解永树，教授, 博士生导师
教育部新世纪优秀人才(2011)，上海市****(2011)，上海市浦江人才(2008)，中国化学会卟啉与酞菁专业委员会副主任委员(2014~)。
电话：
E-mail: yshxie@ecust.edu.cn.
课题组主页：http://www.xielab-ecust.cn/
解永树，1971 年9 月出生于安徽庐江。1998 年于浙江大学化学系获博士学位，导师为
围绕卟啉这一自然界广泛存在的重要功能分子，系统开展特殊功能导向的新型卟啉共轭结构设计、合成与功能调控研究。通过卟啉染料结构优化与共敏化策略，将染料敏化太阳能电池效率可达12% 以上。同时，还系统开展了荧光探针研究，应用于生物体和环境领域有重要价值的离子的检测。发表SCI 论文180 余篇，其中Angew. Chem. Int. Ed.11 篇，J. Am. Chem. Soc.4 篇，并应邀发表Chem. Rev. 和Chem. Soc. Rev.综述各1 篇。全部论文SCI 他引4500 余次，其中近5 年他引3400 余次。两次被Angew. Chem. Int. Ed.highlight 专题报道。美国发明专利授权2 项。目前负责国家自然科学基金面上项目、中国NSFC-瑞典STINT 国际交流项目等项目。
主要研究方向:
1、精细有机合成：设计、合成新型有机光电功能分子，应用于荧光探针和光电转换等领域。
2、新型卟啉研究：基于“生命色素” 卟啉，开展功能导向的新型卟啉研究，应用于太阳能电池等领域。
近年来发表的代表性论文：
1)Yubin Ding, Wei-Hong Zhu, and Yongshu Xie*, Development of ion sensors based on porphyrin analogues, Chem. Rev.,2017, 117, 2203?2256.(IF 52.613).
2)Yubin Ding, Yunyu Tang, Weihong Zhu, and Yongshu Xie*, Fluorescent and colorimetric ion probes based on conjugated oligopyrroles, Chem. Soc. Rev., 2015, 44, 1101–1112(IF 40.182).
3)Qizhao Li, Chengjie Li, Jinseok Kim, Masatoshi Ishida, Xin Li, Tingting Gu, Xu Liang, Weihua Zhu, Hans ?gren, Dongho Kim,*, Hiroyuki Furuta,* and Yongshu Xie*, Regioselectively Halogenated Expanded Porphyrinoids as Building Blocks for Constructing Porphyrin?Porphyrinoid Heterodyads with Tunable Energy Transfer, J. Am. Chem. Soc., 2019, 141, 5294–5302(IF 14.357).
4)Qizhao Li, Masatoshi Ishida, Hiroto Kai, Tingting Gu, Chengjie Li, Xin Li, Glib Baryshnikov, Xu Liang, Weihua Zhu, Hans ?gren, Hiroyuki Furuta*, Yongshu Xie*, Thiophene‐Cleavage‐Triggered Skeletal Rearrangement of a Twisted Thia‐norhexaphyrin towards Multiply‐Annulated Polypyrrolic Aromatic Macrocycles, Angew. Chem. Int. Ed., 2019, 58, 5925–5929 (IF 12.102).
5)Miao Li, Pingchun Wei, Masatoshi Ishida, Xin Li, Mathew Savage, Rui Guo, Zhongping Ou, Sihai Yang, Hiroyuki Furuta,* and Yongshu Xie*, Macrocyclic transformations from norrole to isonorrole and an N-confused corrole with a fused hexacyclic ring triggered by a pyrrole substituent, Angew. Chem. Int. Ed., 2016, 55, 3063(IF 12.102).
6)Yongshu Xie*, Yunyu Tang, Wenjun Wu, Yueqiang Wang, Jingchuan Liu, Xin Li, He Tian, and Wei-Hong Zhu*, Porphyrin cosensitization for a photovoltaic efficiency of 11.5%: a record for non-ruthenium solar cells based on iodine electrolyte, J. Am. Chem. Soc., 2015, 137, 14055–14058(IF 14.357).
7)Andong Shao, Yongshu Xie, Shaojia Zhu, Zhiqian Guo,* Shiqin Zhu, Jin Guo, Ping Shi, Tony D. James, He Tian, and Wei-Hong Zhu*, Far-red and near-IR AIE-active fluorescent organic nanoprobes with enhanced tumor-targeting efficacy: shape-specific effects, Angew. Chem. Int. Ed., 2015,54(25), 7275-7280 (IF 12.102).
8)Yueqiang Wang, Bin Chen, Wenjun Wu, Xin Li, Weihong Zhu, He Tian andYongshu Xie*, Efficient solar cells sensitized by porphyrins with an extended conjugation framework and a carbazole donor: from molecular design to cosensitization, Angew. Chem. Int. Ed., 2014,53,10779–10783 (IF 12.102).
9)Pingchun Wei, Kai Zhang, Xin Li, Deying Meng, Hans ?gren, Zhongping Ou, Seikweng Ng, Hiroyuki Furuta*, and Yongshu Xie*, Neo-fused hexaphyrin: a molecular puzzle containing an N-linked pentaphyrin, Angew. Chem. Int. Ed., 2014,53, 14069–14073(IF 12.102).
10)Yue Wu, Yongshu Xie, Qiong Zhang, He Tian, Weihong Zhu*, Alexander D. Q. Li*, Quantitative photoswitching in bis(dithiazole)ethene enables modulation of light for encoding optical signals, Angew. Chem., Int. Ed., 2014, 53, 2090–2094(IF 12.102).
11)Wenlong Li, Changhong Jiao, Xin Li, Yongshu Xie, Keitaro Nakatani, He Tian, Weihong Zhu*, Separation of photoactive conformers based on hindered diarylethenes: efficient modulation in photocyclization quantum yields, Angew. Chem. Int. Ed., 2014,53, 4603–4607(IF 12.102).
12)Yongshu Xie*,Pingchun Wei, Xin Li, Tao Hong, Kai Zhang, and Hiroyuki Furuta*, Macrocycle contraction and expansion of a dihydrosapphyrin isomer, J. Am. Chem. Soc., 2013, 135, 19119–19122(IF 14.357).
13)Zhiyun Zhang, Bo Xu, Jianhua Su, Leiping Shen, Yongshu Xie, He Tian*, Color-tunable solid-state emission of 2,2'-biindenyl-based fluorophores, Angew. Chem. Int. Ed., 2011, 50, 11654–11657(IF 12.102).
14)Weihong Zhu*, Yuheng Yang, Rémi Métivier, Qiong Zhang, Régis Guillot, Yongshu Xie, He Tian, Keitaro Nakatani*, Unprecedented stability of a photochromic bisthienylethene based on benzobisthiadiazole as an ethene bridge, Angew. Chem. Int. Ed.2011, 50, 10986–10990 (IF 12.102).
15)Yongshu Xie, Keisuke Yamaguchi, Motoki Toganoh, Hidemitsu Uno, Masaaki Suzuki, Shigeki Mori, Shohei Saito, Atsuhiro Osuka*, Hiroyuki Furuta*,Triply N-confused hexaphyrins: near-infrared luminescent dyes with a triangular shape, Angew. Chem. Int. Ed., 2009, 48, 5496–5499(IF 12.102).
16)Francis D’Souza*,Navaneetha K. Subbaiyan, Yongshu Xie, Jonathan P. Hill*, Katsuhiko Ariga, Kei Ohkubo, and Shunichi Fukuzumi*, Anion-complexation-induced stabilization of charge separation, J. Am. Chem. Soc., 2009, 131, 16138–16146(IF 14.357).
17)Yongshu Xie, Tatsuki Morimoto, Hiroyuki Furuta*,SnIVcomplexes of N-confused porphyrins and oxoporphyrins - Unique fluorescence Switch-On halide receptors, Angew. Chem. Int. Ed., 2006, 45, 6907–6910 (IF 12.102).
18)Kaiwen Zeng, Yunyue Lu, Weiqiang Tang, Shuangliang Zhao, Qingyun Liu, Weihong Zhu, He Tian, and Yongshu Xie*, Efficient solar cells sensitized by a promising new type of porphyrins: dye-aggregation suppressed by double strapping, Chem. Sci., 2019, 10, 2186-2192(IF 9.063).
19)Yongshu Xie, Wenjun Wu, Haibo Zhu, Jingchuan Liu, Weiwei Zhang, He Tian, and Wei-Hong Zhu*, Unprecedentedly targeted customization of molecular energy levels with auxiliary-groups in organic solar cell sensitizers, Chem. Sci., 2016, 7, 544-549(IF 9.063).
20)Yunyue Lu, Heli Song, Xin Li, Hans ?gren, Qingyun Liu, Jiwei Zhang, Xuan Zhang,* Yongshu Xie*, Multiply Wrapped Porphyrin Dyes with a Phenothiazine Donor: A High Efficiency of 11.7% Achieved through a Synergetic Coadsorption and Cosensitization Approach, ACS Applied Materials & Interfaces, 2019, 11, 5046-5054(IF 8.097).
21)Yunyue Lu, Qingyun Liu, Jiaxin Luo, Bo Wang, Tong Feng, Xiaoyi Zhou, Xinyu Liu, Yongshu Xie*, Solar Cells Sensitized with Porphyrin Dyes Containing Oligo(Ethylene Glycol) Units: a High Efficiency Beyond 12%, ChemSusChem, 2019, DOI: 10.1002/cssc. (IF 7.411).
22)Fangtao Ma, Li Zhou,Qingyun Liu, Chengjie Li*,and Yongshu Xie*, Selective Photocatalysis Approach for Introducing ArS Units into BODIPYs through Thiyl Radicals, Org. Lett., 2019, 21(3), 733–736(IF 6.492).
23)Yingchun Cheng, Guosheng Yang, Haoran Jiang, Shuangliang Zhao, Qingyun Liu, Yongshu Xie*, Organic Sensitizers with Extended Conjugation Frameworks as Cosensitizers of Porphyrins for Developing Efficient Dye-Sensitized Solar Cells. ACS Applied Materials & Interfaces, 2018, 10, 38880-38891 (IF 8.097).
24)Heli Song, Jing Zhang, Jiamin Jin, Haifeng Wang, and Yongshu Xie*, Porphyrin Sensitizers with Modified Indoline Donors for Dye-Sensitized Solar Cells, J. Mater. Chem. C, 2018, 6 (15), 3927-3936 (IF 5.976).
25)Jiewei Shao, Chengjie Li,*, Jiahui Kong, Haoran Jiang, Shuangliang Zhao, Minzhi Li, Xu Liang, Weihua Zhu, and Yongshu Xie*, Regioselective Oxidative Ring Cleavage of a Phlorin Analogue: an Approach for Synthesizing Linear Tetrapyrroles, Org. Lett., 2018, 20(7),1941-1944 (IF 6.492).
26)Heli Song, Qingyun Liu, Yongshu Xie*, Porphyrin-sensitized solar cells: systematic molecular optimization, coadsorption and cosensitization, Chem. Commun., 2018, 54, 1811-1824 (IF 6.290).
27)Guosheng Yang, Yunyu Tang, Xin Li, Hans ?gren, and Yongshu Xie*, Efficient Solar Cells Based on Porphyrin Dyes with Flexible Chains Attached to the Auxiliary Benzothiadiazole Acceptor: Suppression of Dye Aggregation and the Effect of Distortion, ACS Appl. Mater. Interfaces, 2017,9(42), 36875–36885 (IF 8.097).
28)Jiahui Kong, Jiewei Shao, Chengjie Li*, Dongdong Qi, Minzhi Li, Xu Liang, Weihua Zhu, Jianzhuang Jiang and Yongshu Xie*, Neo-N-confused Phlorins and Phlorinone: Rational Synthesis and Tunable Properties, Org. Lett., 2017, 19 (3), 650-653 (IF 6.492).
29)Jiahui Kong, Qiong Zhang*, Mathew Savage, Minzhi Li, Xin Li, Sihai Yang, Xu Liang, Weihua Zhu, Hans ?gren, and Yongshu Xie*, Tetra- and Octapyrroles Synthesized from Confusion and Fusion Approaches, Org. Lett., 2016, 18, 5046-5049 (IF 6.492).
30)Zhongmiao Gong, Biao Yang, Haiping Lin, Yunyu Tang, Zeyuan Tang, Junjie Zhang, Haiming Zhang, Youyong Li, Yongshu Xie, Qing Li,* and Lifeng Chi*, Structural Variation in Surface-Supported Synthesis by Adjusting the Stoichiometric Ratio of the Reactants, ACS Nano, 2016, 10, 4228?4235(IF 13.709).
31)Kai Zhang, Mathew Savage, Xin Li, Yu Jiang, Masatoshi Ishida, Koki Mitsuno, Satoru Karasawa, Tatsuhisa Kato, Weihua Zhu, Sihai Yang, Hiroyuki Furuta, and Yongshu Xie*, Rational Syntheses of Helical π-Conjugated Oligopyrrins with a Bipyrrole Linkage: Geometry Control of Bis-Copper(II) Coordination, Chem. Commun., 2016, 52, 5148 – 5151 (IF 6.290).
32)Yunyu Tang, Yueqiang Wang, Xin Li, Hans ?gren, Wei-Hong Zhu, and Yongshu Xie*, Porphyrins containing a triphenylamine donor and up to eight alkoxy chains for dye-sensitized solar cells: a high efficiency of 10.9%,ACS Appl. Mater. Interf., 2015, 7(50), 27976-27985(IF 8.097).
33)Wei Tiantian, Xi Sun, Xin Li,* Hans ?gren, and Yongshu Xie*, Systematic investigations on the roles of the electron acceptor and neighboring ethynylene moiety in porphyrins for dye-sensitized solar cells, ACS Appl. Mater. Interf., 2015, 7, 21956?21965 (IF 8.097).
34)Kai Zhang, Junda Zhang, Xin Li, Rui Guo, Hans ?gren, Zhongping Ou, Masatoshi Ishida, Hiroyuki Furuta,* and Yongshu Xie*, Synthesis of a neo-confused octaphyrin and the formation of its mononuclear complexes, Org. Lett. 2015, 17, 4806?4809 (IF 6.492).
35)Xueli Shen, Xiaodong Wei, Pengli Tan,Yingguo Yu, Biao Yang, Zhongmiao Gong, Haiming Zhang, Haiping Lin, Youyong Li, Qing Li,* Yongshu Xie,*Lifeng Chi,* Concentration-controlled reversible phase transitions in self-assembled monolayers on HOPG surfaces, Small, 2015, 11(19), 2284-2290 (IF 9.598).
36)Yunyu Tang, Yubin Ding, Xin Li, Hans ?gren, Tong Li, Weibing Zhang, Yongshu Xie*, Acylation of dipyrromethanes at the aand bpositions and further development of fluorescent Zn2+probes, Sensors and Actuators B: Chemical, 2015, 206, 291–302 (IF 5.667).
37)Kai Zhang, Pingchun Wei, Xin Li, Hans ?gren, Yongshu Xie*,Oxidative ring closure and metal triggered ring opening: syntheses of macrocyclic and linear hexapyrroles, Org. Lett., 2014, 16, 6354–6357(IF 6.492).
38)Xi Sun, Yueqiang Wang, Xin Li, Hans ?gren, Weihong Zhu, He Tian, and Yongshu Xie*, Cosensitizers for simultaneous filling up both absorption valleys of porphyrins: a novel approach for developing efficient panchromatic dye-sensitized solar cells,Chem. Commun.,2014,50, 15609–15612(IF 6.290).
39)Yubin Ding, Xin Li, Jonathan P. Hill, Katsuhiko Ariga, Hans ?gren, Joakim Andréasson, Weihong Zhu, He Tian, Yongshu Xie*, Acid/Base switching of the tautomerism and conformation of a dioxoporphyrin for integrated binary subtraction, Chem. Eur. J., 2014, 20, 12910–12916(IF 5.160).
40)Bin Chen, Xi Sun, Xin Li, Hans ?gren,Yongshu Xie*,TICT based fluorescence “turn-on” hydrazine probes, Sensors and Actuators B: Chemical, 2014, 199, 93–100(IF 5.667).
