578-582.
10.Zhang, Ling; Qiao, Congde; Ding, Yunqiao; Cheng, Jinyong;Li, Tian Duo*. J. Macromol. Sci. B., 2012, 51(4)：747-755.
9. Wang, Shijie; Yang, Pengfei; Li, Tian Duo. Gaofenzi Tongbao. 2012,2: 16-27.
8. Wu, Cuicui; Zhou, Guowei; Xu, Delan; Li, Tian Duo. Advanced Materials Research, 2012, 485: 314-317.
7. 王顺平, 杨鹏飞, 赵超, 李俊英, 李天铎*. 高分子材料科学与工程, 2012, 28:107-110.
6. Li, Junying; Zhang, Qingsi; Wang, Yan; Zhang, Wenyu;Li, Tian Duo. J. Surfactants. Deterg., 2012, 15(3):339-344.
5. Li, Guohong; Liu, Hong; Li, Tian Duo*; Wang, Jiyang. Mat.Sci. Eng., C-Mater., 2012, 32(4):627-636.
4. Wang, Chen; Li, Tian Duo; Asian J.Chem., 2012, 24(1):63-67.
3. Jing Xu, Tian-Duo Li*,Xiao-Long Tang, Cong-de Qiao, Qingwei Jiang. Colloid.Surface.B.,2012, 95: 201-207.
2. Ling Zhang, Congde Qiao, Yunqiao Ding, Jinyong Cheng,Tianduo Li*. Rheological Behavior ofGelatin/1-Allyl-3-Methylimidazolium Chloride Solutions. J. Macromol. Sci. B. 2012, 51: 747-755.
1.王顺平, 杨鹏飞, 赵超, 李俊英, 李天铎*. 高分子材料科学与工程, 2012, 28(7): 39-42.
获得专利
1. 李天铎，姜青伟，许静，唐晓龙. 伯氨基定量仪. ZL5.6
2.李天铎，唐晓龙，姜青伟，许静.伯胺基测定仪.ZL0.1
3. 许静，李天铎，夏永梅. 一种环氧聚硅氧烷改性明胶皮革涂饰剂及其制备方法. ZL9.X
4. 许静，李天铎，夏永梅. 自乳化型耐湿擦皮革顶层涂饰剂及其制备方法. ZL6.0
5. 张华勇，李天铎. 一种x射线衍射仪用简易片状样品台. ZL 5.7
6. 杨效登,王建成, 李天铎. 加热浓缩器. ZL 4.6
7. 杨效登,王建成, 李天铎，张华勇. 快速冷凝回流反应装置. ZL 0.8
8. 杨效登，王建成，李天铎. 快速冷却反应釜. ZL .1
9. 李天铎, 杨效登, 李俊英, 张华勇. 以无水强碱催化剂催化生产高纯度二甲基硅油的方法. CN6.1
10. 李俊英, 崔月芝, 李天铎, 杨效登, 石翠磊, 刘亚明. 一种叔胺基硅烷的生产工艺. CN7.2
11. 李俊英, 班青, 王世杰, 李天铎, 杨鹏飞. 一种叔胺基硅烷的制备方法. CN4.5
12. 李天铎, 张华勇, 邱书波. 一种毛细管粘度计的自动计时装置及计时方法. ZL6
13. 张华勇, 李天铎, 邱书波. 一种毛细管粘度计的自动计时装置. CN2.8.
14. 张华勇, 李天铎, 成金勇, 邱书波. 毛细管粘度计的自动计时装置. CN4.9.
15. 张华勇, 李天铎, 成金勇, 许静. 一种适用于金相显微镜观察的皮革样品制备方法. CN0.4.
16. 邱书波, 李天铎, 王晓芳, 许静, 张磊. 一种小尺寸细纤维张力自动测量装置及其方法. ZL8
17. 许静，李天铎，唐晓龙，姜青伟，一种含有聚硅氧烷，缩水甘油和季铵盐的多功能型明胶皮革涂饰剂及制备方法。CN5.4
18. 许静，李天铎，夏永梅，一种含有聚硅氧烷和季铵盐的抗菌性明胶皮革涂饰剂及制备方法，CNA
19. 许静，李天铎，唐晓龙，一种含有聚硅氧烷和缩水甘油的强疏水型明胶皮革涂饰剂及制备方法，CNA
20. 李天铎，许静，姜青伟，一种伯胺基含量准确测定方法，CNA
21. 杨效登,李天铎, 李俊英，王建成，一种二甲基乳化硅油的制备方法，ZL2013 1 **.2
22. 崔月芝，刁礼晓，李天铎，李俊英，汪永涛，一种超支化共轭聚合物及其制备方法与应用，ZL2013 1 **.X
23. 崔月芝，王栋号，王爱清，石强，李俊英，陶芙蓉，李天铎，一种均三嗪衍生物及其制备方法和应用，ZL2014 1 **.1
24 张华勇, 张志良，李天铎, 成金勇, 一种获取皮革样品截面序列图片的方法，ZL2013 1 **.8
25. 崔月芝，许鹤，宋维强，石强，李俊英，陶芙蓉，李天铎，一种均三嗪衍生物化学修饰玻璃表面传感器及其制备方法和应用，ZL2014 1 **.2
26. 张华勇,刘小建，杨效登，李天铎, 一种金相制样法获取皮革截面图片用抛光液，ZL2013 1 **.8
27. 王传举，刘利斌，吴希文，李天铎，偶氮聚氨酯多孔材料的制备方法，ZL2014 1 **.4
28. 刘利斌，党钊，王彦彦，乔从德，李天铎，徐金库，通过静电纺丝技术制备含氟的N-取代聚氨酯超疏水超疏油薄膜的方法， ZL2014 1 **.9
29. 张华勇,刘小建，李天铎, 一种获取顶伸状态皮革截面的装置及制样方法，ZL2013 1 **.9
30. 刘利斌，刘健，李天铎, 方文元，李婷，向宇，三维网状结构与石墨烯-银复合材料的绿色制备方法，ZL2014 1 **.X
奖励
1. 2011年 胶原功能材料的研究与开发，山东省高校优秀科技成果一等奖
2. 2005年 铬-铝-钛多金属鞣剂的研究，山东省科技进步二等奖
3. 2000年 CDR树脂鞣剂，淄博市科学技术进步奖二等奖
4. 2003年 由制革废料合成蛋白复鞣剂（LB)的研究 山东省科学技术奖二等奖
5. 2007年 系列有机酸碱构筑的共晶体系，山东高等学校优质科研成果一等奖
6. 2002年 由含铬下脚料和猪油制备蛋白型加酯剂，山东省技术创新优秀成果优秀论文一等奖
荣誉
新世纪百千****才工程国家级人选
享受国务院政府特殊津贴
山东省有突出贡献的中青年专家
济南市专业技术拔尖人才
济南市科技明星