赵晓明教授博士生导师
联系电话65981376Emailxmzhao08@tongji.edu.cn
专业方向有机化学办公室原新闻中心205室&化学馆103B
研究方向：有机氟化学、不对称催化及材料化学
个人介绍
2008经同济大学全球人才招聘进入同济工作，担任教授、博士生导师。
简介：男，博士，毕业于大连理工大学。1998启留学美国八年。于佛罗里达大学、南加州大学
研究方向
设计和发现新反应，并将其发展成有用的合成方法，用于目标分子(如药物，功能材料等)或天然产物的合成。有机氟化学包括氟化试剂、氟化方法、含氟材料等研究。高附加值精细化学品如医药、农药、染料中间体等的合成研究。有机材料化学如液晶，非线性材料，荧光和磷光材料等。
科研：主持国家“自然基金项目”、上海市“浦江人才项目”和“教委重大创新项目”等多项，以及与企业合作项目。
教学：主讲本科生和研究生的双语《有机化学》、《现代有机化学》、《绿色化学》、《精细有机合成新方法》等课程。
课题组成员：
在读博士生：郑生才（获2010“优秀研究生”奖、2011“陶氏化学”特等奖、2012“国家奖学金”）
高宁（直博，获2011“倪天增”奖、2012“优秀研究生”奖、“2012博士生第二阶段优秀奖学金”）
刘炜（获2012“和氏璧”奖）
在读硕士生：唐佳亮（获2012“光华奖”）
发表的论文&申请的专利
[1]"Synthesisofchiralallylicthioesters:enantio-andregioselectiveiridium-catalyzedallylationsofKSAc",
NingGaoandXiaomingZhao*
Eur.J.Org.Chem.,2013,accepted.
[2]"Highlyefficientcycloadditionreactionof1,3-diyneswithsodiumazide:anewwayto5-substituted-4-acetylene-1H-1,2,3-triazoles",
JialiangTang,LingMing,andXiaomingZhao*
J.HeterocyclicChem.,2013,accepted.
[3]"Synthesisof2,5-disubstitutedthiophenesviametal-freesulfurheterocyclizationof1,3-diyneswithsodiumhydrosulfide",
JialiangTang,XiaomingZhao*
RSCAdvances,2012,2,5488-5490.
[4]"Iridium-catalyzedenantioselectiveallylationofsodium2-aminobenzenethiolate:anaccesstochiralbenzo-fusedN,S-heterocycles",
NingGao,XinwenGuo,ShengcaiZheng,WeikangYang,XiaomingZhao*
Tetrahedron,2012,68,9413-9418(ThispaperwashighlightedinSynfacts,2013,1,71).
[5]"EnantioselectiveIridium-catalyzedallylationofsodiumbenzotriazolide:anefficientwaytochiralallylbenzotriazoles",
MinZhang,XinwenGuo,ShengcaiZheng,XiaomingZhao*
TetrahedronLetters,2012,53,6995-6998.
[6]"Onepotiridium-catalyzedasymmetricaldoubleallylaitonsofsodiumSulfide:afastandeconomicwaytoconstructchiralC2-symmetricbis(1-substituted-allyl)sulfane",
ShengcaiZheng,WeiqingHuang,NingGao,RuiminCui,MinZhang,andXiaomingZhao*
Chem.Commun.,2011,45,6969-6971.
[7]"EnantioselectivePalladium-CatalyzedAllylicSubstitutionofSodiumBenzotriazoleide",
WeiLiu,DazhiZhang,ShengcaiZheng,YinshuangYue,DonggeLiuandXiaomingZhao*
Eur.J.Org.Chem.,2011,6288-6293(ThispaperwashighlightedinSynfacts,2012,8,188).
[8]"Carbon-sulfurbondformatonviaIridium-catalyzedasymmetricalallylationofaliphaticthiols"
NingGao,ShengcaiZheng,WeikangYang,andXiaomingZhao*
OrganicLetters,2011,13,1514-1516(ThispaperwashighlightedbyOrganicChemistryPortal,2011,Dec,see:www.organic-chemistry.org/abstracts/lit3/207.shtm).
[9]"Iridium-CatalyzedAsymmetricAllylationofSodiumTriisopropylsilanethiolate:aNewWaytoFormChiralThiols"
WeiqingHuang,ShengcaiZheng,JialiangTang,andXiaomingZhao*
Org.Biomol.Chem.,2011,9,7897-7903.
[10]"HighlyregioselectivePd-catalyzedallylicalkylationof?uorobis(phenylsulfonyl)methane",
XiaomingZhao,*DonggeLiu,ShengcaiZheng,andNingGao
TetrahedronLett.,2011,52,665-667.
[11]"Regio-andEnantioselectiveIridium-CatalyzedAllylationofThiophenol:SynthesisofEnantiopureAllylPhenylSulfides"
ShengcaiZheng,NingGao,WeiLiu,DonggeLiu,XiaomingZhao,*andTheodoreCohen
OrganicLetters,2010,12,4454-4457(ThispaperwashighlightedinSynfacts,2010,12,1400).
[12]"ReadilyPrepared3-Chloro-1-(phenylthio)propene,aVersatileThree-CarbonAnnulatingAgent"
TaopingLiu,XiaomingZhao*,LongLu,andTheodoreCohen*
OrganicLetters,2009,11,4576-4579.
[13]"Iridium-catalyzedRegio-andEnantioselectiveAllylicAlkylationofFluorobis(phenylsulfonyl)methane"
WenboLiu,ShengcaiZheng,HuHe,XiaomingZhao*,LixinDai,andShuliYou*
Chem.Commun.,2009,43,6604-6606.
[14]"Iridium-CatalyzedReactionsofTrifluoromethylatedCompoundswithAlkenes:ACsp3-HBondActivationatotheTrifluoromethylGroup",Y.Guo;X.Zhao;D.Zhang;S-I.Murahashi
Angew.Chem.Int.Ed.,2009,48,2047-2049.
[15]"Efficient1,4-additionofa-substitutedfluoro(phenylsulfonyl)methanederivativestoa,b-unsaturatedcompounds",
G.K.SuryaPrakash,*XiaomingZhao,SujithChacko,FangWang,Habiba,Vaghoo,andGeorgeA.Olah*
Beil.J.Org.Chem.,2008,4,No.17.
[16]"2-Phenylthio-3-bromopropene,aValuableSynthons,EasilyPreparedbyaSimpleRearrangement",
WenboChen,XiaomingZhao,*LongLuandT.Cohen*
OrganicLetters,2006,8,2807-2090.
[17]“HighlyEnantioselectiveFormationofTrifluoromethyl(CF3)-containingStereogenicCarbinaminesviaAsymmetricStreckerReaction”,HuaWang,XiaomingZhao,LongLuandYouhua,Li
OrganicLetters,2006,8,1379-1381.
[18]“AsymmetricSynthesisofFourIsomersof2-C-Trifluromethyl-erythriol”,HuaWang,XiaomingZhao,LongLuandYouhua,Li
J.Org.Chem.2006,71,3278-3281.
[19]“APlatinumAcetylidePolymerwithStericallyDemandingSubstituents:EffectofAggregationontheTripletExcitedState”,
XiaomingZhao,ThomasCardolaccia,RichardFarley,KhalilA.AbboudandKirkS.Schanze.
InorganicChemistry,2005,44,2619-2627(IF3.3).
[20]“HighStereoSelectivePreparationofO-protected2-Trifluoromethyl-3-BromoallylicAlcoholsfrom1,1-Dibromo-1-Alkenes”,
YouhuaLi,LongLu,XiaomingZhao
OrganicLetters2004,6,4467-4470(IF4.0).
[21]“Bis-silylsubstitutedferrocenylenes,includingdicyanovinylelectron-withdrawinggroups,aspotentialnon-linearopticalmaterials”,
XiaomingZhao,HemantSharma,FranciscoCervantes-LeeandKeithH.Pannell,GaryJ.Long,AhmedM.Shahin
JournalofOrganometallicChemistry2003,686,235-241(IF2.04).
申请专利：12项。
