赵宝国(BaoguoZhao)教授:上海市东方学者,1996于武汉大学化学系获理学学士学位,2002年于南京大学化学系获理学硕士学位,2006于中国科学院上海有机化学研究所获理学博士学位,2006-2011年于美国科罗拉多州立大学化学系做博士后研究,2011年加入上海师范大学。Email:zhaobg2006@shnu.edu.cn
研究方向:(1)新型反应的发展;(2)不对称催化;(3)天然产物全合成。
发表文章和专利:
1. ThomasA.Ramirez,BaoguoZhaoandYianShi*“Recentadvancesintransitionmetal-catalyzedsp3C–Haminationadjacenttodoublebondsandcarbonylgroups”Chem.Soc.Rev.2012,41,931-942.
2. BaoguoZhao,XingaoPeng,YingguangZhu,ThamosA.Ramirez,RichardG.Cornwall,YianShi*“Cu(I)-CatalyzedDiaminationofConjugatedDienes.ComplementaryRegioselectivityfromTwoDistinctMechanisticPathways”J.Am.Chem.Soc.2011,133,20890-20900.
3. XingaoPeng,YingguangZhu,ThomasA.Ramirez,BaoguoZhao,YianShi*“NewReactivityofOxaziridine:Pd(II)-CatalyzedAromaticC-HEthoxycarbonylationviaC-CBondCleavage”Org.Lett.2011,13,5244-5247.
4. RichardG.Cornwall,BaoguoZhao,YianShi*“ComplementaryRegioselectivityintheCu(I)-CatalyzedDiaminationofConjugatedDienesToFormCyclicSulfamides”Org.Lett.2011,13,434-437.
5. BaoguoZhao,XingaoPeng,SunliangCui,YianShi*“Cu(I)-catalyzedRegioselectiveDiaminationofConjugatedDienesviaDualMechanisticPathways”J.Am.Chem.Soc.2010,132,11009-11011.
6. BaoguoZhao,HaifengDu,SunliangCui,YianShi*“SyntheticandMechanisticStudiesofPd(0)-CatalyzedDiaminationofConjugatedDienes”J.Am.Chem.Soc.2010,132,3523-3532.
7. BaoguoZhao,HaifengDu,RenzhongFu,YianShi*“Pd(0)-CatalyzedAsymmetricAllylicandHomoallylicDiaminationof4-Phenyl-1-butenewithDi-tert-butyldiaziridinone”Org.Synth.2010,87,263.
8. ThamosA.Ramirez,BaoguoZhao,YianShi*“AneffectiveC-CDoublebondformationviaCu(I)-Catalyzeddehydrogenation”TetrahedronLett.2010,51,1822-1825.
9. BaoguoZhao,HaifengDu,YianShi*“Cu(I)-catalyzedDiaminationofConjugatedOlefinswithTunableCounteranions.APossibleApproachtoAsymmetricDiamination”J.Org.Chem.2009,74,8392-8395.
10. BaoguoZhao,HaifengDu,YianShi*“Cu(I)-CatalyzedC-Hα-AminationofArylKetones:DirectSynthesisofImidazolinones”J.Org.Chem.2009,74,4411-4413.
11.YuehongWen,BaoguoZhao,YianShi*“Cu(I)-CatalyzedDiaminationofDisubstitutedTerminalOlefins:AnApproachtoPotentNK1Antagonist”Org.Lett.2009,11,2365-2368.
12. RengzhongFu,BaoguoZhao,YianShi*“Synthesisof(+)-CP-99,994viaPd(0)-CatalyzedAsymmetricAllylicandHomoallylicC-HDiaminationofTerminalOlefin”J.Org.Chem.2009,74,7577-7580.
13.HaifengDu,BaoguoZhao,YianShi*"Pd(0)-CatalyzedDiaminationoftrans-1-Phenyl-1,3-butadienewithDi-tert-butyldiaziridinoneasNitrogenSource”Org.Synth.2009,86,315.
14.BaoguoZhao,HaifengDu,YianShi*“ACu(I)-CatalyzedC-Hα-AminationofEsters.DirectSynthesisofHydantoins”J.Am.Chem.Soc.2008,130,7220-7221.
15.BaoguoZhao,HaifengDu,YianShi*“Cu(I)-CatalyzedCycloguanidinationofOlefins”Org.Lett,2008,10,1087-1090.
16.HaifengDu,BaoguoZhao,YianShi*“CatalyticAsymmetricAllylicandHomoallylicDiaminationofTerminalOlefinsviaFormalC-HActivation”J.Am.Chem.Soc.2008,130,8590-8591.
17.HaifengDu,BaoguoZhao,WeichengYuan,YianShi*“Cu(I)-CatalyzedAsymmetricDiaminationofConjugatedDienes”Org.Lett.2008,10,4231-4234.
18.BaoguoZhao,XingaoPeng,Zhengwang,ChunguXia,KuilingDing*“ModularChiralBidentatePhosphonites:Design,Synthesis,andApplicationinCatalyticAsymmetricHydroformylationReactions”Chem.Eur.J.2008,14,7847-7857.
19.KuilingDing,BaoguoZhao,Xingaopeng,ZhengWang“Preparationofchiralbidentatephosphoniteligandsandtheapplicationinolefinasymmetriccatalytichydroformylationreaction”Chinesepatent,2008,CN101298460A20081105.
20.BaoguoZhao,WeichengYuan,HaifengDu,YianShi*“Cu(I)-CatalyzedIntermolecularDiaminationofActivatedTerminalOlefins”Org.Lett.2007,9,4943-4945.
21.HaifengDu,BaoguoZhao,YianShi*“AFacilePd(0)-CatalyzedRegio-andStereoselectiveDiaminationofConjugatedDienesandTrienes”J.Am.Chem.Soc.2007,129,762-763.
22.HaifengDu,WeichengYuan,BaoguoZhao,YianShi*“APd(0)-CatalyzedDiaminationofTerminalOlefinsatAllylicandHomoallylicCarbonsviaFormalC-HActivationunderSolvent-FreeConditions”J.Am.Soc.Chem.2007,129,7496-7497.
23.HaifengDu,WeichengYuan,BaoguoZhao,YianShi*“CatalyticAsymmetricDiaminationofConjugatedDienesandTriene”J.Am.Soc.Chem.2007,129,11688-11689.
24.WeichengYuan,HaifengDu,BaoguoZhao,YianShi*“AMildCu(I)-CatalyzedRegioselectiveDiaminationofConjugatedDienes”Org.Lett.2007,9,2589-2591.
25.BaoguoZhao,ZhengWang,KuilingDing*“PracticalbyLigandDesign:ANewGenerationofMonodentatePhosphoramiditeLigandsforRhodiumCatalyzedEnantioselectiveHydrogenations”Adv.Synth.Catal.2006,348,1049-1057
26.MinZhang,HuiyingAn,BaoguoZhao,JianhuaXu*“Aromaticannulationstrategyfornaphthalenesfusedat1,?2-and3,?4-?positionswithtwoheterocycles”Org.Biomol.Chem.2006,4,33-35.
27.KuilingDing,BaoguoZhao“Synthesisandapplicationofbidentatephosphoramiditeligandwithbinaphtholbackboneinalkenehydroformylationreaction”Chinesepatent,2006,CN1857776A20061108.
28.KuilingDing,BaoguoZhao“Preparationofchiralmonophosphorousligandforasymmetrichydrogenation”Chinesepatent,2005,CN1616470A20050518.
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