蔡正国
博士
教授
高分子科学与工程系
博士生导师
caizg@dhu.edu.cn



·研究方向:
配位聚合与大分子设计；新型成纤高聚物设计、合成及应用研究

·荣誉获奖:
1、2012年度教育部“新世纪优秀人才支持计划
2、2012年度“曙光计划”项目
3、2010年度日本高分子研究奖励赏
4、2006年度国家优秀自费留学生奖学金

·学习及工作经历:
1993.9 - 1997.7: 吉林工学院，高分子材料，学士
2002.9 - 2004.7: 日本东京工业大学，高分子化学与物理，硕士（导师：Takeshi SHIONO）
2004.9 - 2007.3: 日本广岛大学，高分子化学与物理，博士（导师：Takeshi SHIONO）
2010.8 - 2011.1: 美国芝加哥大学，访问****
2007.4 - 2011: 日本广岛大学，助理教授
2011- 东华大学材料科学与工程学院，教授

·主讲课程：
高分子化学、高分子合成化学

·主要论文：
1. Song, X.; Cao, L.; Tanaka, L.; Shiono, T.*; Cai, Z.* Optically Transparent Functional Polyolefin Elastomer with Excellent Mechanical and Thermal Properties ACS Macro Lett.2019, 8, 299-303.
2. Structurally Simple Dinuclear Nickel Catalyzed Olefin Copolymerization with Polar Monomers, Cheng, H.;Wang, H.; Li, Y.; Hu, Y.; Zhang, X.*; Cai, Z.* J. Catal.2018, 368, 291-297.
3. Efficient Ethylene Copolymerization with Polar Monomers Using Palladium Anilinonaphthoquinone Catalysts. Ding, L.; Cheng, H.; Li, Y.; Tanaka, R.;Shiono, T.*; Cai, Z.* Polym. Chem.2018, 9, 5476-5482.
4. Wang, H.;Cheng, H.; Tanaka, R.; Shiono, T.*; Cai, Z.* Efficient Control of Ethylene–Norbornene Copolymerization Behavior of a Fluorenylamidoligated Titanium Complex: Substituent Effects of The Amido Ligand and Copolymer Properties, Polym. Chem.2018, 9, 4492-4497.
5. Wang, H.; Li, Y.; Cai, Z.* Substituent Effects of Phenyl Group on Silylene Bridge in Stereospecific Polymerization of Propylene with C₁-Symmetric ansa-Silylene(Fluorenyl)(Amido) Dimethyl Titanium Complexes, Polymers2018, 9, 1075-1084.
6. Cheng, H.; Cai, Z.* (Anilino)anthraquinone Nickel-Catalyzed Random Copolymerization of Norbornene and Ethylene, ChemCatChem2018, 10, 497-500.
7．Neutral Nickel(II) Complexes Bearing Aryloxide Imidazolin-2-imine Ligands for Efficient Copolymerization of Norbornene and Polar Monomers, Li, M.; Cai, Z.*; Eisen, M.S.*Organometallics2018, 37, 4753-4762.
8. Li, M.; Shu, X.; Cai, Z.*; Eisen, M.S.* Synthesis, Structures and Norbornene Polymerization Behavior of Neutral Nickel(II) and Palladium(II) Complexes Bearing Aryloxide Imidazolidin-2-imine Ligands, Organometallics2018, 37, 1172-1180.
9. Cheng, H.; Su, Y.; Hu, Y.; Zhang, X.; Cai, Z.*Ethylene Polymerization and Copolymerization with Polar Monomers Using Nickel Complexes Bearing Anilinobenzoic Acid Methyl Ester Ligand, Polymers2018, 10, 754-763.
10. Song, X.; Ma, Q.; Cai, Z.*Synthesis of Hydroxy-functionalized Ultrahigh Molecular Weight Polyethylene Using Fluorenylamidotitanium Complex, Chines J. Polym. Sci. 2018, 36, 171-175.
11. Fu, X.; Zhang, L.; Tanaka, R.; Shiono, T.*; Cai, Z.* Highly Robust Nickel Catalysts Containing Anilinonaphthoquinone Ligand for Copolymerization of Ethylene and Polar Monomers, Macromolecules2017, 50, 9216-9221.
12. Song, X.; Yu, L.; Shiono, T.*; Cai, Z.* Synthesis of Hydroxy-Functionalized Cyclic Olefin Copolymer and Its Block Copolymers with Semicrystalline Polyolefin , Macromol. Rapid Commun.2017, 38, **.
13. Sun, Y.; Xu, B.; Shiono, T.*; Cai, Z.* Highly Active ansa-(Fluorenyl)(amido)titanium-Based Catalysts with Low Load of Methylaluminoxane for Syndiotactic-Speci?c Living Polymerization of Propylene, Organometallics2017, 36, 3009-3012.
14. Sun, Y.; Li, S.; Shiono, T.*; Cai, Z.* Substituent Effects of Adamantyl Group on Amido Ligand in Syndiospecific Polymerization of Propylene with Ansa-Dimethylsilylene(Fluorenyl)(Amido) Zirconium Complex, Polymers2017, 9, 632-641.
15. Song, X.; Ma, Q.; Cai, Z.*;Tanaka, R.; Shiono, T.*; Grubbs, R.B.* Facile Synthesis of Novel Polyethylene-Based A-B-C Block Copolymers Containing Poly(methyl methacrylate) using a Living Polymerization System, Macromol. Rapid Commun.2016, 37, 227-231.
授权专利：
苯胺蒽醌后过渡金属配合物及其制备方法与应用，蔡正国、程程龙，ZL 6.4
苯氧2-亚胺咪唑烷金属配合物及其制备方法和应用，蔡正国、李明远，ZL 7.1
超高分子量乙烯/苯乙烯类共聚物及其制备方法，蔡正国、马琼、袁浩波，ZL 7.3
功能性超高分子量聚乙烯及其制备方法，蔡正国、马琼、李天佑、史新豪、郭敏，ZL 3.1
一种功能性环烯烃/苯乙烯类共聚物及其制备方法，蔡正国、周健，ZL 1.2

近几年承担的科研项目：
国家自然科学基金面上项目三项（**, **, **)，主持人
东华大学中央高校基本科研业务费专项资金（励志计划项目），主持人
东华大学基本科研业务费（追加）专项资金，主持人
日本国家科学研究费，“环烯烃共聚物的精密合成”，项目负责人;
日本学术振兴会青年****海外派遣基金，“乙烯与极性单体的共聚合”，主持人